Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

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  • Article
    Temporal Coherence of Single Photons Emitted by Hexagonal Boron Nitride Defects at Room Temperature
    (Amer Chemical Soc, 2026) Martinez-Pons, Juan Vidal; Kim, Sang Kyu; Behrens, Max; Izquierdo-Molina, Alejandro; Menendez Rua, Adolfo; Pacal, Serkan; Anton-Solanas, Carlos
    Color centers in hexagonal boron nitride (hBN) emerge as promising quantum light sources at room temperature, with potential applications in quantum communications, among others. The temporal coherence of emitted photons (i.e., their capacity to interfere and distribute photonic entanglement) is essential for many of these applications. Hence, it is crucial to study and determine the temporal coherence of this emission under different experimental conditions. In this work, we report the coherence time of the single photons emitted by an hBN defect in a nanocrystal at room temperature, measured via Michelson interferometry. The visibility of this interference vanishes when the temporal delay between the interferometer arms is a few hundred femtoseconds, highlighting that the phonon dephasing processes are 4 orders of magnitude faster than the spontaneous decay time of the emitter. We also analyze the single photon characteristics of the emission via correlation measurements, defect blinking dynamics, and its Debye-Waller factor. Our room temperature results highlight the presence of a strong electron-phonon coupling, suggesting the need to work at cryogenic temperatures to enable quantum photonic applications based on photon interference.
  • Article
    Protection of N-Type (Ni,Fe)TiSb Half-Heusler Materials Against Static and Cyclic Oxidation Using a Si-Doped Cr Coating
    (Amer Chemical Soc, 2025) Gurtaran, Mikdat; Zhang, Zhenxue; Li, Xiaoying; Dong, Hanshan
    In this study, Cr-Si coatings were deposited on N-type (Ni,Fe)TiSb thermoelectric (TE) materials by using a closed-field unbalanced magnetron sputtering PVD technique. Oxidation behavior was evaluated under both isothermal (static) conditions (500 degrees C for 10 h and 600 degrees C for 50 h) and thermal cycling regimens (500 and 600 degrees C for 10 or 50 1 h cycles). Mass gain, surface morphology, cross-sectional microstructure, elemental distribution, and phase composition were examined by using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD). Regardless of exposure mode, uncoated samples oxidized severely: a duplex scale formed, consisting of an outer TiO2 layer and a subjacent NiSb-rich zone, accompanied by extensive cracking and delamination. In sharp contrast, the Cr-Si coatings remained thermally stable and highly oxidation-resistant, maintaining the substrate's integrity during both static and cyclic tests. After exposure, coated samples showed negligible mass gain, no discernible morphological change, and no mechanical damage, confirming that the Cr-Si layer markedly enhances thermal durability and prevents surface degradation.
  • Article
    Citation - WoS: 4
    Citation - Scopus: 4
    Sulfonated Cellulose: a Strategy for Effective Methylene Blue Sequestration
    (Amer Chemical Soc, 2025) Toy, Mustafa; Recepoglu, Yasar Kemal; Arar, Ozgur
    This study investigates the sulfonation modification of cellulose for the removal of methylene blue (MB) from aqueous solutions. The prepared biosorbent was characterized, and its sorption capacity, kinetics, and thermodynamics were systematically evaluated. Fourier-transform infrared (FTIR) spectroscopy analyzed structural modifications, while scanning electron microscopy (SEM) examined the surface properties. The optimal sorbent dosage was determined as 0.05 g. MB removal efficiency increased from 11% at pH 1 to 70% at pH 2, reaching 99% within the pH range of 3 to 7. Kinetic studies revealed rapid sorption, achieving 99% removal within 3 min. Among various isotherm models, the Langmuir model provided the best fit (R 2 = 0.9989), indicating monolayer sorption with a maximum capacity of 37.65 mg/g. Thermodynamic analysis showed negative Delta G degrees values, confirming a spontaneous sorption process, while an enthalpy change (Delta H degrees) of -33.5 kJ/mol indicated exothermic behavior. The entropy change (Delta S degrees) of -82.6 J mol-1<middle dot>K-1 suggested decreased disorder during sorption. Regeneration studies demonstrated that 0.2 M HCl combined with ethanol achieved the highest desorption efficiency, and after three cycles, the MB removal efficiency remained above 99%. The presence of -SO3 - groups played a crucial role in MB sorption via ion exchange and may also contribute through hydrogen bonding, thereby enhancing MB sorption. These findings highlight sulfonated cellulose as an efficient and regenerable biosorbent for MB removal, offering valuable insights into its sorption mechanisms.
