Civil Engineering / İnşaat Mühendisliği
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Article Citation - WoS: 3Citation - Scopus: 4Geothermal Potential of Manuguru Geothermal Field of Godavari Valley, India(Elsevier, 2022) Singh, Hemant K.; Chandrasekharam, Dornadula; Minissale, A.; Raju, N. Janardhana; Baba, AlperThe Godavari geothermal field in India is one of the potential areas manifested by several geothermal waters and groundwaters. The geothermal waters of the area are near neutral (pH: 6.5–7.3) with surface temperature ranging from 30 to 55 °C while groundwaters are also near neutral (pH: 6.6–7.5) with surface temperature ranging from 24 to 28 °C. The hydrogeochemistry of the geothermal waters suggests that the geothermal waters show a Na-Ca-SO4-HCO3 to a Ca-HCO3 type and groundwaters are of the Ca-HCO3 to Na-Ca-HCO3 type while groundwaters and river waters are of the Ca-Na-SO4 types. The geothermal waters of the study area are enriched in SO42– and Cl–, due to the interaction with the pyrite-bearing Gondwana sediments and granitic gneiss basement rocks. Furthermore, enrichment of Ca2+, Mg2+ and an increased HCO3/Cl ratio in geothermal water is caused by the exchange and/or mixing process that takes place during water-rock interaction at an elevated temperature while ascending to the surface. This type of behavior of water is also observed during the water-rock interaction experiment at 100 °C. Studies on geothermal gas geochemistry suggest the deeper circulation of geothermal waters in the crust and high helium concentration as a thermal gas that can be utilized for commercial purposes. Estimated reservoir temperatures from quartz and Na-K-Ca geothermometry are in the range 110–195 °C. Therefore, the geothermal water of the study area is categorized as a moderate enthalpy geothermal system. Thermal logging in the borewell and depth range from 50 to 1000 m suggest that the geothermal gradient in the Manuguru area ranges from 22.5 to 105.5 °C/km and heat flow ranges from 83 to 388 mW/m2, which is higher than the regional condition. Therefore, 3584 MWe power can be produced by using the Organic Rankine Cycle (ORC) from the Manuguru geothermal area of Godavari valleyArticle Citation - WoS: 40Citation - Scopus: 47Boron in Geothermal Energy: Sources, Environmental Impacts, and Management in Geothermal Fluid(Elsevier, 2022) Mott, A.; Baba, Alper; Hadi Mosleh, Mojgan; Ökten, Hatice Eser; Babaei, Masoud; Gören, Ayşegül Yağmur; Feng, C.; Recepoğlu, Yaşar Kemal; Uzelli, Taygun; Uytun, Hüseyin; Morata, Diego; Yüksel Özşen, AslıThe problem of hazardous chemicals in geothermal fluid is a critical environmental concern in geothermal energy developments. Boron is among the hazardous contaminants reported to be present at high concentrations in geothermal fluids in various countries. Poor management and inadequate treatment of geothermal fluids can release excessive boron to the environment that has toxic effects on plants, humans, and animals. Despite the importance of boron management in geothermal fluid, limited and fragmented resources exist that provide a comprehensive understanding of its sources, transport and fate, and the treatment strategies in geothermal energy context. This paper presents the first critical review from a systematic and comprehensive review on different aspects of boron in geothermal fluid including its generation, sources, toxicity, ranges and the management approaches and treatment technologies. Our research highlights the origin of boron in geothermal water to be mainly from historical water-rock interactions and magmatic intrusion. Excessive concentrations of boron in geothermal fluids have been reported (over 500 mg/L in some case studies). Our review indicated that possible boron contamination in geothermal sites are mostly due to flawed construction of production/re-injection wells and uncontrolled discharge of geothermal water to surface water. The dominancy of non-ionic H3BO3 species makes the selection of the suitable treatment method for geothermal waters limited. Combining boron selective resins and membrane technologies, hybrid systems have provided effluents suitable for irrigation. However, their high energy consumption and course structure of boron selective resins encourage further research to develop cost-effective and environmentally friendly alternatives.Article Citation - WoS: 8Citation - Scopus: 11Geothermal Potential of Granites: Case Study- Kaymaz and Sivrihisar (eskisehir Region) Western Anatolia(Elsevier, 2022) Chandrasekharam, Dornadula; Baba, Alper; Ayzit, Tolga; Singh, Hemant K.Radiogenic granites are gaining importance due to their ability to generate a substantial amount of electricity and support the advancement of agricultural and water sectors. In the western Anatolian region, such granites occupy a cumulative area of 6910 km2 varying from 7 to 20 μW/m3, far above the heat generated by the average continental crust of 5 μW/ m3. One cubic. The granite plutons of the Eskisehir region are amongst such granites with radioactive heat generation kilometer of such granite can