Food Engineering / Gıda Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/12
Browse
4 results
Search Results
Review Citation - WoS: 41Citation - Scopus: 43Electrochemical Sensors in the Food Sector: a Review(American Chemical Society, 2024) Ghaani, Masoud; Azimzadeh, Mostafa; Büyüktaş, Duygu; Carullo, Daniele; Farris, StefanoIn a world that is becoming increasingly concerned with health, safety, and the sustainability of food supply chains, the control and assurance of food quality have become of utmost importance. This review examines the application and potential of electrochemical sensors in the dynamic field of food science to meet these expanding demands. The article introduces electrochemical sensors and describes their operational mechanics and the components contributing to their function. A summary of the most prevalent electrochemical methods outlines the diverse food analysis techniques available. The review shifts to discussing the food science applications of these sensors, highlighting their crucial role in detecting compounds in food samples like meat, fish, juice, and milk for contemporary quality control. This paper showcases electrochemical sensors' utility in food analysis, underscoring their significance as powerful, efficient tools for maintaining food safety and how they could transform our approach to global food quality control and assurance.Article Citation - WoS: 6Citation - Scopus: 7Acid-Derived Bacterial Cellulose Nanocrystals as Organic Filler for the Generation of High-Oxygen Barrier Bio-Nanocomposite Coatings(Royal Soc Chemistry, 2023) Carullo, Daniele; Rovera, Cesare; Bellesia, Tommaso; Büyüktaş, Duygu; Ghaani, Masoud; Santo, Nadia; Farris, StefanoMacro-sized bacterial cellulose (BC) derived from Komagataeibacter sucrofermentans was down-sized into nanocrystals (BCNCs) through hydrochloric acid (H-BCNCs) and sulfuric acid (S-BCNCs) hydrolysis. Initially, aqueous dispersions of BCNCs were analyzed for stability, size/morphology, and optical/mechanical properties. Subsequently, BCNCs were incorporated into a main biopolymer phase (i.e., pullulan) to create bio-nanocomposite coatings with high-oxygen barrier performance. Upon treatment with sulfuric acid, nano-sized particles (approximate to 240 nm) were observed, contrasting with significantly larger sizes (approximate to 1.8 mu m) seen for particles obtained using hydrochloric acid. Microscopy analyses revealed a needle-like morphology of the nanocrystals, which appeared organized in stacks for H-BCNCs or as individual units for S-BCNCs. Pullulan/BCNCs coatings applied to polyethylene-terephthalate (PET) films improved the gas barrier performance of the original substrate, by dramatically reducing the oxygen transmission rate (OTR) values from approximate to 120 cm3 m-2 24 h-1 to approximate to 2 cm3 m-2 24 h-1 while preserving its original optical and mechanical properties. Our developed bionanocomposite-coated PET films hold potential as an alternative material for various food packaging applications. This study investigates the effect of the hydrolysis process on bacterial cellulose (BC) to obtain bacterial cellulose nanocrystals (BCNCs) used to create high oxygen barrier nanocomposite coatings for food packaging applications.Article Citation - WoS: 7Citation - Scopus: 9A Screen-Printed Electrode Modified With Gold Nanoparticles/ Cellulose Nanocrystals for Electrochemical Detection of 4,4'-methylene Diphenyl Diamine(Elsevier, 2023) Büyüktaş, Duygu; Ghaani, Masoud; Rovera, Cesare; Carullo, Daniele; Olsson, Richard T.; Korel, Figen; Farris, StefanoDeveloping simple, cost-effective, easy-to-use, and reliable analytical devices if of utmost importance for the food industry for rapid in-line checks of their products that must comply with the provisions set by the current legislation. The purpose of this study was to develop a new electrochemical sensor for the food packaging sector. More specifically, we propose a screen -printed electrode (SPE) modified with cellulose nanocrystals (CNCs) and gold nanoparticles (AuNPs) for the quantification of 4,4'-methylene diphenyl diamine (MDA), which is one of the most important PAAs that can transfer from food packaging materials into food stuffs. The electrochemical performance of the proposed sensor (AuNPs/CNCs/SPE) in the presence of 4,4'- MDA was evaluated using cyclic voltammetry (CV). The modified AuNPs/CNCs/SPE showed the highest sensitivity for 4,4'-MDA detection, with a peak current of 9.81 mu A compared with 7.08 mu A for the bare SPE. The highest sensitivity for 4,4'-MDA oxidation was observed at pH = 7, whereas the detection limit was found at 57 nM and the current response of 4,4'-MDA rose linearly as its concentration increased from 0.12 mu M to 100 mu M. Experiments using real packaging materials revealed that employing nanoparticles dramatically improved both the sensitivity and the selectivity of the sensor, which can be thus considered as a new analytical tool for quick, simple, and accurate measurement of 4,4 '-MDA during converting operations.Article Citation - WoS: 9Citation - Scopus: 8Development of a New Electrochemical Sensor Based on Molecularly Imprinted Biopolymer for Determination of 4,4'-methylene Diphenyl Diamine(MDPI, 2023) Ghaani, Masoud; Büyüktaş, Duygu; Carullo, Daniele; Farris, StefanoA new molecularly imprinted electrochemical sensor was proposed to determine 4,4' methylene diphenyl diamine (MDA) using molecularly imprinted polymer-multiwalled carbon nanotubes modified glassy carbon electrode (MIP/MWCNTs/GCE). GCE was coated by MWCNTs (MWCNTs/GCE) because of their antifouling qualities and in order to improve the sensor sensitivity. To make the whole sensor, a polymeric film made up of chitosan nanoparticles was electrodeposited by the cyclic voltammetry method on the surface of MWCNTs/GCE in the presence of MDA as a template. Different parameters such as scan cycles, elution time, incubation time, molar ratio of template molecules to functional monomers, and pH were optimized to increase the performance of the MIP sensor. With a detection limit of 15 nM, a linear response to MDA was seen in the concentration range of 0.5-100 mu M. The imprinting factor (IF) of the proposed sensor was also calculated at around 3.66, demonstrating the extremely high recognition performance of a MIP/MWCNT-modified electrode. Moreover, the sensor exhibited good reproducibility and selectivity. Finally, the proposed sensor was efficiently used to determine MDA in real samples with satisfactory recoveries ranging from 94.10% to 106.76%.