Sürdürülebilir Yeşil Kampüs Koleksiyonu / Sustainable Green Campus Collection
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Conference Object Citation - WoS: 2Citation - Scopus: 2Arsenic in Groundwater in Western Anatolia, Turkey: a Review(University of Silesia Press, 2010) Gündüz, Orhan; Baba, Alper; Elpit, HandanOccurrence of arsenic (As) in groundwater has been a major problem worldwide for the last hundred years. Considering its toxic effects on human health, the presence of elevated levels of arsenic in groundwater resources used in drinking water supply has been an active research field throughout the world (Van Halem et al., 2009). In this regard, case studies from Bangla-desh, India, Nepal, El Salvador, Ecuador, Honduras, Mexico, Chile, China, Canada, Argentina, Peru, Taiwan, United States, Bolivia and Turkey have been documented with regards to the detection of natural levels in groundwater, the occurrence and distribution mechanisms, the human health effects and the in-situ and ex-situ treatment techniques (Jean et al., 2010). In many of these locations, arsenic is naturally found in the subsurface strata within volcanic and sedimentary formations as well as in areas of geothermal systems related to tectonic activity. Western Anatolia in Turkey is one such area of complex geology with active tectonics and high geothermal potential. This natural setting serves as a suitable environment for the presence of high levels of arsenic in subsurface waters. Based on these fundamentals, this study presents a general overview of arsenic presence in western Anatolia.Conference Object Occurrence of Arsenic and Related Microbial Signature of Hydrothermal Systems in Western Turkey(Taylor & Francis, 2012) Chen, Chienyen; Maity, Jyoti Prakash; Bundschuh, Jochen; Bhattacharya, Prosun; Baba, Alper; Gündüz, OrhanThe naturally occurring aqueous Arsenic (As) and other toxic elements are found around the world. The present study concentrates on arsenic concentrations, speciation and related microbial diversity in a hydrothermal system in Western Turkey. The surface temperatures of hot springs reach up to 90°C and deep well (reservoir) temperatures vary in the range of 40 to 230°C. The elements such as As, B, Br, Ba, Cr, Fe, Mn, V and Zn are found in high concentration in hydrothermal waters. Hydrogeochemically, Seferihisar hot spring exhibited a Na-Cl water type. On the other hand, Karahayit, Pamukkale, Emirfaki, Alaşehir and Sart exhibit a Ca-HCO 3 water type and Çitgöl exhibited a Na-HCO 3-SO 4 water type. The arsenic (As) concentrations in geothermal waters of Western Anatolia have been detected to range from 0.03 mg/L to 1.5 mg/L, including Buharkent (İnalti) (1.50 ± 0.005 mg/L), Kizildere (1.13 ± 0.005 mg/L), Eynal (0.71 ± 0.005 mg/L) and Sarayköy (0.06 ± 0.004 mg/L). Arsenic (III) is the dominant species in geothermal water of Western Anatolia. The 16S rRNA gene sequences of bacterial diversity show that the thermophilic, sulfur/thiosulfate-oxidizing bacterium (Thiobacter subterraneus) is present in Kula geothermal water and mesophilic sulfur- and thiosulfate-oxidizing Sulfurovum lithotrophicum bacterium occurs in Sarayköy geothermal spring. Also, Bacillus fumarioli, (a thermophilic, aerobic endospore forming bacterium growing on (NH 4) 2 SO 4, MgSO 4 and MnSO 4 at 50-55°C), Schlegelella thermodepolymerans and Methylocaldum szegediense are rich in geothermal water.Article Citation - WoS: 18Citation - Scopus: 22The Health Risk Associated With Chronic Diseases in Villages With High Arsenic Levels in Drinking Water Supplies(Springer Verlag, 2017) Gündüz, Orhan; Bakar, Coşkun; Şimşek, Celalettin; Baba, Alper; Elçi, Alper; Gürleyük, Hakan; Mutlu, Merdiye; Çakır, AyşeThis study is intended to compare and assess the distribution and possible causes of current chronic diseases in villages with high arsenic levels in drinking water supplies. It is a cross-sectional epidemiological research that analyzes the frequency and underlying risk factors of chronic diseases in villages with varying levels of arsenic exposure through drinking water. Sample space of study included 1003 individuals, 614 of whom were from villages with high arsenic levels in drinking water and remaining 389 were from two control villages with below-limit arsenic levels in drinking water. While nutritional habits and living environments of two groups were similar, cigarette smoking and alcohol use were higher in villages with low arsenic levels. Mini mental state examination test results in 60+ age group were lower in villages with high arsenic levels. Although no statistically significant differences were detected in chronic disease occurrence between the groups, the number of cases was higher in villages with higher percentage of cigarette smoking and alcohol use. Moreover, cases of lung, colon, and stomach cancers were higher in villages with high arsenic