WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Hydrogeochemical Assessment and Health Risks of Groundwater in Sahand Volcanic Foreland (NW Iran): Arsenic Speciation and Heavy Metal Risk Indicators(Academic Press Inc Elsevier Science, 2026) Ghayurdoost, Farhad; Zarghami, Mahdi; Sadeghfam, Sina; Jabraili-Andaryan, Nasser; Nikmaram, Sara; Baba, Alper; Mosaferi, MohammadDue to the toxic nature of arsenic (As) and its elevated concentrations in many water resources, numerous studies have focused on understanding its origin, distribution, and impacts. This study aimed to identify the dominant As species in groundwater of the Sahand Volcanic Foothills, assess water quality indices, and examine heavy metal (HM) concentrations to address rising concerns about groundwater contamination. A total of 21 groundwater samples were collected and analyzed in accordance with world health organization (WHO) guidelines. Although most samples fell within acceptable ranges, several (notably S10, S20, and S21) exhibited elevated levels of total dissolved solids (TDS), electrical conductivity (EC), and HMs, particularly iron (Fe) and As. Hydrochemical assessments using Piper, Gibbs, Stiff, and Schoeller diagrams indicated that geochemical processes resulting from rock dissolution were the main factors controlling groundwater chemistry, with limited influence from anthropogenic pollution. According to the groundwater quality index (GWQI), most samples were categorized as "good" to "excellent," though some areas ranged from "moderate" to "very poor." HM pollution indices revealed that As concentrations exceeded permissible limits. Health risk assessments further showed that both oral and dermal exposure posed significant carcinogenic and non-carcinogenic risks, especially for children. Speciation analysis indicated that arsenate (As V) was the dominant form of As, consistent with oxidizing aquifer conditions, and is less biologically hazardous than arsenite (As III). The study highlights the necessity of continuous groundwater monitoring, effective pollution source management, and implementation of protective regulations to mitigate environmental and health risks in the region.Article Nature-Based Solutions in Island Water Management: A Case Study From Bozcaada (Türkiye)(Academic Press Ltd- Elsevier Science Ltd, 2025) Samiloglu, Bilgesu; Baba, Alper; Cuevas, Raquel Marijuan; Gunduz, OrhanNature-based Solutions (NbS) are increasingly recognized for their role in the sustainable management of water resources, especially in Mediterranean regions facing seasonal water scarcity. While their benefits for biodiversity and climate resilience are well documented, there is little research on their application in small island regions where ecological fragility and water scarcity intersect. This study fills this gap by investigating the potential of NbS, particularly rainwater harvesting systems, on the island of Bozcaada (T & uuml;rkiye). A high-resolution Digital Elevation Model (DEM) was developed to delineate the watersheds of the island and analyze the water flow patterns. These watersheds were analyzed for their water retention potential and suitability for rainwater storage. The geological structure, soil type and native biodiversity were included in the site selection process to ensure ecological compatibility. Based on this analysis, optimal locations for ponds were identified and designed to support groundwater recharge and preserve local ecosystems. The results show that strategically placed rainwater ponds can improve seasonal water availability, reduce dependence on external sources and support native species throughout the year. This NbS-based approach provides a replicable framework for sustainable water management on small Mediterranean islands, emphasizing ecological integration and long-term resilience.Article Citation - WoS: 4Citation - Scopus: 12Carbon Dioxide Emissions Mitigation Strategy Through Enhanced Geothermal Systems: Western Anatolia, Turkey(Springer, 2022) Chandrasekharam, Dornadula; Baba, AlperAlthough Turkey is not the biggest GHG polluter, its emissions have increased by 110.4% since 1990. Currently, its CO2 emissions alone have crossed 400 Mt. Within the scope of 2 °C targets (2D scenario), the country can easily surpass this target test by increasing its renewable energy sources as a primary energy source mix, by developing its Enhanced Geothermal Sources (EGS) locked up in the radiogenic granites of western Anatolia. The radiogenic heat generated by these granites, spread over an area of 4221 sq. km, varies from 5.3 to 16.34 µW/m3. Based on the electricity generation capacity of granites from Soultz-sous-Forets and Cooper Basin EGS sites, the combined electricity generation capacity of Kestanbol and Kozak granite plutons is about 830 billion kWh. For the period extending from 2019 to 2023, Turkey is aiming at reducing the usage of gas for electricity generation from 29.9 to 20.7%, increasing the share of renewable energy sources from 32.5 to 