Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

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Publisher: search.filters.publisher.Marcel Dekker Inc.Subject: search.filters.subject.Organometallic chemistry

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  • Article
    Citation - WoS: 4
    Citation - Scopus: 4
    Synthesis, Characterization and Reactivity of [exo-Nido 9h10me2)]
    (Marcel Dekker Inc., 1996) Topaloğlu, Işıl; Sözüer, Işıl; 04.01. Department of Chemistry; 04. Faculty of Science; 01. Izmir Institute of Technology
    In this work, the reaction of the 16-electron species [Rh(η3-C8H13)-(η5-C 2B9H9Me2)] with PPh3 was investigated and the product, [exo-nido-Rh-(PPh3)2(η5-C2B 9H10Me2)], which is in an equilibrium with the closo analogue was characterized by 31p{1H}, 1H, 13C and 11B NMR spectroscopy. A mechanism for the complex formation is suggested which is related to the previously reported reactions between the 16-electron complex and PR3 (R = Me and Et) ligands.