generate 79 × 106 kWh of electricity. In the present case, the Eskisehir granites are capable of generating 616 million kWh of carbon-free electricity. Besides electricity, the heat from the granites can be utilized for space heating and greenhouse cultivation. This energy can also be utilized for the generation of fresh water from the sea through the desalination process. Hydrofracturing of the granites to create a fracture network connecting injection and production well is being replaced with closed-loop system that do not require knowledge about the stress pattern of the region and reduce the risk of induced micro-seismicity that was a bottleneck for developing EGS projects. Although the currently estimated cost of electricity generated from EGS projects is 9 euro cents/kWh, this cost will get reduced due to technological development in drilling technology. The Western Anatolian region has an additional advantage over the cost, since the drilling depth to capture the heat from the granites is shallow (∼3 km) which gives further benefit to the cost due to the reduction in drilling depth cost. In addition to high radiogenic granites, the presence of curie point temperature at shallow depth, high heat flow, and high geothermal gradient makes this region a warehouse of energy making Turkey energy-food and water independent in the future.Article Citation - WoS: 2Citation - Scopus: 5Experimental Modeling of Antimony Sulfides-Rich Geothermal Deposits and Their Solubility in the Presence of Polymeric Antiscalants(Elsevier, 2022) Karaburun, Emre; Sözen, Yiğit; Çiftçi, Celal; Şahin, Hasan; Baba, Alper; Akbey, Ümit; Yeşilnacar, Mehmet İrfan; Erdim, Eray; Regenspurg, Simona; Demir, Mustafa MuammerAntimony (Sb)-rich geothermal deposits have been observed in many geothermal power plants worldwide. They occur as red-colored, sulfidic precipitates disturbing energy-harvesting by clogging the geothermal installations. In order to prevent the formation of this scale, information on its physicochemical features is needed. For this purpose, Sb-rich sulfide-based deposits were synthesized at controlled conditions in a pressurized glass reactor at geothermal conditions (135 °C and 3.5 bar). Various polymeric antiscalants with different functional groups, such as acrylic acid, sulphonic acid, and phosphonic acid groups were tested for their effect on Sb sulfide solubility. An additional computational study was performed to determine the binding energy of Sb and S atoms to these groups. The results suggest that sulfonic acid groups are the most affective. Therefore, it was concluded that these macromolecule containing sulfonic acid groups and poly (vinyl sulfonic acid) derivatives could potentially act as antiscalants for the formation of antimony sulfide.Article Citation - WoS: 7Citation - Scopus: 11Utilization of Membrane Separation Processes for Reclamation and Reuse of Geothermal Water in Agricultural Irrigation of Tomato Plants-Pilot Membrane Tests and Economic Analysis(Elsevier, 2022) Jarma, Yakubu A.; Karaoğlu, Aslı; Senan, Islam Rashad Ahmed; Meriç, Mehmet Kamil; Kukul, Yasemin Senem; Özçakal, Emrah; Barlas, Neriman Tuba; Çakıcı, Hakan; Baba, Alper; Kabay, NalanThe quality of irrigation water is critical for enhancing agricultural productivity. As a result, this research was carried out with the aim of treating spent geothermal water before it is used for agricultural irrigation. While doing that, cost analysis of the system was taken into consideration as well. The product water was targeted to suit irrigation water standards for tomato plants. Two commercially available pressure driven membranes (NF8040-70 as NF membrane and TM720D-400 as RO membrane) were employed for this task. A constant applied pressure of 15 bar and 60% of water recovery were kept constant during the product water production while mode of operation for the membrane system was continuous. According to Turkish Ministry of Environment and Urbanization irrigation water standards and the results obtained from this study, it was clearly seen that both NF and RO product waters meet the quality I class irrigation water standards with respect total dissolved substances (TDS), electrical conductivity (EC), concentrations of Na+ and Cl− ions. Quality 1 means that the produced water will not cause any environmental effect when employed for irrigation purpose. Nevertheless, the produced water was found not to obey the irrigation standards with respect to sodium adsorption ratio (SAR) and boron concentration (quality III class). Quality III explains that the water will cause soil infiltration problems when employed for irrigation purpose. Since most of the minerals needed for plant growth were rejected by NF and RO membranes, an appropriate mixing ratio of the product water with well water for remineralization was determined. Mixing 50 and 60% of well water with the product waters of NF (50%) and RO (40%) membranes, respectively was found to be the optimum mixing ratios to produce the requested water quality for tomato irrigation. Quality II class irrigation water which can be applied with