38.8%, increasing the electricity production from local energy sources from 150 to 219 TWh and increasing the electricity usage per-capita from 3.7 to 4.3 MWh. These energy targets can be achieved by major contributions from hydrothermal and EGS energy sources. This review demonstrates that besides electricity and heat, EGS energy can be utilized, together with other renewable energy sources, such as hydrothermal, wind, and concentrated solar for providing fresh water through the desalination process. These energy sources would provide food, energy, and water security to the country for several decades.Article Citation - WoS: 32Citation - Scopus: 35Distribution of Geothermal Arsenic in Relation To Geothermal Play Types: a Global Review and Case Study From the Anatolian Plate (turkey)(Elsevier, 2021) Baba, Alper; Uzelli, Taygun; Sözbilir, HasanArsenic has a natural cycle as it travels underground. It can mix with geothermal fluid in different ways under the control of magmatic and tectonic processes. Geogenic arsenic is present in many geothermal fields in the world at concentrations above the limits set for human health. The arsenic content of geothermal fluids is also related to the concept of geothermal play type, which forms geothermal systems, because the natural processes that form the geothermal system also control the arsenic cycle. In this study, an attempt is made to explain the relationship between the geothermal play type concept and geothermal arsenic circulation. For this purpose, geothermal field examples are given from around the world and Turkey. The result shows that arsenic concentrations can reach significant levels along with plate tectonic boundaries in the world. When arsenic concentrations were evaluated, the effect of major faults on the Anatolian Plate was clearly seen. Also, in the Anatolian plate where volcanosedimentary units are common, geothermal fluids caused more effective alteration along with structural control and increased arsenic concentrations in geothermal systems. This interaction between structural elements, geothermal fluid, and the arsenic cycle shows that the concept of play type in geothermal systems should also be taken into consideration. It was determined that the places with high arsenic values are located within the convective-non-magmatic extensional geothermal play types such as Western Anatolian Extensional System and the North Anatolian Fault. The concept of play type in geothermal systems includes all systematic and external factors that make up these processes. For this reason, it is very important to evaluate the play type classification together with the arsenic cycle.Article Citation - WoS: 58Citation - Scopus: 59Assessment of Different Nanofiltration and Reverse Osmosis Membranes for Simultaneous Removal of Arsenic and Boron From Spent Geothermal Water(Elsevier, 2021) Jarma, Yakubu A.; Karaoğlu, Aslı; Tekin, Özge; Baba, Alper; Ökten, H.Eser; Tomaszewska, Barbara; Kabay, NalanOne of the factors that determine agricultural crops’ yield is the quality of water used during irrigation. In this study, we assessed the usability of spent geothermal water for agricultural irrigation after membrane treatment. Preliminary membrane tests were conducted on a laboratory-scale set up followed by mini-pilot scale tests in a geothermal heating center. In part I, three commercially available membranes (XLE BWRO, NF90, and Osmonics CK- NF) were tested using a cross-flow flat-sheet membrane testing unit (Sepa CF II, GE-Osmonics) under constant applied pressure of 20 bar. In part II, different spiral wound membranes (TR-NE90-NF, TR-BE-BW, and BW30) other than the ones used in laboratory tests were employed for the mini-pilot scale studies in a continuous mode. Water recovery and applied pressure were maintained constant at 60% and 12 bar, respectively. Performances of the membranes were assessed in terms of the permeate flux, boron and arsenic removals. In laboratory tests, the permeate fluxes were measured as 94.3, 87.9, and 64.3 L m?2 h?1 for XLE BWRO, CK-NF and NF90 membranes, respectively. The arsenic removals were found as 99.0%, 87.5% and 83.6% while the boron removals were 56.8%, 54.2%, and 26.1% for XLE BWRO, NF90 and CK-NF membranes, respectively. In field tests, permeate fluxes were 49.9, 26.8 and 24.0 L m?2 h?1 for TR-NE90-NF, BW30-RO and TR-BE-BW membranes, respectively. Boron removals were calculated as 49.9%, 44.1% and 40.7% for TR-BE-BW, TR-NE90-NF and BW30-RO membranes, respectively. Removal efficiencies of arsenic in mini-pilot scale membrane tests were all over 90%. Quality of the permeate water produced was suitable for irrigation in terms of the electrical conductivity (EC) and the total dissolved solids (TDS) for all tested membranes with respect to guidelines set by the Turkish Ministry of Environment and Urbanisation (TMEU). However, XLE BWRO, CK-NF and NF90 membranes failed to meet the required limits for irrigation in terms of boron and arsenic concentrations in the product water. The permeate streams