Selective Catalytic Hydrogenation of Cellulose Into Sorbitol With Ru-Based Catalysts
| dc.contributor.author | Orak, Ceren | |
| dc.contributor.author | Sapmaz, Aycan | |
| dc.contributor.author | Yüksel, Aslı | |
| dc.date.accessioned | 2022-07-28T13:34:05Z | |
| dc.date.available | 2022-07-28T13:34:05Z | |
| dc.date.issued | 2022 | |
| dc.description | This study was financially supported through the projects of both the Scientific and Technological Research Council of Turkey-TUBITAK (Project No. 217M931) and İzmir Institute of Technology Scientific Research Projects Coordination Unit (Project No. 2016IYTE42). | en_US |
| dc.description.abstract | Sorbitol is one of the platform chemicals and can be produced from various renewable and sustainable sources via different processes. Hydrothermal liquefaction is an effective and promising approach to produce sorbitol, since the subcritical reaction media and appropriate catalysts provide a selective production of platform chemicals. In this study, sorbitol was produced from different renewable sources (cellulose and glucose) in the presence of Ru-based catalysts (Ru/SiO2, Ru/AC, Ru/SBA-15, and Ru/SBA-15-SO3) under subcritical conditions. The highest cellulose conversion was achieved as 90% in the presence of Ru/SBA-15-SO3 for 1 h of reaction duration. The highest sorbitol yield (%) by hydrothermal liquefaction of cellulose was obtained as 6.2% by using Ru/AC for 1 h of reaction duration. A total of 99.9% of glucose conversion was achieved in the presence of all catalysts. The highest sorbitol yield (%) by hydrothermal liquefaction of glucose was found as 3.8% for 1 h of reaction duration. Owing to the results of GC-MS analysis, the intermediate products were identified, and, thus, a reaction pathway was proposed. | en_US |
| dc.identifier.doi | 10.55730/1300-0527.3318 | |
| dc.identifier.issn | 1300-0527 | en_US |
| dc.identifier.issn | 1300-0527 | |
| dc.identifier.issn | 1303-6130 | |
| dc.identifier.scopus | 2-s2.0-85129318367 | |
| dc.identifier.uri | https://doi.org/10.55730/1300-0527.3318 | |
| dc.identifier.uri | https://hdl.handle.net/11147/12220 | |
| dc.identifier.uri | https://search.trdizin.gov.tr/yayin/detay/530446 | |
| dc.language.iso | en | en_US |
| dc.publisher | TÜBİTAK | en_US |
| dc.relation | Selülozun sıcak-basınçlı su ortamında değerli kimyasallara seçici dönüştürülmesi için katalizör geliştirilmesi | tr |
| dc.relation | Bifonksiyonel Katalizör ile Selilozun Sorbitole Seçici Katalitik Hidrotermal Elektrolizi | tr |
| dc.relation.ispartof | Turkish Journal of Chemistry | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Cellulose acetate | en_US |
| dc.subject | Hydrothermal liquefaction | en_US |
| dc.subject | Ru-based catalysts | en_US |
| dc.subject | Sorbitol | en_US |
| dc.title | Selective Catalytic Hydrogenation of Cellulose Into Sorbitol With Ru-Based Catalysts | en_US |
| dc.type | Article | en_US |
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| gdc.author.id | 0000-0002-0058-6297 | en_US |
| gdc.author.id | 0000-0002-9273-2078 | en_US |
| gdc.author.institutional | Orak, Ceren | |
| gdc.author.institutional | Sapmaz, Aycan | |
| gdc.author.institutional | Yüksel, Aslı | |
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| gdc.contributor.affiliation | Izmir Institute of Technology | en_US |
| gdc.contributor.affiliation | Izmir Institute of Technology | en_US |
| gdc.contributor.affiliation | Izmir Institute of Technology | en_US |
| gdc.description.department | İzmir Institute of Technology. Chemical Engineering | en_US |
| gdc.description.endpage | 445 | en_US |
| gdc.description.issue | 2 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| gdc.description.scopusquality | Q3 | |
| gdc.description.startpage | 434 | en_US |
| gdc.description.volume | 46 | en_US |
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| gdc.identifier.pmid | 38143466 | |
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