caution was targeted in terms of SAR as well as boron concentration (2–4 and 4–6 mg/L) while determining the mixing ratios. The cost of the product water was found as 0.76 and 1.56$/m3 for NF and RO processes, respectively.Article Citation - WoS: 13Citation - Scopus: 18Integrated Pressure-Driven Membrane Separation Processes for the Production of Agricultural Irrigation Water From Spent Geothermal Water(Elsevier, 2022) Jarma, Yakubu Abdullahi; Karaoğlu, Aslı; Tekin, Özge; Senan, Islam Rashad Ahmed; Baba, AlperThe application of different pressure-driven membranes to treat the spent geothermal water to be used for agricultural irrigation was explored in this study. Firstly, individual performances of different commercially available nanofiltration (NF) and reverse osmosis (RO) membranes attached to a mini-pilot membrane test system were studied. For the single membrane test TR-NF and NF90 as NF membranes and TR-BWRO, Vontrone, TR-SWRO and BW30 as RO membranes were employed while combination of TR-NF with TR-BWRO, Vontrone, TR-SWRO and BW30 was employed in the integrated study (with and without pH adjustment).When performances of individual membranes were investigated, the permeate fluxes obtained it was found that there was no significant flux drop with the experimental time (4 h) in all the studies. In terms of boron removals, boron was partially removed in single membrane study as 22.7–23.6% and 30.6–56.8% by NF and RO membranes, respectively. For the integrated NF + RO membrane configuration (without pH adjustment), boron removals were in the range of 42.1–59.4% while 91.3–95.4% of boron removal was obtained in the integrated NF + RO (at elevated pH). It was found that the produced water complied with class I quality with respect to irrigation water parameters with the exception of boron and sodium adsorption ratio (SAR), while the pH of the product water in the integrated NF + RO study at elevated pH was found to be in class III. Hence, produced water will be suitable (class II) for irrigation if 30% of well water should be blended with the product water in the integrated NF + RO studies (with and without pH adjustment) as well as pH adjustment when necessary.Article Citation - WoS: 58Citation - Scopus: 76Utilization of Renewable Energy Sources in Desalination of Geothermal Water for Agriculture(Elsevier, 2021) Tomaszewska, Barbara; Gökçen Akkurt, Gülden; Kaczmarczyk, Michal; Bujakowski, Wieslaw; Keleş, Nazlı; Jarma, Yakubu A.; Baba, Alper; Bryjak, Marek; Kabay, NalanThe agricultural sector, which is highly dependent on water, is urged to build on improved water management practices and explore available options to match supply and demand because of the water scarcity risks and a sustainable and productive agri-food chain. Geothermal water is an energy source used to generate electricity and/or heat. After harnessing its energy, the remaining water can be used as a water source for irrigation following treatment because of its high ionic content. Geothermal fields are mostly located in rural areas where agricultural activities exist. This would be a good match to decrease the transportation cost of irrigation water. The energy demand of the desalination process for agriculture is higher, requiring additional post-treatment processes. Fossil fuels to fulfill the energy requirements are becoming expensive, and greenhouse gas emissions are harmful to the environment. Thus, efforts should be directed towards integrating renewable energy resources into desalination process. This work focuses on presenting a comprehensive review of geothermal water desalination which is powered by renewable energy and provides specific cases from Turkey and Poland. Furthermore, possible new generation renewable energy systems in desalination are introduced, considering their potential application in the desalination of geothermal water for agricultural irrigation.Article Citation - WoS: 32Citation - Scopus: 35Distribution of Geothermal Arsenic in Relation To Geothermal Play Types: a Global Review and Case Study From the Anatolian Plate (turkey)(Elsevier, 2021) Baba, Alper; Uzelli, Taygun; Sözbilir, HasanArsenic has a natural cycle as it travels underground. It can mix with geothermal fluid in different ways under the control of magmatic and tectonic processes. Geogenic arsenic is present in many geothermal fields in the world at concentrations above the limits set for human health. The arsenic content of geothermal fluids is also related to the concept of geothermal play type, which forms geothermal systems, because the natural processes that form the geothermal system also control the arsenic cycle. In this study, an attempt is made to explain the relationship between the geothermal play type concept and geothermal arsenic circulation. For this purpose, geothermal field examples are given from around the world and Turkey. The result shows that arsenic concentrations can reach significant levels along with plate tectonic boundaries in the world. When arsenic concentrations were evaluated, the effect of major faults on the Anatolian Plate was clearly