Synthesis, Characterization and Reactivity of [exo-Nido 9h10me2)]
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Topaloğlu, Işıl
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BRONZE
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Yes
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Abstract
In this work, the reaction of the 16-electron species [Rh(η3-C8H13)-(η5-C 2B9H9Me2)] with PPh3 was investigated and the product, [exo-nido-Rh-(PPh3)2(η5-C2B 9H10Me2)], which is in an equilibrium with the closo analogue was characterized by 31p{1H}, 1H, 13C and 11B NMR spectroscopy. A mechanism for the complex formation is suggested which is related to the previously reported reactions between the 16-electron complex and PR3 (R = Me and Et) ligands.
Description
Keywords
Synthesis(Chemistry), Organometallic chemistry, Synthesis(Chemistry)
Fields of Science
01 natural sciences, 0104 chemical sciences
Citation
Topaloğlu, I. (1996). Synthesis, characterization and reactivity of [exo-nido-Rh(PPh3)2(η5-C2B 9H10Me2)]. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 26(8), 1295-1305. doi:10.1080/00945719608005125
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OpenCitations Citation Count
3
Volume
26
Issue
8
Start Page
1295
End Page
1305
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