Influence of Swelling and Diffusion-Induced Convection on Polymer Sorption Processes
| dc.contributor.author | Alsoy Altınkaya, Sacide | |
| dc.contributor.author | Duda, John Larry | |
| dc.coverage.doi | 10.1002/aic.690480903 | |
| dc.date.accessioned | 2016-05-13T08:56:02Z | |
| dc.date.available | 2016-05-13T08:56:02Z | |
| dc.date.issued | 2002 | |
| dc.description.abstract | Unsteady-state sorption of a vapor or liquid by a polymer is modeled to include the influence of the moving phase boundary associated with the polymer swelling and diffusion-induced convection. A formulation presented clearly elucidates the influence of these two effects on the overall sorption process. Numerical solutions of the model equations indicate the errors that can be induced when swelling or convection are neglected. For most polymer-solvent systems, the influence of the diffusion-induced convection associated with volume changes in mixing can be neglected in the analysis of sorption processes. In contrast, the correction for the moving boundary or swelling of the polymer phase can be quite significant, particularly when a large step change in solvent concentration is considered. | en_US |
| dc.identifier.citation | Alsoy, S., and Duda, J. L. (2002). Influence of swelling and diffusion-induced convection on polymer sorption processes. AIChE Journal, 48(9), 1849-1855. doi:10.1002/aic.690480903 | en_US |
| dc.identifier.doi | 10.1002/aic.690480903 | en_US |
| dc.identifier.doi | 10.1002/aic.690480903 | |
| dc.identifier.issn | 0001-1541 | |
| dc.identifier.issn | 0001-1541 | |
| dc.identifier.issn | 1547-5905 | |
| dc.identifier.scopus | 2-s2.0-0036769006 | |
| dc.identifier.uri | http://doi.org/10.1002/aic.690480903 | |
| dc.identifier.uri | https://hdl.handle.net/11147/4638 | |
| dc.language.iso | en | en_US |
| dc.publisher | John Wiley and Sons Inc. | en_US |
| dc.relation.ispartof | AICHE Journal | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Sorption | en_US |
| dc.subject | Phase boundaries | en_US |
| dc.subject | Diffusion | en_US |
| dc.subject | Organic solvents | en_US |
| dc.subject | Polymer | en_US |
| dc.subject | Swelling | en_US |
| dc.title | Influence of Swelling and Diffusion-Induced Convection on Polymer Sorption Processes | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
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| gdc.author.id | 0000-0002-7049-7425 | en_US |
| gdc.author.institutional | Alsoy Altınkaya, Sacide | |
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| gdc.description.department | İzmir Institute of Technology. Chemical Engineering | en_US |
| gdc.description.endpage | 1855 | en_US |
| gdc.description.issue | 9 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
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| gdc.description.startpage | 1849 | en_US |
| gdc.description.volume | 48 | en_US |
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| gdc.oaire.keywords | Diffusion | |
| gdc.oaire.keywords | Organic solvents | |
| gdc.oaire.keywords | Phase boundaries | |
| gdc.oaire.keywords | Sorption | |
| gdc.oaire.keywords | Polymer | |
| gdc.oaire.keywords | Swelling | |
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