Photonics / Fotonik

Permanent URI for this collectionhttps://hdl.handle.net/11147/2590

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Author: search.filters.author.Çevik Eren, MerveSubject: search.filters.subject.BODIPY

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  • Article
    Citation - WoS: 4
    Citation - Scopus: 4
    A Cyclopalladated Bodipy Construct as a Fluorescent Probe for Carbon Monoxide
    (Wiley, 2022) Çevik Eren, Merve; Eren, Ahmet; Tütüncü, Büşra Buse; Tütüncü, Büşra Buse; Emrullahoğlu, Mustafa; Dartar, Suay; Emrullahoğlu, Mustafa; 04.01. Department of Chemistry; 04.04. Department of Photonics; 01. Izmir Institute of Technology; 04. Faculty of Science
    By introducing a palladium ion into the backbone of BODIPY, we devised a cyclopalladated BODIPY construct that was almost non-emissive in the absence of any analyte but became highly fluorescent upon interacting with carbon monoxide (CO) in solution and in living cells. A process of ortho-carbonylation and depalladation mediated by the specific binding of CO to palladium, promoted the release of the heavy atom from the fluorophore and consequently generated a fluorescence signal with an exceptionally high (60-fold) enhancement ratio.