Esterification of Cetyl Alcohol With Palmitic Acid Over Wo3/Zr-sba-15 and Zr-Sba Catalysts
| dc.contributor.author | Mutlu, Nahide Nuran | |
| dc.contributor.author | Yılmaz, Selahattin | |
| dc.coverage.doi | 10.1016/j.apcata.2016.05.010 | |
| dc.date.accessioned | 2017-08-23T13:51:24Z | |
| dc.date.available | 2017-08-23T13:51:24Z | |
| dc.date.issued | 2016 | |
| dc.description.abstract | Tungsten loaded and Zr incorporated SBA-15 catalysts (WO3/Zr-SBA-15 and Zr-SBA-15) were developed for esterification of cetyl alcohol and palmitic acid. The influence of the Zr content, tungsten loading amount, calcination temperature, feed composition and catalyst amount has been studied. Higher tungsten loading decreased the acidity due to formation of WO3 crystals whereas calcination temperature enhanced the acidity by favoring the dispersion of WOx species. Activities of the catalyst changed depending on their amount of Brønsted sites and total number of acid sites. Zr-SBA-15 catalyst which had the highest amount of Brønsted acid sites gave maximum cetyl palmitate yield (63.1%). This catalyst retained its activity up to 3 reuse cycles without significant loss of activity. | en_US |
| dc.description.sponsorship | Scientific and Technological Research Council of Turkey (TUBITAK MAG 112M701) | en_US |
| dc.identifier.citation | Mutlu, N. N., and Yılmaz, S. (2016). Esterification of cetyl alcohol with palmitic acid over WO3/Zr-SBA-15 and Zr-SBA-15 catalysts. Applied Catalysis A: General, 522, 194-200. doi:10.1016/j.apcata.2016.05.010 | en_US |
| dc.identifier.doi | 10.1016/j.apcata.2016.05.010 | |
| dc.identifier.doi | 10.1016/j.apcata.2016.05.010 | en_US |
| dc.identifier.issn | 0926-860X | |
| dc.identifier.scopus | 2-s2.0-84970028521 | |
| dc.identifier.uri | http://doi.org/10.1016/j.apcata.2016.05.010 | |
| dc.identifier.uri | https://hdl.handle.net/11147/6173 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Ltd. | en_US |
| dc.relation | info:eu-repo/grantAgreement/TUBITAK/MAG/112M701 | en_US |
| dc.relation.ispartof | Applied Catalysis A: General | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Cetyl alcohol | en_US |
| dc.subject | Cetyl palmitate | en_US |
| dc.subject | Esterification | en_US |
| dc.subject | Mesoporous acid catalysts | en_US |
| dc.subject | Tungsten loaded | en_US |
| dc.subject | Palmitic acid | en_US |
| dc.title | Esterification of Cetyl Alcohol With Palmitic Acid Over Wo3/Zr-sba-15 and Zr-Sba Catalysts | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| gdc.author.institutional | Mutlu, Nahide Nuran | |
| gdc.author.institutional | Yılmaz, Selahattin | |
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| gdc.description.department | İzmir Institute of Technology. Chemical Engineering | en_US |
| gdc.description.endpage | 200 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| gdc.description.scopusquality | Q2 | |
| gdc.description.startpage | 194 | en_US |
| gdc.description.volume | 522 | en_US |
| gdc.description.wosquality | Q2 | |
| gdc.identifier.openalex | W2391104075 | |
| gdc.identifier.wos | WOS:000379369800022 | |
| gdc.index.type | WoS | |
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| gdc.oaire.keywords | Cetyl alcohol | |
| gdc.oaire.keywords | Esterification | |
| gdc.oaire.keywords | Palmitic acid | |
| gdc.oaire.keywords | Mesoporous acid catalysts | |
| gdc.oaire.keywords | Tungsten loaded | |
| gdc.oaire.keywords | Cetyl palmitate | |
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