Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Synthetic Memory: A Key Link Between Biocatalytically Synthesized Polyesters and Melt Electrowriting Performance(Taylor & Francis inc, 2025) Dinckal, Sanem; Yildiz, Umit HakanThe biocatalytic synthesis of polycaprolactone (PCL) and its copolymers has garnered significant attention due to their reduced toxicity and enhanced 3D processability compared to metal-catalyzed alternatives. The objective of this study is to employ biocatalysts-citric acid (CA), glycolic acid (GA) and salicylic acid (SAA)-and explore their catalytic effects on the synthesis of poly(epsilon-caprolactone) (PCL) and poly(epsilon-caprolactone)-b-poly(delta-valerolactone) (PCL-b-PVL) block copolymers. Additionally, we aimed to examine the link between synthetic memory of resultant PCL and PCL-b-PVL polymers and their melt electrowriting performance. Nuclear magnetic resonance analysis confirms successful synthesis of copolymers by monitoring signals of hydrogens at 2.30 ppm. Differential scanning calorimetry results reveal shifts in thermal properties of copolymers upon varying biocatalysts CA-, SAA- and GA-catalyzed copolymers exhibit Tm values between similar to 52 and 54 degrees C. Melt electrowriting (MEW) results demonstrate that catalyst selection plays significant role in fiber morphology and scaffold architecture, with GA- and CA-catalyzed copolymers exhibiting finer fibers (5-8 mu m), while SAA led to thicker fibers (similar to 12 mu m) and reduced spacing. Moreover, precipitation solvents MeOH and acetonitrile (ACN) affect fidelity, with ACN-prepared scaffolds exhibiting more uniform fiber diameters. Atomic force microscopy imaging of electrowritten scaffolds made of ACN- and MeOH-precipitated PCL-b-PVL both exhibit large (>15 mu m) and smaller (<10 mu m) spherulitic structure as major topological features. These findings confirm that the synthetic memory of polyesters-governed by catalyst choice and processing conditions-directly influences their printability, making them promising candidates for MEW-based biomedical scaffolds in tissue engineering, where fine fiber morphology and architectural fidelity are essential for cell attachment and tissue regeneration.Article The Infinitude of the Primes and Some Coloring Theorems(Taylor & Francis inc, 2025) Adibelli, Azem Berivan; Goral, HaydarWe first prove the infinitude of the primes via a special case of Rado's theorem whose proof is based on the infinite Ramsey theorem. In the proof, we use the colorings of the positive integers introduced by Levent Alpoge [1] and Andrew Granville [2]. Finally, using Rado's theorem for integral domains, we will give another proof for the infinitude of nonassociated prime elements in any unique factorization domain R with a few units.Article Citation - WoS: 1Citation - Scopus: 1Microporous Carbon Spheres for the Enrichment of Lead From Water Samples With Determination by Microsample Injection System - Flame Atomic Absorption Spectrometry (MIS-FAAS)(Taylor & Francis inc, 2025) Njjar, Muath; Ugan, Muhammet; Akturk, Ezgi Zekiye; Pelech, Iwona; Staciwa, Piotr; Akdogan, AbdullahMicroporous carbon spheres (MCSs) are advanced materials known for their high surface area, well-developed pore structure, low density, and rapid molecular diffusion, making them highly effective in solid-phase extraction (SPE) and other applications. In this study, MCSs synthesized from previously reported resorcinol-formaldehyde resin were employed as an adsorbent for the extraction and preconcentration of Pb(II) ions. The material was comprehensively characterized to confirm its suitability for adsorption applications. The adsorption and desorption behavior of MCSs toward lead ions was systematically examined under optimized conditions, including pH, eluent volume, eluent type, eluent concentration, and sample volume. Microinjection microsample injection system-flame atomic absorption spectrometry (MIS-FAAS) was used for the determination of lead ions. Experimental results from batch experiments showed that the MCSs exhibited a maximum adsorption capacity of 37.31 mg g-1. Under optimal conditions (pH 8.0, 1.0 mL of 0.1 M HNO3 eluent, and 10 mg of adsorbent), a preconcentration factor of 100 was achieved, with recovery values exceeding 90%. The method exhibited a limit of detection (LOD) of 0.73 mu g L-1. The developed method was successfully applied to real water samples, including tap water, entering industrial wastewater, and exiting industrial wastewater, confirming its potential for use in environmental monitoring and contamination control.Article Rings Whose Mininjective Modules Are Injective(Taylor & Francis inc, 2025) Alagoz, Yusuf; Benli-Goral, Sinem; Buyukasik, Engin; Garcia Rozas, Juan Ramon; Oyonarte, LuisThe main goal of this paper is to characterize rings