Photonics / Fotonik

Permanent URI for this collectionhttps://hdl.handle.net/11147/2590

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Author: search.filters.author.Demir, Mustafa MuammerPublisher: search.filters.publisher.Elsevier Ltd.

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  • Article
    Citation - WoS: 30
    Citation - Scopus: 32
    Perylene-Embedded Electrospun Ps Fibers for White Light Generation
    (Elsevier Ltd., 2019) Güner, Tuğrul; Aksoy, Erkan; Demir, Mustafa Muammer; Varlıklı, Canan
    Perylene dyes have been employed in the fabrication of white light due to their superior photophysical properties and relatively easy synthetic methods. However, their molecular aggregation in solid state is one of the main handicaps since it causes deviation in their optical properties and quenches photoluminescence quantum yields (Phi(f)). Investigation of the photophysical properties of a green (PTE), a yellow (PDI) and a new red (DiPhAPDI) emitting perylene derivative in solution, drop-casted films, polystyrene (PS) fibers and PS fibers embedded in poly (dimethyl siloxane) (PDMS) showed that PS:dye fibers prevent aggregation to some extend and allows high Of of dyes. The Of values of PTE, PDI and DiPhAPDI were all higher than 93.0% in solution and 84.8%, 94.3% and 73.6%, respectively in PS:dye fibers. Embedding the fibers in PDMS improved the photostabilities of the dyes two folds compared to their solution phases. The prepared dye containing fibers were combined together into a single PDMS film and utilized as a frequency conversion layer on a blue LED. Fabricated samples were found to show high color rendering index (>= 90), adjustable CCT (7500 K-5000 K), and power efficiency values exceeding 2001m/W depending on the used fiber amount in mass.
  • Article
    Citation - WoS: 21
    Citation - Scopus: 27
    Increasing Solubility of Metal Silicates by Mixed Polymeric Antiscalants
    (Elsevier Ltd., 2019) Topçu, Gökhan; Çelik, Aslı; Kandemir, Ali; Baba, Alper; Şahin, Hasan; Demir, Mustafa Muammer
    The increase of silicate solubility is a big challenge for both hot and cold water because it reduces the deposition of metal silicates frequently observed in such systems and causes operational obstacles. The deposition of silicate coats the inner surface of the pipelines in an uncontrolled manner and reduces the harvesting of energy from brines. In this work, the solubility performance of two commercial water-soluble polymeric agents (poly(ethylene glycol) (PEG) and poly(vinyl alcohol) (PVA)) of various molecular weights employing dosage from 25 to 100 mg/L was examined. Along with dispersant-type antiscalant, poly(acrylamide) (PAM), poly(vinylsulfonic acid, sodium salt) (PVSA), and poly(vinylphosphonic acid) (PVPA) having chelating acidic groups were employed. Metal silicate deposits were obtained artificially in the lab-scale pressurized reactor. The experimental conditions employed were quite similar to a model power plant located in Çanakkale, Turkey. The concentration of dissolved silica was increased from 130 to 420 mg/L when 100 mg/L PEG 1500 and 25 mg/L PVSA were employed as a mixture. For the atomic-level understanding of the interaction of chelating groups with metal cations, DFT calculations were performed too.