Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 39Citation - Scopus: 43Adsorption of Peo/Ppo Triblock Co-Polymers and Wetting of Coal(Elsevier Ltd., 1999) Polat, Hürriyet; Chander, SubhashThe adsorption characteristics of PEO/PPO/PEO triblock co-polymers on coal were investigated using surface tension and contact angle measurements. Although these surfactants have been widely used as wetting agents, it was observed that they increased the hydrophobicity of coal at concentrations below about 10-6 M. Surface tension studies were carried out to explain the reasons for this behavior. The surface tension versus concentration profiles displayed three distinct regions. In region I, surface tension decreased linearly and monomers were proposed to be the dominant species. This region extended to a surfactant concentration of about 10-6 M. In region II, a transition region between regions I and III, dimers, trimers, etc., were considered to form. In region III, micelles formed and surface tension was independent of concentration. The concentration at which monomers associate to form dimers, etc., is referred to as the critical association concentration (cac). The contact angle of coal increased when concentration was raised from low values to the cac. It decreased when the reagent concentration was above the cac. Finally, at concentrations above the cmc, the wetting of coal was complete and contact angle was zero.Article Citation - WoS: 15Citation - Scopus: 18Modeling of Diffusion in Closed Cell Polymeric Foams(SAGE Publications Inc., 1999) Alsoy Altınkaya, SacideClosed-cell foams made of polymers have the lowest thermal conductivity of any currently available insulation material other than vacuum insulation systems. The increase of foam conductivity with age occurs as air diffuses into the foam while the blowing agent diffuses out, thus modifying the cell gas composition. Also, the change in cell gas composition influences the dimensional stability of the foams. To predict the long term aging behavior and dimensional stability of these foams, the diffusion characteristics of the different components need to be known. Several models exist in the literature which describe diffusion in foams. The most popular of these models are reviewed, and effective diffusivities predicted from one model are compared with experimental data. An unsteady state model is then proposed and solved numerically using a finite difference scheme. The numerical solution algorithm is developed to efficiently solve the large number of coupled equations resulting from this model. The uptake curves predicted from both the unsteady-state model and a discrete model (Bart and Du Cauze De Nazelle, 1993) are compared with available experimental data for the polystyrene-nitrogen system. From the analysis of uptake curves generated for different numbers of cells, the effective diffusivity of the PS/N2 system is predicted. Also, the effect of initial cell gas composition and cell size on both the long term aging profile and dimensional stability of polyurethane foam is considered. The proposed model can easily be extended to include the influence of blowing agent concentration on diffusivity in the polymer phase and the isotherm describing the distribution of blowing agent between the gas and polymer phases.Article Citation - WoS: 1Citation - Scopus: 1Modification of Al-Oxide Tunnel Barriers With Organic Self-Assembled Monolayers(American Institute of Physics, 1999) Okur, Salih; Zasadzinski, John F.Al-oxide tunneling barriers were modified by exposure to a vapor of n-octadecyltrimethoxysilane which forms self-assembled monolayers. The dynamic conductance dI/dV of the modified Al-oxide barrier between Al and Pb electrodes was measured at 4.2 K. Quasilinear conductance backgrounds are observed up to 200 mV with a strength that increases with increasing exposure time from 10 to 60 min. A saturation effect is observed around 200 mV. Beyond 200 mV the dynamic conductance shows a parabolic behavior indicative of elastic tunneling from an asymmetric barrier. The linear background is attributed to inelastic tunneling from a continuum of excitationsArticle Citation - WoS: 21Citation - Scopus: 24Kinetics of Oil Dispersion in the Absence and Presence of Block Copolymers(John Wiley and Sons Inc., 1999) Polat, Hürriyet; Polat, Mehmet; Chander, SubhashA phenomenological model proposed describes droplet breakup in the turbitlently agitated lean oil-in-water dispersions and provides a correlation between the median droplet size in an agitated vessel of standard geometry and the time of dispersion. It was assumed that the droplet breakup takes place in the dispersion-only region and coalescence is negligible. Vie model described the data from this study and the literature