levels in drinking water supplies.Article Citation - WoS: 20Citation - Scopus: 22Modeling of Seawater Intrusion in a Coastal Aquifer of Karaburun Peninsula, Western Turkey(Springer Verlag, 2017) Mansour, Ahmed Y. S.; Baba, Alper; Gündüz, Orhan; Şimşek, Celalettin; Elçi, Alper; Murathan, Alim; Sözbilir, HasanSeawater intrusion is a major problem to freshwater resources especially in coastal areas where fresh groundwater is surrounded and could be easily influenced by seawater. This study presents the development of a conceptual and numerical model for the coastal aquifer of Karareis region (Karaburun Peninsula) in the western part of Turkey. The study also presents the interpretation and the analysis of the time series data of groundwater levels recorded by data loggers. The SEAWAT model is used in this study to solve the density-dependent flow field and seawater intrusion in the coastal aquifer that is under excessive pumping particularly during summer months. The model was calibrated using the average values of a 1-year dataset and further verified by the average values of another year. Five potential scenarios were analyzed to understand the effects of pumping and climate change on groundwater levels and the extent of seawater intrusion in the next 10 years. The result of the analysis demonstrated high levels of electrical conductivity and chloride along the coastal part of the study area. As a result of the numerical model, seawater intrusion is simulated to move about 420 m toward the land in the next 10 years under “increased pumping” scenario, while a slight change in water level and TDS concentrations was observed in “climate change” scenario. Results also revealed that a reduction in the pumping rate from Karareis wells will be necessary to protect fresh groundwater from contamination by seawater.Conference Object Citation - Scopus: 4High Arsenic Levels in Groundwater Resources of Gediz Graben, Western Turkey(CRC Press, 2016) Baba, Alper; Gündüz, Orhan; Şimşek, Celalettin; Elçi, Alper; Sözbilir, Hasan; Murathan, AlimGediz Graben situated in western Turkey is an area containing extensional structures with active tectonics and geothermal systems that serves as a suitable environment for the presence of high levels of arsenic (As) in groundwater. The results of a comprehensive monitoring program in the basin revealed that the maximum As concentration detected during the monitoring program was 3086 ppb and the average value was calculated to be 23.63 ppb. In addition, As levels in 28% of the water samples were above the 10 ppb limit value making them unsuitable for drinking water supply. These high As concentrations in the basin was mostly associated with long detention times of water in altered rocks located along detachment faults, strong water–rock interaction processes in the alteration zones and anthropogenic influences made within the geothermal fluid reservoir. © 2016 Taylor & Francis Group, London.Article Citation - WoS: 27Citation - Scopus: 31Statistical Analysis of Causes of Death (2005-2010) in Villages of Simav Plain, Turkey, With High Arsenic Levels in Drinking Water Supplie(Taylor and Francis Ltd., 2015) Gündüz, Orhan; Bakar, Coşkun; Şimşek, Celalettin; Baba, Alper; Elçi, Alper; Gürleyük, Hakan; Mutlu, Merdiye; Çakır, AyşeThe purpose of this research was to compare the causes of death in 5 villages situated in Simav Plain, Turkey, during 2005-2010 where different arsenic levels were detected in drinking water supplies. Since groundwater in Simav Plain had arsenic concentrations that ranged between 7.1 and 833.9 ppb, a two-phase research was formulated. In the first phase, public health surveys were conducted with 1,003 villagers to determine the distribution of diseases. In the second phase, verbal autopsy surveys and official death records were used to investigate the causes of death. In total, 402 death cases were found in the study area where cardiovascular system diseases (44%) and cancers (15.2%) were major causes. Cancers of lung (44.3%), prostate (9.8%), colon (9.8%), and stomach (8.2%) were comparably higher in villages with high arsenic levels in drinking water supplies. Furthermore, the majority of cases of liver, bladder, and stomach cancers were observed in villages with high arsenic levels. © 2015 Taylor and Francis Group, LLC.Article Citation - WoS: 2Citation - Scopus: 2Sample Collection Into Sterile Vacuum Tubes To Preserve Arsenic Speciation in Natural Water Samples(American Society of Civil Engineers (ASCE), 2013) Gündüz, Orhan; Gürleyük, Hakan; Çakır, Ayşe; Elçi, Alper; Baba, Alper; Şimşek, CelalettinThe accurate speciation analysis of arsenic is a serious concern for water quality monitoring programs. Because the preservation of sample integrity until analysis is one of the most important aspects of speciation, this study aims to compare the performance of four different sample