Synthesis, Structural Characterization, and Magnetic Properties of Nare9(geo4)(6)o-2 (re=nd, Pr)
| dc.contributor.author | Eanes, Mehtap | |
| dc.contributor.author | Emirdağ Eanes, Mehtap | |
| dc.contributor.author | Pennington, WT | |
| dc.contributor.author | Kolis, JW | |
| dc.contributor.other | 04.01. Department of Chemistry | |
| dc.contributor.other | 04. Faculty of Science | |
| dc.contributor.other | 01. Izmir Institute of Technology | |
| dc.coverage.doi | 10.1016/S0925-8388(03)00725-4 | |
| dc.date.accessioned | 2021-01-24T18:28:24Z | |
| dc.date.available | 2021-01-24T18:28:24Z | |
| dc.date.issued | 2004 | |
| dc.description.abstract | The new compounds NaRE9(GeO4)(6)O-2 (RE = Nd, Pr) have been synthesized at 500 and 524 degreesC, respectively, via the hydrothermal method. The compounds crystallize with an oxyapatite structure in the hexagonal space group P6(3)/m with one formula unit in a cell of dimensions a = 9.782(1) Angstrom, c = 7.083(1) Angstrom (T = 293 K), V = 587.0(2) Angstrom(3) for RE = Nd and a = 9.802(1) Angstrom, c = 7.116(1) Angstrom (T = 293 K), V = 592.1(2) Angstrom(3) for RE = Pr. Each structure is composed of REO7 and REO9 polyhedra as well as GeO4 tetrahedra. The magnetic susceptibility data indicates paramagnetic behavior for both compounds at temperatures between 60-300 K for Nd and 2-300 K for Pr with a Weiss constant of theta = 44.8 and 33.5 K for Nd and Pr, respectively. (C) 2003 Elsevier B.V. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/S0925-8388(03)00725-4 | |
| dc.identifier.issn | 0925-8388 | |
| dc.identifier.uri | https://doi.org/10.1016/S0925-8388(03)00725-4 | |
| dc.identifier.uri | https://hdl.handle.net/11147/9751 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Ltd. | en_US |
| dc.relation.ispartof | Journal of Alloys and Compounds | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | hydrothermal | en_US |
| dc.subject | crystal structure | en_US |
| dc.subject | germanate | en_US |
| dc.subject | oxyapatite | en_US |
| dc.subject | rare earths | en_US |
| dc.title | Synthesis, Structural Characterization, and Magnetic Properties of Nare9(geo4)(6)o-2 (re=nd, Pr) | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| gdc.author.institutional | Eanes, Mehtap | |
| gdc.bip.impulseclass | C5 | |
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| gdc.coar.access | metadata only access | |
| gdc.coar.type | text::journal::journal article | |
| gdc.collaboration.industrial | false | |
| gdc.description.department | İzmir Institute of Technology. Chemistry | en_US |
| gdc.description.departmenttemp | Clemson Univ, Hunter Res Lab, Dept Chem, Clemson, SC 29634 USA | en_US |
| gdc.description.endpage | 80 | en_US |
| gdc.description.issue | 01.Feb | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| gdc.description.scopusquality | Q1 | |
| gdc.description.startpage | 76 | en_US |
| gdc.description.volume | 366 | en_US |
| gdc.description.wosquality | Q1 | |
| gdc.identifier.openalex | W1487688982 | |
| gdc.identifier.wos | WOS:000189081000017 | |
| gdc.index.type | WoS | |
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| gdc.oaire.sciencefields | 02 engineering and technology | |
| gdc.oaire.sciencefields | 0210 nano-technology | |
| gdc.oaire.sciencefields | 01 natural sciences | |
| gdc.oaire.sciencefields | 0104 chemical sciences | |
| gdc.openalex.collaboration | International | |
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| gdc.opencitations.count | 22 | |
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