quite satisfactorily under these conditions. The effect of adding triblock PEO/PPO/PEO copofymeric surfactants on the dispersion kinetics of oil was also investigated. Addition of surfactant reduced the median oil droplet size significanfty, and the extent of this reduction was a strong function of surfactant concentration. Application of the model on these data demonstrated that the change in the median droplet size could be divided into two distinct regions. The breakage rate was high initially, most probably due to continuous adsorption of surfactant molecules at the oil/water interface. A lower breakage rate was attained at longer tunes, as the surfactant molecules were depleted from the solution. The time of transition bet\veen the t\vo was affected strongly by the concentration of the surfactant added. Furthermore, the time of addition of the surfactant did not affect the final droplet-size distribution in the system.Article Citation - WoS: 24Citation - Scopus: 25Processing of Polymers With Supercritical Fluids(John Wiley and Sons Inc., 1999) Alsoy Altınkaya, Sacide; Duda, John LarryThe removal of impurities, such as residual solvents, unreacted monomers, catalysts, and side-reaction products from polymers represents an important step in polymer processing. Conventional devolatilization techniques for the purification of polymers have limited effectiveness. Devolatilization with supercritical fluids, however, can enhance impurity removal by increasing the thermodynamic driving force and molecular diffusivity.Article Citation - WoS: 13Citation - Scopus: 15A Study of Adsorption of Water Vapour on Wool Under Static and Dynamic Conditions(Springer Verlag, 1998) Ülkü, Semra; Balköse, Devrim; Çağa, Tayfun; Özkan, Fehime; Ulutan, SevgiAdsorption of water vapour on wool provides not only textile comfort, but also convenience in transportation due to increase in its bulk density. The adsorption and desorption isotherms of water vapour for wool were determined by both volumetric technique using a Coulter Omnisorp 100CX instrument and gravimetric method employing a Cahn 2000 electronic microbalance. Adsorption isotherm fitting to B.E.T. model and hysteresis on desorption was observed. The average effective diffusion coefficient of water in wool was found to be 8.4 × 10-14 m2 s-1 at 25°C from gravimetric data. The effects of packing height and air velocity on the breakthrough curves were also investigated in the wool packed columns. For pseudo first order model, k values changing between 0.33 × 10-6 -69 × 10-6 s-1 was obtained for 2.2-6.4 cm s-1 air velocity and 0.05-0.20 m packing height ranges.Article Citation - WoS: 37Citation - Scopus: 41Differences in the Densities of Charged Defect States and Kinetics of Staebler-Wronski Effect in Undoped (nonintrinsic) Hydrogenated Amorphous Silicon Thin Films(American Institute of Physics, 1997) Güneş, Mehmet; Wronski, Christopher R.A variety of undoped (nonintrinsic) hydrogenated amorphous silicon (a-Si:H) thin films was studied in greater detail using steady-state photoconductivity, σph, subband-gap absorption, α(hν), steady-state photocarrier grating (SSPG), and electron-spin-resonance (ESR) techniques both in the annealed and stabilized light soaked states. The experimental results were self-consisiently modeled using a detailed numerical analysis. It was found that large differences in the optoelectronic properties of device quality a-Si:H thin films can only be explained using a gap slate distribution which consists of positively charged D+ defect states above the Fermi level, the neutral D0 defect states, and the negatively charged D- defect states below the Fermi level. There are large differences both in the densities of neutral and charged defect states and R ratios in different a-Si:H films in the annealed state. The densities of both neutral and charged defect states increased, however, R ratios decreased in the stabilized light soaked state. Very good agreement was obtained between the densities of neutral defect states measured by ESR and those derived from the numerical analysis in the stabilized light soaked state. The kinetics of the Staebler-Wronski effect was also investigated. There was no direct correlation between the decrease of steady-state photoconductivity and increase of subband-gap absorption. The self-consistent fits to wide range of experimental results obtained with the three Gaussian distributions of charged defect states imply that this model is much better representation of the bulk defect states in undoped hydrogenated amorphous silicon thin films.Article Citation - WoS: 22Citation - Scopus: 24Prolactin Receptor Gene Expression in Rat Splenocytes and Thymocytes From Birth To Adulthood(Elsevier Ltd., 1996) Güneş, Hatice; Mastro, Andrea