Environmental Engineering / Çevre Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/4321
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Article Citation - WoS: 40Citation - Scopus: 47Boron in Geothermal Energy: Sources, Environmental Impacts, and Management in Geothermal Fluid(Elsevier, 2022) Mott, A.; Baba, Alper; Hadi Mosleh, Mojgan; Ökten, Hatice Eser; Babaei, Masoud; Gören, Ayşegül Yağmur; Feng, C.; Recepoğlu, Yaşar Kemal; Uzelli, Taygun; Uytun, Hüseyin; Morata, Diego; Yüksel Özşen, AslıThe problem of hazardous chemicals in geothermal fluid is a critical environmental concern in geothermal energy developments. Boron is among the hazardous contaminants reported to be present at high concentrations in geothermal fluids in various countries. Poor management and inadequate treatment of geothermal fluids can release excessive boron to the environment that has toxic effects on plants, humans, and animals. Despite the importance of boron management in geothermal fluid, limited and fragmented resources exist that provide a comprehensive understanding of its sources, transport and fate, and the treatment strategies in geothermal energy context. This paper presents the first critical review from a systematic and comprehensive review on different aspects of boron in geothermal fluid including its generation, sources, toxicity, ranges and the management approaches and treatment technologies. Our research highlights the origin of boron in geothermal water to be mainly from historical water-rock interactions and magmatic intrusion. Excessive concentrations of boron in geothermal fluids have been reported (over 500 mg/L in some case studies). Our review indicated that possible boron contamination in geothermal sites are mostly due to flawed construction of production/re-injection wells and uncontrolled discharge of geothermal water to surface water. The dominancy of non-ionic H3BO3 species makes the selection of the suitable treatment method for geothermal waters limited. Combining boron selective resins and membrane technologies, hybrid systems have provided effluents suitable for irrigation. However, their high energy consumption and course structure of boron selective resins encourage further research to develop cost-effective and environmentally friendly alternatives.Article Citation - WoS: 5Citation - Scopus: 7Effect of High Salinity and Temperature on Water-Volcanic Rock Interaction(Springer, 2021) Gören, Ayşegül Yağmur; Gören, Ayşegül Yağmur; Topçu, Gökhan; Demir, Mustafa Muammer; Demir, Mustafa M.; Baba, Alper; Baba, AlperIn order to understand the processes occurring in natural hydrothermal systems, it was carried out a series of water-volcanic rock interaction studies in the laboratory and an intermediate volcanic rock samples from geothermal production wells in Tuzla geothermal field (TGF) in western Turkey. A high-pressure autoclave was used to conduct water-rock interaction experiments under similar conditions of the field. Rainwater and seawater were treated with volcanic rocks at 140 degrees C (reservoir temperature) and 4.5 bar pressure. The change in the ionic content of the resulting fluids was examined in terms of the type of volcanic rocks and mineral saturation index. The results indicate that talc and diopside minerals in geothermal systems may cause scaling at high temperatures depending on the geothermal fluid and pH.Article İzotop Özelliklerinin Kullanılarak Su-kayaç Etkileşiminin İncelenmesi: Alaşehir Alt Havzası Örneği(DSİ, 2019) Tonkul, Serhat; Şimşek, Celalettin; Baba, AlperYeraltı su kaynakları yenilenebilir kaynaklar olmasına karşın, havzalarda aşırı çekim baskısı nedeniyle akiferlerde yeterince depolanamamakta ve depolama rezervi sürekli olarak azalmaktadır. Bu bağlamda son yıllarda yeraltısuyunun sürdürülebilir verimliliğinin arttırılması için kalite ve miktarın belirlenmesine yönelik olarak yüzey ve yeraltısuyu sistemleri arasındaki ilişkinin detaylı olarak çalışılmasına ihtiyaç duyulmuştur. Yüzey ve yeraltısuları arasındaki ilişkinin ortaya konulmasında en çok kullanılan özelliklerden birisi de izotoplardır. İzotoplar yeraltısuları ile kayaçlar arasındaki etkileşimini (su-kayaç ilişkisi) anlamada büyük öneme sahiptir. İzotoplar ile suların izledikleri yollar ve kökenleri hakkında önemli bilgiler alınabilmektedir. Özellikle, jeotermal bir sistemin bulunduğu bölgede, jeotermal rezervuar sıcaklığını tahmin etmede yardımcı olabilen bu izotoplar, aynı zamanda jeotermal bir sistemin evrimini de ortaya çıkarmaktadır. Türkiye’nin