seen. Also, in the Anatolian plate where volcanosedimentary units are common, geothermal fluids caused more effective alteration along with structural control and increased arsenic concentrations in geothermal systems. This interaction between structural elements, geothermal fluid, and the arsenic cycle shows that the concept of play type in geothermal systems should also be taken into consideration. It was determined that the places with high arsenic values are located within the convective-non-magmatic extensional geothermal play types such as Western Anatolian Extensional System and the North Anatolian Fault. The concept of play type in geothermal systems includes all systematic and external factors that make up these processes. For this reason, it is very important to evaluate the play type classification together with the arsenic cycle.Article Citation - WoS: 11Citation - Scopus: 15Groundwater Resources and Quality in Syria(Elsevier, 2021) Baba, Alper; Karem, Ruwad AL.; Yazdani, HamidrezaThe resources of groundwater and its pollution in Syria are identified, and pathways of contaminants to groundwater are described. Then, suggestions for improvement of groundwater quality in Syria are evaluated. Syria is located in a region where water scarcity is dominant. About 87% of all water in Syria is mainly used for irrigation, with almost 60% of this water taken from groundwater resources. The rest is used for domestic and industrial purposes, which account for 9% and 4%, respectively. Due to over-pumping and the increase in the number of unsustainable wells observed in recent decades, groundwater is quantitatively deteriorating. In general, sources of groundwater contamination fall into two main categories: natural and anthropogenic sources. Important sources of natural groundwater pollution include climate effects. About 43% of groundwater has a high concentration of SO4 and/or NaCl. This is specifically dominant in the eastern region of Syria due to the harsh environment where precipitation is relatively low, and evaporation is high. One of the major sources of anthropogenic groundwater contamination is civil war. Most of the damaged regions are located on permeable rocks, which increases the probability of groundwater contamination due to chemical weapons (CW) used. It is vital to manage and control groundwater resources well. With the increase in water contamination and with the absence of poor water management, access to drinking water will be more of a problem than it is now.Article Citation - WoS: 58Citation - Scopus: 59Assessment of Different Nanofiltration and Reverse Osmosis Membranes for Simultaneous Removal of Arsenic and Boron From Spent Geothermal Water(Elsevier, 2021) Jarma, Yakubu A.; Karaoğlu, Aslı; Tekin, Özge; Baba, Alper; Ökten, H.Eser; Tomaszewska, Barbara; Kabay, NalanOne of the factors that determine agricultural crops’ yield is the quality of water used during irrigation. In this study, we assessed the usability of spent geothermal water for agricultural irrigation after membrane treatment. Preliminary membrane tests were conducted on a laboratory-scale set up followed by mini-pilot scale tests in a geothermal heating center. In part I, three commercially available membranes (XLE BWRO, NF90, and Osmonics CK- NF) were tested using a cross-flow flat-sheet membrane testing unit (Sepa CF II, GE-Osmonics) under constant applied pressure of 20 bar. In part II, different spiral wound membranes (TR-NE90-NF, TR-BE-BW, and BW30) other than the ones used in laboratory tests were employed for the mini-pilot scale studies in a continuous mode. Water recovery and applied pressure were maintained constant at 60% and 12 bar, respectively. Performances of the membranes were assessed in terms of the permeate flux, boron and arsenic removals. In laboratory tests, the permeate fluxes were measured as 94.3, 87.9, and 64.3 L m?2 h?1 for XLE BWRO, CK-NF and NF90 membranes, respectively. The arsenic removals were found as 99.0%, 87.5% and 83.6% while the boron removals were 56.8%, 54.2%, and 26.1% for XLE BWRO, NF90 and CK-NF membranes, respectively. In field tests, permeate fluxes were 49.9, 26.8 and 24.0 L m?2 h?1 for TR-NE90-NF, BW30-RO and TR-BE-BW membranes, respectively. Boron removals were calculated as 49.9%, 44.1% and 40.7% for TR-BE-BW, TR-NE90-NF and BW30-RO membranes, respectively. Removal efficiencies of arsenic in mini-pilot scale membrane tests were all over 90%. Quality of the permeate water produced was suitable for irrigation in terms of the electrical conductivity (EC) and the total dissolved solids (TDS) for all tested membranes with respect to guidelines set by the Turkish Ministry of Environment and Urbanisation (TMEU). However, XLE BWRO, CK-NF and NF90 membranes failed to meet the required limits for irrigation in terms of boron and arsenic concentrations in the product water. The permeate streams of TR-BE-BW, TR-NE90-NF and BW30-RO membranes complied with the irrigation water standards in terms of EC, TDS and arsenic concentration while boron concentration remained above the allowable limit. © 2020 Elsevier B.V.