Karabudak, Engin
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Karabudak, E
Karabudak, E.
Karabudak, E.
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enginkarabudak@iyte.edu.tr
Main Affiliation
04.01. Department of Chemistry
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Current Staff
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Sustainable Development Goals
1NO POVERTY
0
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2ZERO HUNGER
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3GOOD HEALTH AND WELL-BEING
1
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4QUALITY EDUCATION
4
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5GENDER EQUALITY
0
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6CLEAN WATER AND SANITATION
2
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7AFFORDABLE AND CLEAN ENERGY
12
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8DECENT WORK AND ECONOMIC GROWTH
3
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9INDUSTRY, INNOVATION AND INFRASTRUCTURE
10
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10REDUCED INEQUALITIES
0
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11SUSTAINABLE CITIES AND COMMUNITIES
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12RESPONSIBLE CONSUMPTION AND PRODUCTION
3
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13CLIMATE ACTION
5
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14LIFE BELOW WATER
1
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15LIFE ON LAND
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16PEACE, JUSTICE AND STRONG INSTITUTIONS
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Documents
18
Citations
503
h-index
11
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0
Scholarly Output
19
Articles
6
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12297/8220
Supervised MSc Theses
9
Supervised PhD Theses
2
WoS Citation Count
72
Scopus Citation Count
85
Patents
0
Projects
7
WoS Citations per Publication
3.79
Scopus Citations per Publication
4.47
Open Access Source
15
Supervised Theses
11
| Journal | Count |
|---|---|
| Acs Omega | 1 |
| Analytical Ultracentrifugation: Instrumentation, Software and Applications | 1 |
| Angewandte Chemie - International Edition | 1 |
| Applied Spectroscopy Reviews | 1 |
| Journal of Applied Electrochemistry | 1 |
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19 results
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Now showing 1 - 10 of 19
Doctoral Thesis Synthesis, Characterization, Optimization, and Electrochemical Analysis of Novel Multimetal Oxide Materials for Energy Applications(01. Izmir Institute of Technology, 2024) Karabudak, Engin; Aytekin, Ahmet; Karabudak, EnginSon zamanlarda, enerji ve enerjiye olan ihtiyaç gittikçe artmaktadır. Bu enerji ihtayacını karşılamak adına, araştırmacılar enerji ile ilintili malzemelerin elektrokimyasal özelliklerini ve kullanım alanlarını iyileştirmek için çalışmaktadırlar. Günümüzde, multimetal oksit malzemeler bataryada (lityum iyon batarya ve Ni tabanlı batarya), yarı iletkenlerde, suyu ayrıştırma çalışmalarında, yakıt hücrelerinde ve kataliz çalışmalarında geniş bir şekilde kullanılmaktadır. Bu tezde nikel hidroksit (alfa ve beta formu), üre parçalanması metoduyla sentezlenmiştir. Kobalt, çinko, alüminyum ve bakır katkılı Ni(OH)2 aynı metotla sentezlenmiştir. Bu katkılı nikel hidroksitlerin elektrokimyasal analizi yapılmış ve karakterize edilmiştir. Nikel hidroksit kapasitesini iyileştirmek için küçük bir hücre çalışması yapılmış ve optimizasyon çalışması yapılarak bazı etkiler (c rate, tutkal etkisi ve elektrolit etki) incelenmiştir. Ayrıca NMC katot malzemesi katı-hal yöntemi ile sentezlenmiş ve kapasite çalışması yapılmıştır. Çalışmada BSCF, Ag-BSCF ve yeni BSNF malzemeleri sol jel yöntemi ile sentezlenmiş ve karakterize edilmiştir. Ayrıca, perovskite sınıfında olup olmadıklarını belirlemek adına Goldschmidt tolerans faktörleri hesaplanmış ve tartışılmıştır. Tezde çeşitli metal tuzları (Cr, Co, Fe, Mn, Ni) kullanılarak basılabilir mürekkep hazırlanmıştır. Hazırlanmış olan basılabilir mürekkeplerin optimizasyon çalışması yapılmıştır. Bu mürekkeplerden yola çıkarak multimetal oksit katalizörleri sentezlenmiştir, bu da suyu ayrıştırarak hidrojen ve oksijen elde etme imkanı sunar. Son olarak, PbVO3CI malzemesi sentezlenmiş ve karakterize edilmiştir. Yarı iletkenliği, elektronik yapısı, dinamik kararlılığı (Born-Phonon) ve perovskite sınıfı özelliği ele alınmıştır. Tezde, irdelenen bu malzemeler ( özellikle Ag-BSCF, BSNF, PbVO3CI) solar hücrelerde, katı hal yakıt hücrelerinde (SOFC), bataryalarda, yarı iletken ve katalizör çalışmalarında kullanılabilme potansiyeline sahiptir.Doctoral Thesis Synthesis and Characterization of Novel Organometallic-Semicondutor Nanocomposit Photoelectrodes(Izmir Institute of Technology, 2022) Göl, Yusuf