  • Article
    Citation - WoS: 2
    Citation - Scopus: 2
    Integration of Leu-Asp Cell Attachment Motif Into Self-Assembling Peptide Sequences for Nanofibrillar Hydrogel Formation in Wound Healing
    (Amer Chemical Soc, 2025) Tarim, Burcu Sirma; Sırma Tarım, Burcu; Tamburaci, Sedef; Top, Ayben; Uysal, Berk; Top, Ayben
    Functionalizing peptide sequences with cell adhesion motifs enhances their cellular bioactivity. Numerous studies have focused on incorporating the Arg-Gly-Asp (RGD) motif into peptide hydrogels; however, the integration of other bioactive domains has yet to be comprehensively investigated. In this study, one of the essential fibronectin-derived cell-binding domains, Leu-Asp-Val (LDV), was integrated into the self-assembling peptide to obtain extracellular matrix (ECM)-mimetic nanofibrillar hydrogelators. IBP1A (NH2-KLDVKLDVKLKV-CONH2) and IBP1B (NH2-KLDVKLDVKLDV-CONH2) peptides were designed accordingly. These peptides self-assemble into hydrogels in phosphate-buffered saline (PBS) at pH 7.4 and deionized water at neutral pH with storage modulus values between similar to 200 and similar to 2000 Pa. Flow curves and the cyclic strain sweep data confirmed that the hydrogels have shear thinning, injectability, and self-healing properties. Flexible nanofibrillar morphology was observed in the TEM images. Nanofibril widths of IBP1A and IBP1B networks were measured as 8.2 +/- 1.1 and 4.5 +/- 0.8 nm, respectively. In vitro tests were also conducted to evaluate these peptides in wound healing applications. The IBP1A peptide with a +3 charge at neutral pH exhibited modest antibacterial activity against Gram (+) and Gram (-) bacteria. In vitro cell culture experiments show that the IBP1A and IBP1B hydrogels promoted the growth of fibroblast cells and glycosaminoglycan secretion compared with the KLDL12 control peptide, which does not contain the LDV motif. The designed hydrogels induced cell attachment within 72 h by altering the cell morphology similar to their natural 3D microenvironment, whereas cells exhibited spindle-like morphology on the KLDL12 hydrogel and tissue culture polystyrene (TCP). Moreover, IBP1B accelerated in vitro wound healing by facilitating fibroblast migration. These results suggest that these bioactive injectable peptide hydrogels have potential in wound healing and skin tissue regeneration.
  • Article
    Selective Growth of Fapbbr3 Nanocrystals With Precisely Tailored Optical Properties for Advanced Optoelectronic Applications
    (Amer Chemical Soc, 2025) Guvenc, C. Meric; Polat, Nahit; Arica, Tugce A.; Balci, Sinan
    Understanding the evolution of semiconductor nanocrystals (NCs) during their colloidal synthesis is essential for achieving improved control over their physical and chemical properties. The fast reaction kinetics and concurrent nucleation and growth periods of lead halide perovskite NCs pose significant challenges in controlling the synthesis. Here, we present the room-temperature colloidal synthesis of FAPbBr3 NCs with physically decoupled nucleation and growth periods by using the common oleylamine and oleic acid ligand pair for lead halide perovskite NCs. Importantly, in this method, the nucleation and growth phases are entirely decoupled by halting the reaction at a metastable state, where the FAPbBr3 nuclei are formed. Subsequently, preformed FAPbBr3 nuclei are selectively grown by increasing supersaturation. This is achieved by reducing the monomer solubility through the injection of oleic acid into the solution. Notably, two-dimensional perovskite nanostructures form as intermediate products during the synthesis. Furthermore, the size of the FAPbBr3 NCs is tuned from 5.7 to 13.5 nm by controlling the injected oleic acid amount. Photoluminescence quantum yields of the FAPbBr3 perovskite NCs synthesized by using this method reached up to 95%. These findings demonstrate a robust strategy for the controlled synthesis of FAPbBr3 perovskite NCs, providing precisely tailored optical properties for advanced applications such as solar cells, photodetectors, and light-emitting diodes.
