Dutta, Abhishek
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Dutta, A.
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abhishekdutta@iyte.edu.tr
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03.02. Department of Chemical Engineering
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Current Staff
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Sustainable Development Goals
1NO POVERTY
0
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2ZERO HUNGER
1
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3GOOD HEALTH AND WELL-BEING
0
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4QUALITY EDUCATION
1
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5GENDER EQUALITY
0
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6CLEAN WATER AND SANITATION
3
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7AFFORDABLE AND CLEAN ENERGY
4
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8DECENT WORK AND ECONOMIC GROWTH
1
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9INDUSTRY, INNOVATION AND INFRASTRUCTURE
4
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10REDUCED INEQUALITIES
0
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11SUSTAINABLE CITIES AND COMMUNITIES
1
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12RESPONSIBLE CONSUMPTION AND PRODUCTION
2
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13CLIMATE ACTION
3
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14LIFE BELOW WATER
1
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15LIFE ON LAND
1
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16PEACE, JUSTICE AND STRONG INSTITUTIONS
0
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17PARTNERSHIPS FOR THE GOALS
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Documents
92
Citations
1990
h-index
24
Documents
71
Citations
1632
Scholarly Output
20
Articles
16
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44747/3823
Supervised MSc Theses
0
Supervised PhD Theses
0
WoS Citation Count
96
Scopus Citation Count
110
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0
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0
WoS Citations per Publication
4.80
Scopus Citations per Publication
5.50
Open Access Source
14
Supervised Theses
0
| Journal | Count |
|---|---|
| Processes | 4 |
| ISIJ International | 2 |
| Chemical Engineering Journal | 2 |
| Heliyon | 1 |
| Ironmaking and Steelmaking | 1 |
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20 results
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Now showing 1 - 10 of 20
Editorial Citation - WoS: 1Citation - Scopus: 1Special Issue on “process Modeling in Pyrometallurgical Engineering”(MDPI, 2021) Saxen, Henrik; Ramirez-Argaez, Marco A.; Conejo, Alberto N.; Dutta, AbhishekThis Special Issue on “Process Modeling in Pyrometallurgical Engineering” consists of 39 articles, including two review papers, and covers a wide range of topics related to process development and analysis based on modeling in ironmaking, steelmaking, flash smelting, casting, rolling operations, etc. The approaches include small-scale experiments and experimental design, first-principles modeling, detailed modeling based on CFD or DEM, and statistical and machine-learning-based methods. In the following paragraphs the issue is briefly scanned, presenting the papers in the order roughly following the route from raw materials processing to rolling and heat treatment.Article Citation - WoS: 3Citation - Scopus: 3Numerical Study of Electrostatic Desalting: a Detailed Parametric Study(MDPI, 2022) Ramirez-Argaez, Marco A.; Abreú-López, Diego; Gracia-Fadrique, Jesús; Dutta, AbhishekA systematic process analysis was conducted to study the effect of the main variables in an industrial electrostatic desalter, such as electric field intensity, wash water content, droplet size, and oil viscosity, on the efficiency of the separation of water from oil. The analysis was assessed through an already published and validated CFD multiphase numerical model that considers the expression of the frequency of collisions as a function of the mentioned process variables. Additionally, the study allowed the formal optimization exercise of the operation to maximize the separation efficiency. The most significant variables were the initial water content and the electric field intensity, while the temperature (oil viscosity) had an effect to a lower extent. An increase in the electric field and temperature and a decrease in the water content improved the water separation from