Fructose Dehydration To 5-Hydroxymethylfurfural Over Sulfated Tio2-Sio2, Ti-Sba Zro2, Sio2, and Activated Carbon Catalysts
| dc.contributor.author | Kılınç, Emre | |
| dc.contributor.author | Yılmaz, Selahattin | |
| dc.coverage.doi | 10.1021/acs.iecr.5b00628 | |
| dc.date.accessioned | 2017-07-07T13:49:12Z | |
| dc.date.available | 2017-07-07T13:49:12Z | |
| dc.date.issued | 2015 | |
| dc.description.abstract | Different sulfated catalysts including SO4/TiO2-SiO2, SO4/Ti-SBA-15, SO4/ZrO2, SO4/AC, and SO4/SiO2 were tested in fructose dehydration to 5-hydroxymethylfurfural (HMF). Reactions were carried out in dimethyl sulfoxide (DMSO) at 110 °C. Characterization results indicated that no sulfur leaching was observed from SO4/ZrO2, SO4/TiO2-SiO2, and SO4/Ti-SBA-15 catalysts in the reaction tests. The SO4/TiO2-SiO2 catalyst had a high amount of strong acid sites and the highest amount of Bronsted sites. The highest selectivity to HMF at high conversion, that is, 89% selectivity at 77% fructose conversion was obtained over this catalyst. It preserved its activity after four times reuse.Activated carbonCarbonCatalystsDehydration | en_US |
| dc.identifier.citation | Kılıç, E., and Yılmaz, S. (2015). Fructose dehydration to 5-hydroxymethylfurfural over sulfated TiO2-SiO2, Ti-SBA-15, ZrO2, SiO2, and activated carbon catalysts. Industrial and Engineering Chemistry Research, 54(19), 52209-5225. doi:10.1021/acs.iecr.5b00628 | en_US |
| dc.identifier.doi | 10.1021/acs.iecr.5b00628 | en_US |
| dc.identifier.doi | 10.1021/acs.iecr.5b00628 | |
| dc.identifier.issn | 0888-5885 | |
| dc.identifier.issn | 1520-5045 | |
| dc.identifier.scopus | 2-s2.0-84930225823 | |
| dc.identifier.uri | https://doi.org/10.1021/acs.iecr.5b00628 | |
| dc.identifier.uri | https://hdl.handle.net/11147/5895 | |
| dc.language.iso | en | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.relation.ispartof | Industrial and Engineering Chemistry Research | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Activated carbon | en_US |
| dc.subject | Catalysts | en_US |
| dc.subject | Dehydration | en_US |
| dc.subject | Catalyst selectivity | en_US |
| dc.subject | Dimethyl sulfoxide | en_US |
| dc.subject | Organic solvents | en_US |
| dc.title | Fructose Dehydration To 5-Hydroxymethylfurfural Over Sulfated Tio2-Sio2, Ti-Sba Zro2, Sio2, and Activated Carbon Catalysts | en_US |
| dc.type | Article | en_US |
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| gdc.author.institutional | Kılınç, Emre | |
| gdc.author.institutional | Yılmaz, Selahattin | |
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| gdc.description.department | İzmir Institute of Technology. Civil Engineering | en_US |
| gdc.description.endpage | 5225 | en_US |
| gdc.description.issue | 19 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
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| gdc.description.startpage | 5220 | en_US |
| gdc.description.volume | 54 | en_US |
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| gdc.oaire.keywords | Catalyst selectivity | |
| gdc.oaire.keywords | Organic solvents | |
| gdc.oaire.keywords | Catalysts | |
| gdc.oaire.keywords | Dehydration | |
| gdc.oaire.keywords | Activated carbon | |
| gdc.oaire.keywords | Dimethyl sulfoxide | |
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