  • Article
    Citation - WoS: 14
    Citation - Scopus: 15
    Predictive Modeling of Photocatalytic Hydrogen Production: Integrating Experimental Insights With Machine Learning on Fe/G-c3n4 Catalysts
    (Amer Chemical Soc, 2025) Arabaci, Bahriyenur; Bakir, Rezan; Orak, Ceren; Yuksel, Asli
    Hydrogen emerges as a promising alternative to fossil fuels with its pollutant-free emissions, high energy density, versatility, and efficiency in generating power. In this study, photocatalytic hydrogen production from using 1000 ppm of model solution prepared with sucrose was investigated in the presence of Fe/g-C3N4 photocatalysts over Box-Behnken experimental design developed using the Minitab statistical software. The amount of hydrogen produced was optimized at different pH environments (3, 5, and 7) for 2 h reaction time with different amounts of metal loaded (10, 20, and 30 wt %), Fe/g-C3N4 (0.1, 0.2, and 0.3 g/L), and oxidant (H2O2; 0, 10, and 20 mM) concentrations. SEM, BET, XRD, FTIR, and PL analyses were employed for the characterization of synthesized photocatalysts. According to the response optimization, using Fe/g-C3N4, the optimal conditions for hydrogen production were found as 0.3 g/L catalyst loading, 18.8 mM H2O2, and 26.6% Fe loading by mass when the pH was 3 for the reaction medium. Furthermore, machine learning algorithms were employed to predict hydrogen evolution based on experimental parameters. Notably, ensemble models such as Voting Regressor combining the Bagging Regressor, Random Forest Regressor, LGBM Regressor, Extra Trees Regressor, XGB Regressor, and Gradient Boosting Regressor achieved superior performance with a mean squared error of 0.0068 and R-squared (R 2) of 0.9895. This integrated approach demonstrates the efficacy of machine learning in optimizing photocatalytic hydrogen generation processes.
  • Article
    Citation - WoS: 7
    Citation - Scopus: 7
    Periodate-Mediated Cross-Linking for the Preparation of Catechol Conjugated Albumin Nanoparticles Used for in Vitro Drug Delivery
    (Amer Chemical Soc, 2025) Argitekin, Eda; Erez, Ozlem; Cakan-Akdogan, Gulcin; Akdogan, Yasar
    Conjugation of serum albumin protein with catechol-containing dopamine molecules provides an alternative method for the preparation of albumin nanoparticles (NPs). A commonly used desolvation method utilizes glutaraldehyde as a cross-linking agent. Here, the catechol cross-linking mechanism is used instead of glutaraldehyde providing advantages to prevent toxicity and an undesirable reaction of glutaraldehyde with cargo molecules. Covalent cross-linking between dopamine conjugated bovine serum albumin (D-BSA) proteins was obtained in the presence of sodium periodate (NaIO4) as an oxidizer. As a result, spherical D-BSA NPs with a uniform size distribution of around 100 nm in diameter and negative zeta potential around -28 mV were prepared. Optimal conditions were reached when a dopamine:IO4 - molar ratio of 2:1, pH 7.4 of the medium, and acetone as the desolvating agent were used. Furthermore, the obtained NPs display antioxidant properties, have rapid biodegradability in the presence of trypsin, and have a high doxorubicin (DOX) loading (9.1%) with a sustainable drug release. DOX loaded D-BSA NPs also caused up to 90% breast cancer cell (MCF-7) death within 24 h. These results show that drug carrying albumin NPs can alternatively be prepared via covalently cross-linked catechol groups and used in drug delivery studies.
  • Article
    Citation - WoS: 2
    Citation - Scopus: 2
    Temperature-Dependent Spectral Properties of Hexagonal Boron Nitride Color Centers
    (Amer Chemical Soc, 2025) Ari, Ozan; Polat, Nahit; Firat, Volkan; Cakir, Ozgur; Ates, Serkan
    Color centers in hexagonal boron nitride (hBN) are emerging as a mature platform for single-photon sources in quantum technology applications. In this study, we investigate the temperature-dependent spectral properties of a single defect in hBN to understand the dominant dephasing mechanisms due to phonons. We observe a sharp zero-phonon line (ZPL) emission accompanied by Stokes and anti-Stokes optical phonon sidebands assisted by the Raman-active low-energy (approximate to 6.5 meV) interlayer shear mode of hBN. The shape of the spectral lines around the ZPL is measured down to 78 K, at which the line width of the ZPL is measured as 211 mu eV. Using a quadratic electron-phonon interaction, the temperature-dependent broadening and the lineshift of the ZPL are found to follow a temperature dependence of T + T 5 and T + T 3, respectively. Furthermore, the temperature-dependent line shape around the ZPL at low-temperature conditions is modeled with a linear electron-phonon coupling theory, which results in a 0 K Debye-Waller factor of the ZPL emission as 0.59. Our results provide insights into the underlying mechanisms of electron-phonon coupling in hBN, which is critical to enhance their potential for applications in quantum technologies.