oil. Optimum values suggested from the factorial experimental design and the optimization implemented in this work indicated the use of an electric field of 3 kV/cm, water content of 3%, and an oil viscosity of 0.017 kg/ms. At the same time, the droplet size showed no significant effect under the conditions explored in this work.Article Fractionation of Guaiacyl and Syringyl-Lignin Units Using Organic Solvent Nanofiltration(Elsevier, 2026) Croes, Tim; Dutta, Abhishek; Van Aelst, Korneel; Sels, Bert; Van der Bruggen, Bart; Cornet, IrisA major obstacle to employing the full potential of lignin-based aromatics is the fractionation of the monomers present in lignin, specifically the separation of guaiacyl (G) and syringyl (S) units, which possess nearly identical molecular weights (196 Da versus 166 Da) and dimensions, and identical functional groups. Such similarities make their separation highly challenging using conventional techniques and are generally considered beyond the capabilities of size-based membrane processes. This study examines the feasibility of organic solvent nano-filtration for fractionation of guaiacyl and syringyl units, and how membrane and process parameters affect separation of these two molecules. Sixteen commercially available membranes were tested with methanol and ethyl acetate as solvents. The results demonstrate that, despite the extreme similarity of the solutes, selective separation is achievable and is primarily governed by membrane material and solvent selection rather than the pore size-based molecular weight cut-off. Polyimide-based solvent-resistant membranes exhibited the highest selectivity, with a maximum observed separation factor of 3.33 obtained using a DuraMemTM 500 membrane in methanol. These findings demonstrate the potential of nanofiltration to address previously unresolved separation challenges in lignin valorization and provide a basis for further process development.Article Citation - WoS: 5Citation - Scopus: 5Flat sheet metakaolin ceramic membrane for water desalination via direct contact membrane distillation(IWA Publishing, 2022) Zewdie, Tsegahun Mekonnen; Habtu, Nigus Gabbiye; Dutta, Abhishek; Van der Bruggen, BartHydrophobic metakaolin-based flat sheet membrane was developed via phase inversion and sintering technique and modified through 1H,1H,2H,2H-perfluorooctyltriethoxysilane grafting agents. The prepared membrane was characterized by different techniques such as XRD, FTIR, SEM, contact angle, porosity, and mechanical strength. Their results indicated that the wettability, structural, and mechanical properties of the prepared membrane confirm the suitability of the material for membrane distillation (MD) application. The prepared metakaolin-based flat sheet membrane acquired hydrophobic properties after surface modification with the water contact angle values of 113.2° to 143.3°. Afterward, the membrane performance was tested for different sodium chloride aqueous solutions (synthetic seawater) and various operating parameters (feed temperature, feed flow rate) using direct contact membrane distillation (DCMD). Based on the findings, the prepared membrane at metakaolin loading of 45 wt.% and sintered at 1,300 °C was achieved the best performance with >95% salt rejection and permeate flux of 6.58 + 0.3 L/m2 · h at feed temperature of 80 °C, feed concentration of 35 g/L, and feed flow rate of 60 L/h. It can be con-cluded that further optimization of membrane porosity, mechanical, and surface properties is required to maximize the permeate flux and salt rejection.Article Citation - WoS: 13Citation - Scopus: 17Characterization and Beneficiation of Ethiopian Kaolin for Use in Fabrication of Ceramic Membrane(IOP Publishing, 2021) Zewdie, Tsegahun Mekonnen; Prihatiningtyas, Indah; Dutta, Abhishek; Habtu, Nigus Gabbiye; Van der Bruggen, BartKaolin (china clay) is a rock material that is very rich in kaolinite. A kaolin ore from Debre Tabor, Ethiopia containing 59.2 wt% SiO2, 24.9 wt% Al2O3, 2.4 wt% Fe2O3, and 8.22 wt% loss on ignition (LOI) was physically beneficiated, chemically leached, and thermally treated for possible industrial use, especially for ceramic membrane fabrication. The leaching experiments were carried out using oxalic acid solutions as leaching reagents for the iron extraction process. The effect of acid concentration, reaction temperature, and contact time on iron leaching was investigated. It was determined that the rate of iron extraction increased with the oxalic acid concentration, leaching