Emre; Karabudak, Engin; Karabudak, EnginStudies on novel electrochemical catalyst synthesis for efficient oxygen evolution reaction (OER) attract the attention of researchers. In general, changing of synthesis method and the doping metal affect the electrochemical activities of BSCF. In this work, silver doped Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF-Ag) perovskite structure is shown to be a better electrocatalyst for oxygen evolution reaction (OER) due to its lower overpotential and extended durability. BSCF structure was synthesized by the EDTA-citric acid method. Appropriate amount of Ba(NO3)2 and EDTA were dissolved 0.1 M NH4OH solution. Nitrate salts of other metals were dissolved in distilled water, then mixed with prepared Ba(NO3)2 solution. The mixture was stirred at 70 °C until gelation occurred. The gelled samples obtained were baked in a drying oven at 250 °C for 24 h before being calcined at 1000 °C for 12 h. To achieve a current density of 10 mA cm−2, BSCF-Ag has required an overpotential of 0.36 V, which is very low compared to BSCF. To determine the stability of BSCF-Ag, continuous chronopotentiometry tests were carried out for 5 h and at a constant current density of 10 mA cm−2. BSCF-Ag was characterized by XRD, SEM, and XPS. Recent advances in inkjet printing technology for applications relating to heterogeneous catalysis are presented. Catalysts lie at the heart of most chemical reactions where raw materials are converted to value-added products. Therefore, synthesis and immobilization of active catalysts in the reactor are of great importance. Inkjet printing is an additive manufacturing technology introduced recently as a useful method for the fabrication and application of catalysts as a class of functional materials. Inkjet printing provides special features which can be tailored to the design of high-efficient catalytic processes. This thesis presents an overview of the technology along with developments and challenges associated with the combination of inkjet printing and heterogeneous catalysis, such as ink preparation, thin-film properties and real-life applications.Article Citation - WoS: 7Citation - Scopus: 8Investigation of Oxygen Evolution Reaction Performance of Silver Doped Ba0.5sr0.5co0.8fe0.2o3-Delta Perovskite Structure(Springer, 2020) Göl, Emre Yusuf; Aytekin, Ahmet; Özkahraman, Ecem Ezgi; Karabudak, EnginStudies on novel electrochemical catalyst synthesis for efficient oxygen evolution reaction (OER) attract the attention of researchers. In general, changing of synthesis method and the doping metal affect the electrochemical activities of BSCF. In this work, silver doped Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF-Ag) perovskite structure is shown to be a better electrocatalyst for oxygen evolution reaction (OER) due to its lower overpotential and extended durability. BSCF structure was synthesized by the EDTA-citric acid method. Appropriate amount of Ba(NO3)(2) and EDTA were dissolved 0.1 M NH4OH solution. Nitrate salts of other metals were dissolved in distilled water, then mixed with prepared Ba(NO3)(2) solution. The mixture was stirred at 70 degrees C until gelation occurred. The gelled samples obtained were baked in a drying oven at 250 degrees C for 24 h before being calcined at 1000 degrees C for 12 h. To achieve a current density of 10 mA cm(-2), BSCF-Ag has required an overpotential of 0.36 V, which is very low compared to BSCF. To determine the stability of BSCF-Ag, continuous chronopotentiometry tests were carried out for 5 h and at a constant current density of 10 mA cm(-2). BSCF-Ag was characterized by XRD, SEM, and XPS.Master Thesis Developing Mobile, Electronic and Positioning Applications for Emergency Situations Inside the Hospital(Izmir Institute of Technology, 2018) Keskin, Özge Sevin; Sürmeli, Nur Başak; Karabudak, Engin; Karabudak, Engin; Sürmeli, Nur BaşakThe aim of this project is to prevent mortality by providing emergency response on time. The communication inside the hospital is provided via developing application for Android and Ios operating system. The content of application is suitable for everyone’s use. The emergency call button makes it easy to call, and if the button is disabled, the heart rate rhythm starts for emergency intervention. This application is associated with bluetooth low energy systems in terms of help to locate the patient. Beacon systems provide data transfer through bluetooth by this means location is detected without internet. The project will be tested primarily at the laboratory following these steps. If it succeeds statistically, the project will be tried at the Tepecik Education and Research Hospital. The success of the project will be reviewed depends on the scenarios in the hospital.Master Thesis Development of Multi Metal Oxide Photo-Electrodes for Energy