  • Article
    Radially Aligned Carbon Nanotube Glass Fiber Composites as Ion-Selective Microelectrodes
    (Amer Chemical Soc, 2025) Onder, Ahmet; Ng, Zhi Kai; Tsang, Siu Hon; Alagappan, Palaniappan; Teo, Edwin Hang Tong; Yildiz, Umit Hakan
    Detection of ions is challenging due to their small size, rapid diffusion, and high mobility, especially for assaying in samples of low volumes. Among the traditional analytical methods, potentiometric ion-selective electrodes (ISE) have become a popular choice for detecting ions as they are cost-effective, user-friendly and can be miniaturized, making them useful for on-site analysis. In this context, radially aligned carbon nanotubes (RACNT) directly grown on glass fibers (GF) via the chemical vapor deposition method is investigated as a solid contact material for the fabrication of ion-selective microelectrodes (mu ISE) upon incorporating specific ionophores within a polymeric encapsulation membrane. As an illustration, sensitive detection of ammonium ions is accomplished by the fabricated mu ISE (plasticized PVC membrane containing nonactin ionophores), which yielded a LOD and a linear response range between 7.5 x 10-6 and 1.0 x 10-5 to 1.0 x 10-1 M, respectively. The mu ISE fabricated with RACNT-GF as an interface material exhibited improvements in LOD and enhanced the detection selectivity as compared to a conventional ISE fabricated using planar solid contact materials such as graphite. We hypothesize that the fabricated mu ISE with a high surface area and mechanical durability maximize the accommodation of ionophores in the barrier membrane for yielding improved potentiometric responses. Experimental results illustrate that the mu ISE possesses the potential to be utilized for the fabrication of selective and sensitive ISE upon incorporation of specific ionophores with RACNT-GF composites.
  • Article
    Citation - WoS: 2
    Citation - Scopus: 2
    Fabrication of Bioactive Helix Aspersa Extract-Loaded Chitosan-Based Bilayer Wound Dressings for Skin Tissue Regeneration
    (Amer Chemical Soc, 2024) Perpelek, Merve; Tıhmınlıoğlu, Funda; Tamburaci, Sedef; Karakasli, Ahmet; Tihminlioglu, Funda
    In recent years, there has been a notable shift toward exploring plant and animal extracts for the fabrication of tissue engineering structures that seamlessly integrate with the human body, providing both biological compatibility and physical reinforcement. In this particular investigation, we synthesized bilayer wound dressings by incorporating snail (Helix aspersa) secretions, comprising mucus and slime, into chitosan matrices via lyophilization and electrospinning methodologies. A nanofiber layer was integrated on top of the porous structure to mimic the epidermal layer for keratinocyte activity as well as acting as an antibacterial barrier against possible infection, whereas a porous structure was designed to mimic the dermal microenvironment for fibroblast activity. Comprehensive assessments encompassing physical characterization, antimicrobial efficacy, in vitro bioactivity, and wound healing potential were conducted on these bilayer dressings. Our findings revealed that the mucus and slime extract loading significantly altered the morphology in terms of nanofiber diameter and average pore size. Snail extracts loaded on a nanofiber layer of bilayer dressings showed slight antimicrobial activity against Staphylococcus epidermidis and Escherichia coli. An in vitro release study of slime extract loaded in the nanofiber layer indicated that both groups 1 and 2 showed a burst release up to 6 h, and a sustained release was observed up to 96 h for group 1, whereas slime extract release from group 2 continued up to 72 h. In vitro bioactivity assays unveiled the favorable impact of mucus and slime extracts on NIH/3T3 fibroblast and HS2 keratinocyte cell attachment, proliferation, and glycosaminoglycan synthesis. Furthermore, our investigations utilizing the in vitro scratch assay showcased the proliferative and migratory effects of mucus and slime extracts on skin cells. Collectively, our results underscore the promising prospects of bioactive snail secretion-loaded chitosan constructs for facilitating skin regeneration and advancing wound healing therapies.