Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
Browse
4 results
Search Results
Article Citation - WoS: 17Citation - Scopus: 18Origin of Anomalous Band-Gap Bowing in Two-Dimensional Tin-Lead Mixed Perovskite Alloys(American Physical Society, 2021) Gao, Qiang; Şahin, Hasan; Kang, Jun; Wei, Su-HuaiThe origin of the pronounced and composition-dependent band-gap bowing in Sn/Pb mixed perovskite alloys has been under debate for a long time. Previous studies reported conflicting results on whether the chemical or structural effect is the dominant mechanism. In this paper, the band-gap bowing effect and its possible origins in recently synthesized two-dimensional (2D) Cs2PbxSn1-xI2Cl2 alloys are investigated from first-principles calculations. In agreement with experiments, a large and composition-dependent bowing coefficient is observed. By analyzing the contribution from volume deformation, charge exchange, structural relaxation, and short-range order, it is found that the dominant mechanism causing the anomalous gap bowing is the structural relaxation-induced wave-function localization, forming isovalent-defect-like states, despite the negligible octahedral distortion and small lattice mismatch between the two end compounds. This is understood by the s-p repulsion-induced strong antibonding character of the valence-band maximum which leads to a large deformation potential, thus even a small atomic displacement can result in a large shift of the energy level. These results thus highlight the critical role of strong deformation potential and structural relaxation effect in unusual band evolution of 2D Sn/Pb perovskite alloys, and can be helpful to the modulation of their band gap for optoelectronic applications.Article Citation - WoS: 2Citation - Scopus: 2Determination of Solid/Liquid Fraction of Three Aluminium Binary Alloys Using a New Single-Pan Scanning Calorimete(Springer Verlag, 2017) Savaş, Sinan; Dong, HongbiaoThere is an increased demand for data with higher precision for the enthalpy changes and the fraction of solid/liquid temperatures of materials. Therefore, continuous efforts are often devoted to design calorimeters that can accurately measure materials’ thermophysical properties. In this study, a new single-pan scanning calorimeter was used to measure the transition temperature and enthalpy change of three aluminium binary alloys. Measured results also were compared with the calculated results using thermodynamic software. The measured high accuracy enthalpy data were used to determine transient temperature. It is concluded that the new instrument is a promising device that can achieve reliable and reproducible materials’ thermophysical data.Article Citation - WoS: 61Citation - Scopus: 111Measurement of the B± Meson Nuclear Modification Factor in Pb-Pb Collisions at ??snn =5.02 Tev(American Physical Society, 2017) CMS Collaboration; Karapınar, GülerThe differential production cross sections of B± mesons are measured via the exclusive decay channels B±→J/ψK±→μ+μ-K± as a function of transverse momentum in pp and Pb-Pb collisions at a center-of-mass energy sNN=5.02 TeV per nucleon pair with the CMS detector at the LHC. The pp(Pb-Pb) data set used for this analysis corresponds to an integrated luminosity of 28.0 pb-1 (351 μb-1). The measurement is performed in the B± meson transverse momentum range of 7 to 50 GeV/c, in the rapidity interval |y|<2.4. In this kinematic range, a strong suppression of the production cross section by about a factor of 2 is observed in the Pb-Pb system in comparison to the expectation from pp reference data. These results are found to be roughly compatible with theoretical calculations incorporating beauty quark diffusion and energy loss in a quark-gluon plasma.Article Citation - WoS: 88Citation - Scopus: 92Material Parameters of Quaternary Iii–v Semiconductors for Multilayer Mirrors at 1:55 Μm Wavelength(IOP Publishing Ltd., 1996) Güden, Mustafa; Piprek, JoachimNine quaternary (Al,Ga,In) - (P,As,Sb) semiconductor compounds lattice matched to InP are investigated theoretically. Direct bandgap, refractive index at wavelength, and thermal conductivity are calculated as a function of the composition. These material properties are important, e.g. in distributed Bragg reflectors of vertical-cavity lasers. The alloy systems AlGaAsSb, AlGaPSb and GaInPSb are found to promise better performance of those mirrors than the common InGaAsP system.