over which the mininjective modules are injective, so that the classes of mininjective modules and injective modules coincide. We show that these rings are precisely those Noetherian rings for which every min-flat module is projective and we study this characterization in the cases when the ring is Kasch, commutative and when it is quasi-Frobenius. We also treat the case of nxn upper triangular matrix rings, proving that their mininjective modules are injective if and only if n=2. We use the developed machinery to find a new type of examples of indigent modules (those whose subinjectivity domain contains only the injective modules), whose existence is known, so far, only in some rather restricted situations.Article Citation - WoS: 1Citation - Scopus: 2The Impact of Genetic Variants Related To the Fatty Acid Metabolic Process Pathway on Milk Production Traits in Jersey Cows(Taylor & Francis inc, 2024) Ardicli, Sena; Senturk, Nursen; Bozkurt, Berkay; Babayev, Huseyn; Selvi, Tugce; Skolnick, Stephen; Cobanoglu, OzdenThe synthesis of fatty acids plays a critical role in shaping milk production characteristics in dairy cattle. Thus, identifying effective haplotypes within the fatty acid metabolism pathway will provide novel and robust insights into the genetics of dairy cattle. This study aimed to comprehensively examine the individual and combined impacts of fundamental genes within the fatty acid metabolic process pathway in Jersey cows. A comprehensive phenotypic dataset was compiled, considering milk production traits, to summarize a cow's productivity across three lactations. Genotyping was conducted through PCR-RFLP and Sanger sequencing, while the association between genotype and phenotype was quantified using linear mixed models. Moderate biodiversity and abundant variation suitable for haplotype analysis were observed across all examined markers. The individual effects of the FABP3, LTF and ANXA9 genes significantly influenced both milk yield and milk fat production. Additionally, this study reveals novel two-way interactions between genes in the fatty acid metabolism pathway that directly affect milk fat properties. Notably, we identified that the GGAAGG haplotype in FABP3xLTFxANXA9 interaction may be a robust genetic marker concerning both milk fat yield and percentage. Consequently, the genotype combinations highlighted in this study serve as novel and efficient markers for assessing the fat content in cow's milk. [GRAPHICS]Article W-Locally Isomorphic Torsionless Modules Over Weakly Matlis Domains(Taylor & Francis inc, 2024) Ay Saylam, Basak; Gurbuz, Ezgi; Hamdi, HalehLet R be an integral domain. An R-module G is torsionless if it is isomorphic to a submodule of a finitely generated free R-module. For torsionless modules, we define w-weak isomorphism types which are new versions of weak isomorphism types with respect to the w-operation: w-local isomorphism and w-nearly isomorphism. Furthermore, we examine the relationship between w-local isomorphism, w-nearly isomorphism, and stable isomorphism for torsionless w-modules over weakly Matlis domains.Article Genetic Factors Associated With Age-Related Macular Degeneration Modulating Plasma Inflammatory Biomarker Levels in Patients With Aids(Taylor & Francis inc, 2024) Sezgin, Efe; Schneider, Michael F.; Hunt, Peter W.; Beck-Engeser, Gabriele; Ambayac, Gabriele C.; Jabs, Douglas A.IntroductionPatients with the acquired immunodeficiency syndrome (AIDS) have an increased prevalence and incidence of intermediate-stage age-related macular degeneration (AMD). Several elevated plasma inflammatory biomarkers are associated with increased incidence of intermediate-stage AMD in this population. We evaluated the association between AMD risk alleles and plasma inflammatory biomarker levels in persons with AIDS.Materials and MethodsCryopreserved plasma specimens of 229 non-Hispanic White and 252 non-Hispanic blacks from the Longitudinal Study of the Ocular Complications of AIDS cohort were assayed for plasma levels of soluble tumor necrosis factor receptor (sTNFR) 2, interleukin (IL)-18, C x 3motif chemokine ligand 1 (CX3CL1), C-reactive protein (CRP), and soluble CD14 (sCD14). Genotyping included AMD-associated variants rs10801553 and rs800292 for complement factor H (CFH) rs9332739 and rs547154 for complement factor 2 (C2), rs2230199 for C3, rs2285714 for CFI, and rs3732379 and rs3732378 for C x 3motif chemokine receptor 1 (CX3CR1).ResultsIn Whites, AMD low-risk CX3CR1 variants (V249I and T280M) were associated with reduced plasma levels of IL-18. In Blacks, AMD low-risk C3 R102G and low-risk CX3CR1 T280M variants were associated with reduced CRP levels.ConclusionsGenetic variants in AMD-associated immune genes may influence AMD-associated systemic plasma inflammatory biomarker levels in patients with AIDS.