Application of Inverse Gas Chromatography To the Measurement of Diffusion and Phase Equilibria in Polyacrylate-Solvent Systems
| dc.contributor.author | Tıhmınlıoğlu, Funda | |
| dc.contributor.author | Danner, Ronald P. | |
| dc.coverage.doi | 10.1016/S0021-9673(99)00258-7 | |
| dc.date.accessioned | 2016-04-19T11:23:56Z | |
| dc.date.available | 2016-04-19T11:23:56Z | |
| dc.date.issued | 1999 | |
| dc.description.abstract | The inverse gas chromatography technique (IGC) was used to determine the partition and diffusion coefficients of ethyl acetate and 2-ethylhexyl acrylate in polyacrylate for both infinite dilution and finite concentrations of solvent. Experiments were performed over a temperature range of 60 to 100°C, more than 100°C above the glass transition temperature of the polymer. The capillary column IGC model previously developed for determining partition and diffusion coefficients of infinitely dilute solvent has been modified to account for the concentration of the solvent in the polymer phase. Thermodynamic data obtained from retention theory and the modified capillary column IGC model are compared | en_US |
| dc.identifier.citation | Tıhmınlıoğlu, F., and Danner, R. P. (1999). Application of inverse gas chromatography to the measurement of diffusion and phase equilibria in polyacrylate-solvent systems. Journal of Chromatography A, 845(1-2), 93-101. doi:10.1016/S0021-9673(99)00258-7 | en_US |
| dc.identifier.doi | 10.1016/S0021-9673(99)00258-7 | en_US |
| dc.identifier.doi | 10.1016/S0021-9673(99)00258-7 | |
| dc.identifier.issn | 0021-9673 | |
| dc.identifier.scopus | 2-s2.0-0033045596 | |
| dc.identifier.uri | http://doi.org/10.1016/S0021-9673(99)00258-7 | |
| dc.identifier.uri | https://hdl.handle.net/11147/4519 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Ltd. | en_US |
| dc.relation.ispartof | Journal of Chromatography A | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Inverse gas chromatography | en_US |
| dc.subject | Diffusion coefficients | en_US |
| dc.subject | Partition coefficients | en_US |
| dc.subject | Thermodynamic parameters | en_US |
| dc.title | Application of Inverse Gas Chromatography To the Measurement of Diffusion and Phase Equilibria in Polyacrylate-Solvent Systems | en_US |
| dc.type | Article | en_US |
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| gdc.author.institutional | Tıhmınlıoğlu, Funda | |
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| gdc.description.department | İzmir Institute of Technology. Chemical Engineering | en_US |
| gdc.description.endpage | 101 | en_US |
| gdc.description.issue | 1-2 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| gdc.description.scopusquality | Q1 | |
| gdc.description.startpage | 93 | en_US |
| gdc.description.volume | 845 | en_US |
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| gdc.oaire.keywords | Inverse gas chromatography | |
| gdc.oaire.keywords | Partition coefficients | |
| gdc.oaire.keywords | Thermodynamic parameters | |
| gdc.oaire.keywords | Diffusion coefficients | |
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