Applications(Izmir Institute of Technology, 2020) Özkahraman, Ecem Ezgi; Karabudak, EnginWater splitting via artificial photosynthesis uses only sunlight and water to produce hydrogen and oxygen. Hydrogen can be used as a green energy source. To be able this reaction to occur there is a catalyst needed as reaction center. Platinum and Iridium are the state-of-art catalyst used for water splitting reactions. The goal of this study is to develop an earth abundant, highly stable and efficient catalyst as an alternative to noble metal catalysts. For this purpose, ABO3 type perovskites was chosen to study for their abundancy and proven electrochemical efficiencies. BSCF was chosen as the starting point of this study because it is known for its great catalytic activity compared to state-of-art catalysts such as Iridium Oxide. To enhance the stability and catalytic activity of synthesized perovskite oxides, several foreign atoms (dopants) were introduced to their structure from B-site. Each perovskite was synthesized by the EDTA-Citrate complexing Sol-Gel method. Also, for dopants, cost-efficient and electron conductive elements was chosen in each study. As HER catalysts, manganese, zinc, and copper were introduced to BSCF structure as dopant, while for OER, silver was used as a dopant. In this study, catalytic activities and stabilities were tested by electrochemical methods. All electrochemical measurements were performed in alkaline media by three-electrode configurations. Perovskite oxides were prepared by the coating of their inks on Ni foam substrates by drop coating for HER and OER activity measurements by electrochemical methods. For the bulk and surface characterization of synthesized perovskite oxide powders, SEM, XRD, XPS, and BET analysis was performed.Publication Mikroşekillenmiş Atr-ır Orta Kızılaltı Spektroskopi Tekniği ile Kan Ölçüm Cihazı Üretilmesi(2018) Karabudak, Engin; Özçelik, Serdar; Ergün, Armağan; Öztürk, Betül; Keskin, Özge Sevin; Çımrın, DilekProjemizden Mert Koç isimli öğrencimiz yüksek lisans tezini başarı ile sunmuş ve mezun olmuştur. Proje ile ilgili çalışmalarına doktora öğrencisi olarak devam etmektedir. ? Mert Koç ve Engin Karabudak?a ait ?History Of Spectroscopy And Modern Micromachined Disposable Si ATR-IR Spectroscopy? isimli makale ?Applied Spectroscopy Reviews? adlı dergide yayınlanmıştır. (Etki faktörü: 2.826) ? Bu projenin çıktısı olarak geliştirilen cihaz sayesinde; doktoru kan ölçümlerinden önce ve sonra ayrı ayrı görmek ve randevu almak ihtiyacını bu ölçümler için gereksiz kılacaktır. Böylece tıp doktorlarının, laborantların ve hastaların harcadıkları zamanı azaltacak ve hastanelerin sağlıklı hizmet vermesine yardımcı olacak, böylece hastanelerdeki personel masraflarını da azaltacaktır. ? Daha ucuz ve daha kaliteli bir yöntem olduğu için tüm hastalara rutin uygulanacak, toplum ve çevre sağlığını artıracak ve herkese uygulandığı için hastalığın erken tanısı konusunda yardımcı olacaktır. ? Yeni bir teknoloji olduğu için sistemin yurtdışına da satılma potansiyeli vardır. Dolayısıyla Türkiye?nin teknoloji tüketen ülke durumundan teknoloji üreten ülke modeline geçmesine yardımcı olacaktır. Türkiye?nin biyomedikal alanında rekabet potansiyelini artıracaktır. ? Mevcut bilim insanlarımızın bilimsel birikimlerini teknolojiye dönüştürerek bu konuda bir kültür oluşmasına yardımcı olacaktır.Master Thesis On the Pathway of Whole Blood Analysis by Portable Atr-Ir and Chemometrics(Izmir Institute of Technology, 2017) Koç, Mert; Karabudak, EnginCurrently, the number of patients per state hospital in Turkey is too high. Doctors need point of care(PoC) tests like blood analysis, to diagnose his/her patients. Patients is firstly examined by a doctor. If the doctor needs blood analysis, then patient gives blood to blood laboratory. After a certain time, the results are given to the patient and he/she meets with the doctor again to show the results. This causes too much time loss. In addition, these analyses are not performed in some small healthcare centers and cause extra time loss, which is another major problem in the health care system. Electrochemical, spectrophotometric and enzymatic analysis methods are mostly used for blood analysis. The sum of glucose, urea, triglycerides, cholesterol, albumin and total protein tests cost for 7TL. Blood samples are taken separately about 2-5ml volume for each test and preliminary procedures are required. On the other hand, ATR-IR spectrometry is a technique that does not require preliminary sample preparation, less sample volume, cheap and results in shorter time. Studies have been carried out in the literature which have shown positive results on glucose, urea, triglycerides, cholesterol, albumin and total protein in blood, plasma and serum using ATR technique. The six components in blood have importance in the diagnosis of a disease