Microporous Carbon Spheres for the Enrichment of Lead From Water Samples With Determination by Microsample Injection System - Flame Atomic Absorption Spectrometry (MIS-FAAS)

Abstract

Microporous carbon spheres (MCSs) are advanced materials known for their high surface area, well-developed pore structure, low density, and rapid molecular diffusion, making them highly effective in solid-phase extraction (SPE) and other applications. In this study, MCSs synthesized from previously reported resorcinol-formaldehyde resin were employed as an adsorbent for the extraction and preconcentration of Pb(II) ions. The material was comprehensively characterized to confirm its suitability for adsorption applications. The adsorption and desorption behavior of MCSs toward lead ions was systematically examined under optimized conditions, including pH, eluent volume, eluent type, eluent concentration, and sample volume. Microinjection microsample injection system-flame atomic absorption spectrometry (MIS-FAAS) was used for the determination of lead ions. Experimental results from batch experiments showed that the MCSs exhibited a maximum adsorption capacity of 37.31 mg g-1. Under optimal conditions (pH 8.0, 1.0 mL of 0.1 M HNO3 eluent, and 10 mg of adsorbent), a preconcentration factor of 100 was achieved, with recovery values exceeding 90%. The method exhibited a limit of detection (LOD) of 0.73 mu g L-1. The developed method was successfully applied to real water samples, including tap water, entering industrial wastewater, and exiting industrial wastewater, confirming its potential for use in environmental monitoring and contamination control.