Civil Engineering / İnşaat Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/13
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Article Citation - WoS: 40Citation - Scopus: 47Boron in Geothermal Energy: Sources, Environmental Impacts, and Management in Geothermal Fluid(Elsevier, 2022) Mott, A.; Baba, Alper; Hadi Mosleh, Mojgan; Ökten, Hatice Eser; Babaei, Masoud; Gören, Ayşegül Yağmur; Feng, C.; Recepoğlu, Yaşar Kemal; Uzelli, Taygun; Uytun, Hüseyin; Morata, Diego; Yüksel Özşen, AslıThe problem of hazardous chemicals in geothermal fluid is a critical environmental concern in geothermal energy developments. Boron is among the hazardous contaminants reported to be present at high concentrations in geothermal fluids in various countries. Poor management and inadequate treatment of geothermal fluids can release excessive boron to the environment that has toxic effects on plants, humans, and animals. Despite the importance of boron management in geothermal fluid, limited and fragmented resources exist that provide a comprehensive understanding of its sources, transport and fate, and the treatment strategies in geothermal energy context. This paper presents the first critical review from a systematic and comprehensive review on different aspects of boron in geothermal fluid including its generation, sources, toxicity, ranges and the management approaches and treatment technologies. Our research highlights the origin of boron in geothermal water to be mainly from historical water-rock interactions and magmatic intrusion. Excessive concentrations of boron in geothermal fluids have been reported (over 500 mg/L in some case studies). Our review indicated that possible boron contamination in geothermal sites are mostly due to flawed construction of production/re-injection wells and uncontrolled discharge of geothermal water to surface water. The dominancy of non-ionic H3BO3 species makes the selection of the suitable treatment method for geothermal waters limited. Combining boron selective resins and membrane technologies, hybrid systems have provided effluents suitable for irrigation. However, their high energy consumption and course structure of boron selective resins encourage further research to develop cost-effective and environmentally friendly alternatives.Article Citation - WoS: 58Citation - Scopus: 59Assessment of Different Nanofiltration and Reverse Osmosis Membranes for Simultaneous Removal of Arsenic and Boron From Spent Geothermal Water(Elsevier, 2021) Jarma, Yakubu A.; Karaoğlu, Aslı; Tekin, Özge; Baba, Alper; Ökten, H.Eser; Tomaszewska, Barbara; Kabay, NalanOne of the factors that determine agricultural crops’ yield is the quality of water used during irrigation. In this study, we assessed the usability of spent geothermal water for agricultural irrigation after membrane treatment. Preliminary membrane tests were conducted on a laboratory-scale set up followed by mini-pilot scale tests in a geothermal heating center. In part I, three commercially available membranes (XLE BWRO, NF90, and Osmonics CK- NF) were tested using a cross-flow flat-sheet membrane testing unit (Sepa CF II, GE-Osmonics) under constant applied pressure of 20 bar. In part II, different spiral wound membranes (TR-NE90-NF, TR-BE-BW, and BW30) other than the ones used in laboratory tests were employed for the mini-pilot scale studies in a continuous mode. Water recovery and applied pressure were maintained constant at 60% and 12 bar, respectively. Performances of the membranes were assessed in terms of the permeate flux, boron and arsenic removals. In laboratory tests, the permeate fluxes were measured as 94.3, 87.9, and 64.3 L m?2 h?1 for XLE BWRO, CK-NF and NF90 membranes, respectively. The arsenic removals were found as 99.0%, 87.5% and 83.6% while the boron removals were 56.8%, 54.2%, and 26.1% for XLE BWRO, NF90 and CK-NF membranes, respectively. In field tests, permeate fluxes were 49.9, 26.8 and 24.0 L m?2 h?1 for TR-NE90-NF, BW30-RO and TR-BE-BW membranes, respectively. Boron removals were calculated as 49.9%, 44.1% and 40.7% for TR-BE-BW, TR-NE90-NF and BW30-RO membranes, respectively. Removal efficiencies of arsenic in mini-pilot scale membrane tests were all over 90%. Quality of the permeate water produced was suitable for irrigation in terms of the electrical conductivity (EC) and the total dissolved solids (TDS) for all tested membranes with respect to guidelines set by the Turkish Ministry of Environment and Urbanisation (TMEU). However, XLE BWRO, CK-NF and NF90 membranes failed to meet the required limits for irrigation in terms of boron and arsenic concentrations in the product water. The permeate streams of TR-BE-BW, TR-NE90-NF and BW30-RO membranes complied with the irrigation water standards in terms of EC, TDS and arsenic concentration while boron concentration remained above the allowable limit. © 2020 Elsevier B.V.Conference Object Factors Affecting the Quality of Groundwater Resources and Its Effects in Turkey(Bozok Üniversitesi, 2016) Baba, AlperMany civilizations have been located along the water basins throughout history. Civilizations have enabled the survival and growth by these water resources in world. For natural wealth, the need of water is increase. Therefore, investigation of the water potential, available of protection, efficient and planned use has begun to supply vital.Article Citation - WoS: 14Citation - Scopus: 17Blowout Mechanism of Alasehir (turkey) Geothermal Field and Its Effects on Groundwater Chemistry(Springer Verlag, 2017) Rabet, Rita Sandrina; Şimşek, Celalettin; Baba, Alper; Murathan, AlimAnatolia region is one of the most seismically active regions in the world and has a considerably high level of geothermal energy potential. Some of these geothermal resources have been used for power generation and direct heating. Most of the high enthalpy geothermal systems are located in western part of Turkey. Alasehir is the most important geothermal site in western part of Turkey. Many geothermal wells have been drilled in Alasehir Plain to produce the geothermal fluid from the deep reservoir in the last 10 years. A blowout accident happened during a geothermal well drilling operation in Alasehir Plain, and significant amount of geothermal fluid surfaced out along the fault zone in three locations. When drilling string entered the reservoir rock about 1000 m, blowout occurred. As the well head preventer system was closed because of the blowout, high-pressure fluid surfaced out along the fault zone cutting the Neogene formation. In order to understand the geothermal fluid effects on groundwater chemistry, physical and chemical compositions of local cold groundwater were monitored from May 2012 to September 2014 in the study area. The geothermal fluid was found to be of Na–HCO3 water type, and especially, arsenic and boron concentrations reached levels as high as 3 and 127 mg/L, respectively. The concentrations of arsenic and boron in the geothermal fluid and groundwater exceeded the maximum allowable limits given in the national and international standards for drinking water quality. According to temporally monitored results, geothermal fluid has extremely high mineral content which influenced the quality of groundwater resources of the area where water resource is commonly used for agricultural irrigation.