temperature, and contact time. A substantial reduction of iron oxide (2.4 to 0.36 wt%) from the raw kaolin was observed at operating conditions of 2.0 M oxalic acid, the temperature of 120 degrees C, and contact time of 120 min. A maximum kaolin whiteness index of 81.4% was achieved through this leaching process. Finally, the physically beneficiated, chemically leached, and thermally treated kaolin raw material was used to fabricate a low-cost kaolin-based ceramic membrane. After firing at 1100 degrees C the ceramic membrane was found to have a mass loss of 11.04 +/- 0.05%, water absorption of 8.9 +/- 0.4%, linear shrinkage of 14.5 +/- 0.05%. It was demonstrated to be chemically stable, having less than 3% mass loss in acid solution, and less than 1% mass loss in alkali solution. The newly developed membranes have thus properties comparable to commercial ceramic membranes.Article Citation - WoS: 5Citation - Scopus: 5Numerical Study of Electrostatic Desalting Process Based on Droplet Collision Time(MDPI, 2021) Ramirez-Argaez, Marco A.; Abreu-Lopez, Diego; Gracia-Fadrique, Jesus; Dutta, AbhishekThe desalting process of an electrostatic desalting unit was studied using the collision time of two droplets in a water-in-oil (W/O) emulsion based on force balance. Initially, the model was solved numerically to perform a process analysis and to indicate the effect of the main process parameters, such as electric field strength, water content, temperature (through oil viscosity) and droplet size on the collision time or frequency of collision between a pair of droplets. In decreasing order of importance on the reduction of collision time and consequently on the efficiency of desalting separation, the following variables can be classified such as moisture content, electrostatic field strength, oil viscosity and droplet size. After this analysis, a computational fluid dynamics (CFD) model of a biphasic water-oil flow was developed in steady state using a Eulerian multiphase framework, in which collision frequency and probability of coalescence of droplets were assumed. This study provides some insights into the heterogeneity of a desalination plant which highlights aspects of design performance. This study further emphasizes the importance of two variables as moisture content and intensity of electrostatic field for dehydrated desalination by comparing the simulation with the electrostatic field against the same simulation without its presence. The overall objective of this study is therefore to show the necessity of including complex phenomena such as the frequency of collisions and coalescence in a CFD model for better understanding and optimization of the desalting process from both process safety and improvement.Article Citation - WoS: 4Citation - Scopus: 5Numerical Study of Fluid Flow and Mixing in the Argon Oxygen Decarburization (aod) Process(Iron and Steel Institute of Japan, 2023) Cheng, Zhongfu; Wang, Yannan; Dutta, Abhishek; Blanpain, Bart; Guo, Muxing; Malfliet, AnneliesA three-dimensional (3D) model has been developed based on the Eulerian multiphase flow approach to investigate the fluid flow behavior and mixing efficiency in the multi-tuyere AOD process. The interphase forces, including drag force, lift force, virtual force, turbulent dispersion force, and wall lubrication force, were incorporated into this model. The model was used to simulate six-tuyere and seven-tuyere AOD processes. The phenomena of multi-jet penetration, bubble plume merging, 3D turbulent flow and mixing characteristics were considered. The results indicate that the bubble plume merging occurs in the upper part of the liquid bath, forming a typical plume cluster. The predicted penetration length for a single tuyere jet agrees well with the previous work. For the multi-jet system, the side jets penetrate deeper than the inside ones. The six-tuyere AOD has a good flow condition in the center of the liquid bath, while the seven-tuyere AOD has a better flow pattern in the sidewall region and the lower bath. Overall, the seven-tuyere AOD performs better in mixing efficiency than the six-tuyere AOD under the same gas flow rate. These findings increase the understanding of the AOD process, allowing further optimization of process parameters. This model can be further extended to incorporate the thermochemical reactions into the modeling of the AOD reactor.Article Citation - WoS: 6Citation - Scopus: 6Mathematical Modelling of the Liquid/Liquid Mass Transfer Behaviour in Gas Stirred Ladles(Taylor & Francis, 2022) Zhang, Han; Conejo, Alberto N.; Dutta, Abhishek; Ramírez-Argáez, Marco A.; Yan, HanA three-dimensional numerical model consistent with physical simulations (water/oil/thymol) has been developed to explore the mass transfer behaviour of sulphur. Euler-Lagrangian and Euler-Euler, were applied to simulate the multiphase flow; compared with experimental data, the Euler-Euler method was more accurate. The small eddy model was used for mass transfer calculations. As a new type of bottom stirring scheme, the effect of central-eccentric parallel injection on mass transfer was investigated. Moving the eccentric nozzle towards the sidewall or increasing the number of eccentric nozzles decreases the mass transfer rate at a constant total gas flow rate. The mass transfer rate increases with increasing central gas flow rate under the differential flow bottom stirring scheme. The single-nozzle central injection is still considered the most superior bottom-blowing scheme. The bubble diameter has an insignificant effect on the liquid–liquid mass transfer. The mass transfer rate of thymol is weakly accelerated with increasing bubble diameter.Article Citation - WoS: 1Citation - Scopus: 1Polynomial Approaches in Improving Accuracy of Probability Distribution Estimation Using the Method of Moments(Wiley, 2024) Turan, Meltem; Munkhammar, Joakim; Dutta, AbhishekBACKGROUNDDetermination of a probability density function (PDF) is an area of active research in engineering sciences as it can improve process systems. A previously developed polynomial method-of-moments-based PDF estimation model has been applied in the research to produce accurate approximations to both standard and more complex PDF. A model with a different polynomial basis than a monomial is still to be developed and evaluated. This is the work that is undertaken in this study.RESULTSA set of standard PDF (Normal, Weibull, Log Normal and Bimodal) and more complex distributions (solutions to the Smoluchowski coagulation equation and Population Balance equation) were approximated by the method-of-moments using Chebyshev, Hermite and Lagrange polynomial-based density functions. Results show that Lagrange polynomial-based models improve the fit compared to monomial based-modeling in terms of RMSE and Kolmogorov-Smirnov test statistic estimates. The Kolmogorov-Smirnov test-statistics decreased by 19% and the RMSE values were improved by around 85% compared to the standard monomial basis when using Lagrange polynomial basis.CONCLUSIONThis study indicates that the procedure using Lagrange polynomials with method-of-moments is a more reliable reconstruction procedure that calculates the approximate distribution using lesser number of moments, which is desirable. (c) 2024 The Authors. Journal of Chemical Technology and Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry (SCI).Article Citation - WoS: 11Citation - Scopus: 12Numerical Modelling Assisted Design of a Compact Ultrafiltration (uf) Flat Sheet Membrane Module(MDPI, 2021) Bopape, Mokgadi F.; Van Geel, Tim; Dutta, Abhishek; Van der Bruggen, Bart; Onyango, Maurice StephenThe increasing adoption of ultra-low pressure (ULP) membrane systems for drinking water treatment in small rural communities is currently hindered by a limited number of studies on module design. Detailed knowledge on both intrinsic membrane transport properties and fluid hydrodynamics within the module is essential in understanding ULP performance prediction, mass transfer analysis for scaling-up between lab-scale and industrial scale research. In comparison to hollow fiber membranes, flat sheet membranes present certain advantages such as simple manufacture, sheet replacement for cleaning, moderate packing density and low to moderate energy usage. In the present case study, a numerical model using computational fluid dynamics (CFD) of a novel custom flat sheet membrane module has been designed in 3D to predict fluid flow conditions. The permeate flux through the membrane decreased with an increase in spacer curviness from 2.81 L/m(2)h for no (0%) curviness to 2.73 L/m(2)h for full (100%) curviness. A parametric analysis on configuration variables was carried out to determine the optimum design variables and no significant influence of spacer inflow or outflow thickness on the fluid flow were observed. The numerical model provides the necessary information on the role of geometrical and operating parameters for fabricating a module prototype where access to technical expertise is limited.