preservation methods under diverse conditions of sample quality. Natural samples with different characteristics were collected into the following containers to study their effectiveness: (1) standard high-density polyethylene bottle with no preservative; (2) empty, sterile Vacuette tube with no preservative; (3) sterile tripotassium ethylenediaminetetraacetic acid (K3EDTA) Vacuette tube with K3EDTA additive; and (4) empty, sterile Vacuette tube with added hydrochloric acid (HCl). Known concentrations of arsenite [As(III)] were also added to each container to monitor the oxidation of As(III) to arsenate [As(V)]. The results revealed recovery ratios exceeding 95% in all containers with sterile vacuum conditions. In particular, the K3EDTA Vacuette tube yielded a recovery very close to 100% of the spiked As(III), which is known to rapidly oxidize to As(V). Overall, collecting the sample into a container under sterile vacuum conditions and using a universally accepted preserving agent such as EDTA or HCl significantly improved the preservation of the original species distribution in the water matrix studied, compared to sampling without the use of preservation methods. After validation by future research, these sterile vacuum tubes can possibly be utilized for collecting and storing samples for the routine speciation analysis of other elements such as selenium, chromium, and antimony.Article Citation - WoS: 72Citation - Scopus: 90Naturally Occurring Arsenic in Terrestrial Geothermal Systems of Western Anatolia, Turkey: Potential Role in Contamination of Freshwater Resources(Elsevier Ltd., 2013) Bundschuh, Jochen; Maity, Jyoti Prakash; Nath, B.; Baba, Alper; Gündüz, Orhan; Kulp, Thomas R.; Jean, Jiin-Shuh; Kar, Sandeep; Yang, Huai-Jen; Tseng, Yujung; Bhattacharya, Prosun; Chen, ChienyenArsenic (As) contamination in terrestrial geothermal systems has been identified in many countries worldwide. Concentrations higher than 0.01mg/L are detrimental to human health. We examined potential consequences for As contamination of freshwater resources based on hydrogeochemical investigations of geothermal waters in deep wells and hot springs collected from western Anatolia, Turkey. We analyzed samples for major ions and trace element concentrations. Temperature of geothermal waters in deep wells showed extreme ranges (40 and 230°C), while, temperature of hot spring fluids was up to 90°C. The Piper plot illustrated two dominant water types: Na-HCO3 - type for geothermal waters in deep wells and Ca-HCO3 - type for hot spring fluids. Arsenic concentration ranged from 0.03 to 1.5mg/L. Dominance of reduced As species, i.e., As(III), was observed in our samples. The Eh value ranged between -250 and 119mV, which suggests diverse geochemical conditions. Some of the measured trace elements were found above the World Health Organization guidelines and Turkish national safe drinking water limits. The variation in pH (range: 6.4-9.3) and As in geothermal waters suggest mixing with groundwater. Mixing of geothermal waters is primarily responsible for contamination of freshwater resources and making them unsuitable for drinking or irrigation.Article Citation - WoS: 24Citation - Scopus: 28Effect of Alteration Zones on Water Quality: a Case Study From Biga Peninsula, Turkey(Springer Verlag, 2010) Baba, Alper; Gündüz, OrhanWidespread and intense zones of silicified, propylitic, and argillic alteration can be found in the Çan volcanics of Biga Peninsula, northwest Turkey. Most of the springs in the study area surface out from the boundary between fractured aquifer (silicified zone) and impervious boundary (argillic zone). This study focuses on two such springs in KirazlI area (KirazlI and Balaban springs) with a distinct quality pattern. Accordingly, field parameters (temperature, pH, and electrical conductivity), major anion and cation (sodium, potassium, calcium, magnesium, chloride, bicarbonate, and sulfate), heavy metals (aluminum, arsenic, barium, chromium, cobalt, cupper, iron, lithium, manganese, nickel, lead, and zinc), and isotopes (oxygen-18, deuterium, and tritium) were determined in water samples taken from these springs during 2005 through 2007. The chemical analyses showed that aluminum concentrations were found to be two orders of magnitude greater in KirazlI waters (mean value 13813.25 μg/L). The levels of this element exceeded the maximum allowable limits given in national and international standards for drinking-water quality. In addition, Balaban and KirazlI springs are >55 years old according to their tritium levels; KirazlI spring is older than Balaban spring. KirazlI spring is also more enriched than Balaban spring based in oxygen-18 and deuterium values. Furthermore, KirazlI spring water has been in contact with altered rocks longer than Balaban spring water, according to its relatively high chloride and electrical conductivity values.