M.In vivo and in vitro studies have indicated that the anterior pituitary hormone prolactin (PRL) is an immunoregulator and functions in the development of the neonatal immune system. In this study, prolactin receptor (PRL-R) expression from birth to adulthood as well as the effect of milk ingestion on the PRL-R expression were examined in splenocytes and thymocytes of neonatal rats. Three approaches were taken to measure PRL-R expression: (i) polymerase chain reaction (RT-PCR); (ii) antibody to PRL-R and Western blotting; (iii) antibody to PRL-R and flow cytometry. RT-PCR analysis revealed the short and long form of PRL-R mRNA in both spleen and thymus at every age tested. However, the long form of PRL-R mRNA was always more abundant than that of the short form. In addition, antipeptide antibody against the long form of PRL-R recognized 84 and 42 kD proteins in the spleen, but only the 84 kD protein in the thymus. A monoclonal antibody U6 recognized 38 and 40 kD proteins in both the spleen and thymus. Although the mRNA level of PRL-R was relatively low at birth and increased with age in both the spleen and thymus, the levels of protein bands detected with both antibodies correlated with development in the spleen; whereas the levels remained steady in the thymus. Therefore, we concluded that the expression of PRL-R at the protein level is developmentally regulated in the spleen but not in the thymus. Finally, milk ingestion in the first seven hours decreased the percentage of cells expressing cell surface PRL-R, suggesting that milk-borne PRL may have a direct effect on lymphocytes.Article Citation - WoS: 12Citation - Scopus: 13Modeling Deficit Irrigation in Alfalfa Production(American Society of Civil Engineers (ASCE), 1995) Tayfur, Gökmen; Tanji, Kenneth K.; House, Brett; Robinson, Frank; Teuber, Larry; Kruse, GordonA conceptual agronomic model EPIC was extended to consider the effects of salinity in alfalfa production under optimal and water stress irrigation conditions. The extended model was calibrated and validated with observed lysimeter data. The model parameters that affected alfalfa yield and soil salinity the most were wilting point, field capacity, hydraulic conductivity, nitrate concentration, biomass energy ratio, seeding rate, average soil salinity EC e at which crop yield is reduced by 50% ( EC50 ), and initial soil gypsum concentration. The calibrated and validated model was then applied to an alfalfa deficit irrigation study. The four irrigation treatments included optimum check, minimum stress, short stress, and long stress, each of which produced differential alfalfa yields. The purpose of summer deficit irrigation was to ascertain how much agricultural water at what cost could be made available for urban water uses during water shortfalls. The results of model simulation were found to be satisfactory under all irrigation treatments though the model slightly overestimated the yields and underestimated the soil EC e at the end of short and long stress treatments. An economic component is included to determine the appropriate compensation for farmers undergoing a range of deficit irrigations.Article Citation - WoS: 20Dry Deposition Fluxes and Atmospheric Size Distributions of Mass, Al, and Mg Measured in Southern Lake Michigan During Aeolos(Taylor and Francis Ltd., 1998) Sofuoğlu, Sait Cemil; Paode, Rajendra D.; Sivadechathep, Jakkris; Noll, Kenneth E.; Holsen, Thomas M.; Keeler, Gerald J.In this study, which was a part of the Atmospheric Exchange Over Lakes and Oceans Study (AEOLOS) investigation, the dry deposition fluxes and atmospheric size distributions (ASDs) of mass and crustal metals (aluminum and magnesium) were measured over the southern basin of Lake Michigan (in Chicago, over Lake Michigan, and in South Haven, Michigan). Airborne crustal metals arise primarily from fugitive dust emissions and are associated with the coarse fraction of atmospheric aerosol. Consequently, they can serve as fingerprints for the atmospheric behavior of fugitive dust. The flux of these metals were substantially higher in Chicago than in either South Haven or over Lake Michigan. The measured average mass, aluminum, and magnesium fluxes were 138, 2.23, and 5.32 mg/m2-day in Chicago, 47.8, 0.24, and 0.28 mg/m2-day over Lake Michigan, and 37.4, 0.17, and 0.12 mg/m2-day in South Haven, respectively. The ASDs of crustal metals measured in Chicago had higher concentrations of coarse particles than ASDs measured over Lake Michigan and in South Haven. The calculated flux of metals using a multistep model and dry deposition velocities obtained from the Sehmel-Hodgson model were in general agreement with measured fluxes of crustal metals. Particles >10 μm were found to be responsible for the majority of the flux.