at the patient. The aim of this thesis is a preliminary study to determine the glucose, urea, triglyceride, cholesterol, albumin and total protein concentrations in 1 minute, 1 u of blood, using disposable crystals and less than 1 dollar in the doctor's room by direct analysis of the blood using ATR-IR spectrometry and using chemometrics algorithms to predict them from the spectral data.Article Citation - WoS: 47Citation - Scopus: 49Simultaneous Identification of Spectral Properties and Sizes of Multiple Particles in Solution With Subnanometer Resolution(John Wiley and Sons Inc., 2016) Karabudak, Engin; Brookes, Emre; Lesnyak, Vladimir; Gaponik, Nikolai; Eychmüller, Alexander; Walter, Johannes; Segets, Doris; Peukert, Wolfgang; Wohlleben, Wendel; Demeler, Borries; Cölfen, HelmutWe report an unsurpassed solution characterization technique based on analytical ultracentrifugation, which demonstrates exceptional potential for resolving particle sizes in solution with sub-nm resolution. We achieve this improvement in resolution by simultaneously measuring UV/Vis spectra while hydrodynamically separating individual components in the mixture. By equipping an analytical ultracentrifuge with a novel multi-wavelength detector, we are adding a new spectral discovery dimension to traditional hydrodynamic characterization, and amplify the information obtained by orders of magnitude. We demonstrate the power of this technique by characterizing unpurified CdTe nanoparticle samples, avoiding tedious and often impossible purification and fractionation of nanoparticles into apparently monodisperse fractions. With this approach, we have for the first time identified the pure spectral properties and band-gap positions of discrete species present in the CdTe mixture.Article Citation - WoS: 12Citation - Scopus: 13History of Spectroscopy and Modern Micromachined Disposable Si Atr-Ir Spectroscopy(Taylor and Francis Ltd., 2018) Koç, Mert; Karabudak, EnginIn this article, the historical development of spectroscopy is examined and the spectroscopy devices used today are described. Then, we focus on infrared (IR) spectroscopy, which cannot give valuable signal in aqueous solution. Attenuated total reflection (ATR)-IR technique solves the problem. In addition, we specifically mention newly developed disposable ATR-IR crystals and micromachined silicon (Si) ATR-IR. Disposable crystal systems and microfluidics systems can be integrated with existing miniature ATR analyzers. If the integration is successful, the technique might be used in biomedical measuring instruments, reactions' analyses, and ultra-high-pressure analyses.Master Thesis 3d-Printed Multiprobe Analysis System for Solar Fuel Research; Design, Fabrication and Testing(Izmir Institute of Technology, 2016) Harmanlı, İpek; Karabudak, Engin; Ebil, ÖzgençMethods of generating electricity with unlimited, clean and cheap energy from solar energy are tried to be investigated and developed in practical and theoretical academic fields. Especially, photocatalytic water splitting (PWS) systems have been identified as the main method in this study as well as in many studies due to the advantages provided by production of solar fuels from water. In this research, a study was carried out on the alternatives of the both used experimental set-up and used photocatalytic material for PWS systems. A study has been carried out on both the used experimental setup and the used photocatalytic material alternatives in PWS systems. As an alternative experimental setup that allows small volume analysis for PWS by Unisense gas microsensors, a mini photoreactor was designed using 3-D drawing and printing techniques and its usability was tested for PWS applications. Moreover, some characterization results for the electronic band structure and the band gap of the lead (II) trioxovanadate (V) chloride [PbVO3Cl] crystal, which was discovered by Eanes and co-workers in 2007 at IZTECH, was introduced in this study by not only theoretical (DFT approximations; LDA, GGA and HSE06) but also experimental (XRD, Diffuse Reflectance Method- Tauc Plot, Raman Spectroscopy, Four Probe) methods. Also, its estimated theoretical price and its potential for future application in tandem solar fuel device as a photoanode in combination with Si photocathode was calculated and discussed. The results showed that the designed mini photoreactor system is an open to development apparatus that is suitable for PWS, besides, PbVO3Cl has an "indirect transition" band structure and a band energy of ~ 2.2 eV. Although it did not give an effective result in PWS applications done by the designed mini photoreactor, it can be said that it is a semiconductor which is worth studying and developing in detail for other researches in this field due to the compatibility of its band energy amount and optical properties for PWS.