batısında yer alan ve ülkenin %2’sini oluşturan Gediz Havzası, önemli bir jeotermal potansiyelin olduğu alan konumundadır. Bu çalışma kapsamında çalışma alanındaki suların fiziksel ve kimyasal özelliklerinin kullanılarak, Alaşehir alt (Manisa) havzasında yüzey ve yeraltısuyu sistemleri arasındaki ilişkinin belirlenmesi amaçlanmıştır. Bu amaçla, Alaşehir alt havzasında 25 farklı noktada araştırma kuyuları açılmış olup, bu kuyulardan yağışlı ve kurak dönemde alınan yeraltısuyu örnekleri ile bu alandaki yağmur suyu örnekleri üzerinde laboratuvar ortamında, 2017 ve 2018 yılına ait numunelerin izotopik özellikleri değerlendirilmiştir. Buna göre, çalışma sahası ve çevresinde yeraltısularının 2017 ve 2018 yıllarına ait yağışlı ve kurak dönem ? 18O, ? 2H ve ? 3H izotop dağılımlarına bakıldığında genel olarak suların önemli bir kısmının meteorik kökenli olduğu anlaşılmaktadır.Article Citation - WoS: 58Citation - Scopus: 59Assessment of Different Nanofiltration and Reverse Osmosis Membranes for Simultaneous Removal of Arsenic and Boron From Spent Geothermal Water(Elsevier, 2021) Jarma, Yakubu A.; Karaoğlu, Aslı; Tekin, Özge; Baba, Alper; Ökten, H.Eser; Tomaszewska, Barbara; Kabay, NalanOne of the factors that determine agricultural crops’ yield is the quality of water used during irrigation. In this study, we assessed the usability of spent geothermal water for agricultural irrigation after membrane treatment. Preliminary membrane tests were conducted on a laboratory-scale set up followed by mini-pilot scale tests in a geothermal heating center. In part I, three commercially available membranes (XLE BWRO, NF90, and Osmonics CK- NF) were tested using a cross-flow flat-sheet membrane testing unit (Sepa CF II, GE-Osmonics) under constant applied pressure of 20 bar. In part II, different spiral wound membranes (TR-NE90-NF, TR-BE-BW, and BW30) other than the ones used in laboratory tests were employed for the mini-pilot scale studies in a continuous mode. Water recovery and applied pressure were maintained constant at 60% and 12 bar, respectively. Performances of the membranes were assessed in terms of the permeate flux, boron and arsenic removals. In laboratory tests, the permeate fluxes were measured as 94.3, 87.9, and 64.3 L m?2 h?1 for XLE BWRO, CK-NF and NF90 membranes, respectively. The arsenic removals were found as 99.0%, 87.5% and 83.6% while the boron removals were 56.8%, 54.2%, and 26.1% for XLE BWRO, NF90 and CK-NF membranes, respectively. In field tests, permeate fluxes were 49.9, 26.8 and 24.0 L m?2 h?1 for TR-NE90-NF, BW30-RO and TR-BE-BW membranes, respectively. Boron removals were calculated as 49.9%, 44.1% and 40.7% for TR-BE-BW, TR-NE90-NF and BW30-RO membranes, respectively. Removal efficiencies of arsenic in mini-pilot scale membrane tests were all over 90%. Quality of the permeate water produced was suitable for irrigation in terms of the electrical conductivity (EC) and the total dissolved solids (TDS) for all tested membranes with respect to guidelines set by the Turkish Ministry of Environment and Urbanisation (TMEU). However, XLE BWRO, CK-NF and NF90 membranes failed to meet the required limits for irrigation in terms of boron and arsenic concentrations in the product water. The permeate streams of TR-BE-BW, TR-NE90-NF and BW30-RO membranes complied with the irrigation water standards in terms of EC, TDS and arsenic concentration while boron concentration remained above the allowable limit. © 2020 Elsevier B.V.Conference Object Groundwater Pollution by Nitrate From Agricultural Fertilizers: the Case of Menemen Basin (aegean Region, Turkey)(İZSU, 2017) Gören, Ayşegül Yağmur; Genişoğlu, Mesut; Balcı, Esin; Ökten, Hatice Eser; Baba, AlperGroundwater is an essential drinking water source in Menemen subbasin of İzmir city, Turkey. The aim of this study was to investigate the groundwater contamination by nitrates of agricultural lands. For this purpose, we evaluated variations of groundwater pH, redox potential, electrical conductivity (EC), major anions (NO3, Cl, SO4, HCO3 and CO3) and cations (Na, K, Ca and Mg). A statistical correlation procedure and piper diagram for hydrogeochemistry of groundwater were also applied. Nitrate levels were found to be higher around agricultural areas. Also EC values and Cl were measured to be higher as proximity to coastal areas increased, indicating seawater intrusion. Agricultural activities and excessive freshwater withdrawal were shown to impair groundwater quality and quantity at Menemen subbasin.