of TR-BE-BW, TR-NE90-NF and BW30-RO membranes complied with the irrigation water standards in terms of EC, TDS and arsenic concentration while boron concentration remained above the allowable limit. © 2020 Elsevier B.V.Article Citation - WoS: 16Citation - Scopus: 20Groundwater Recharge Estimation Using Hydrus 1d Model in Alaşehir Sub-Basin of Gediz Basin in Turkey(Springer Verlag, 2019) Tonkul, Serhat; Baba, Alper; Şimşek, Celalettin; Durukan, Seda; Demirkesen, Ali Can; Tayfur, GökmenGediz Basin, located in the western part of Turkey constituting 2% land of the country, has an important groundwater potential in the area. Alasehir sub-basin, located in the southeast of the Gediz Basin and subject to the extensive withdrawal for the irrigation, constitutes the study area. Natural recharge to the sub-basin due to precipitation is numerically investigated in this study. For this purpose, 25 research wells, whose depths range from 20 to 50 m, were drilled to observe the recharge and collect the necessary field data for the numerical model. Meteorological data were collected from 3 weather stations installed in the study area. The numerical model HYDRUS was calibrated using the field water content data. Soil characterization was done on the core samples; the aquifer characterization was performed, and the alluvial aquifer recharge due to precipitation was calculated. As a result, the computed recharge value ranges from 21.78 to 68.52 mm, with an average value of 43.09 mm. According to the numerical model, this amount of recharge corresponds to 10% of the amount of annual rainfall.Article Citation - WoS: 39Citation - Scopus: 47Quality of Groundwater Resources in Afghanistan(Springer Verlag, 2017) Hayat, Ehsanullah; Baba, AlperWater is the main source of energy production and economy in Afghanistan where agriculture accounts for more than 50% of the country’s gross domestic product (GDP). Access to safe drinking water is still a problem in the country, which has caused different health issues and even child mortality especially in rural areas. Groundwater is the main source of drinking water in the country. However, little knowledge is available about the quality of groundwater throughout the entire country, and its quality has not been investigated extensively yet like in other countries in the world. While most people think that consuming groundwater is a reliable and safe source of drinking water for health, the United Nations (UN) agencies report various kinds of waterborne diseases and even child mortalities due to drinking water quality in the country. In this article, significant geogenic and anthropogenic factors that play a vital role in groundwater contamination of the country are identified and explained. Different geogenic contaminations such as arsenic, fluoride, sulfate, and boron occur in several areas of Afghanistan that have a direct effect on human health. The water quality mapping for Afghanistan is completed for half of the country, which shows that groundwater is plagued by high levels of fluoride and arsenic in some areas. The water quality mapping of the other half of the country cannot be completed due to security concerns currently. Also, there are different kinds of waterborne diseases such as diarrhea, cholera, and dysentery that can be seen in different parts of the country because of anthropogenic activities which continuously deteriorate groundwater.Article Citation - WoS: 25Citation - Scopus: 26Generation of Acid Mine Lakes Associated With Abandoned Coal Mines in Northwest Turkey(Springer Verlag, 2016) Şanlıyüksel Yücel, Deniz; Balcı, Nurgül; Baba, AlperA total of five acid mine lakes (AMLs) located in northwest Turkey were investigated using combined isotope, molecular, and geochemical techniques to identify geochemical processes controlling and promoting acid formation. All of the investigated lakes showed typical characteristics of an AML with low pH (2.59-3.79) and high electrical conductivity values (1040-6430 μS/cm), in addition to high sulfate (594-5370 mg/l) and metal (aluminum [Al], iron [Fe], manganese [Mn], nickel [Ni], and zinc [Zn]) concentrations. Geochemical and isotope results showed that the acid-generation mechanism and source of sulfate in the lakes can change and depends on the age of the lakes. In the relatively older lakes (AMLs 1 through 3), biogeochemical Fe cycles seem to be the dominant process controlling metal concentration and pH of the water unlike in the younger lakes (AMLs 4 and 5). Bacterial species determined in an older lake (AML 2) indicate that biological oxidation and reduction of Fe and S are the dominant processes in the lakes. Furthermore, O and S isotopes of sulfate indicate that sulfate in the older mine lakes may be a product of much more complex oxidation/dissolution reactions. However, the major source of sulfate in the younger mine lakes is in situ pyrite oxidation catalyzed by Fe(III) produced by way of oxidation of Fe(II). Consistent with this, insignificant fractionation between δ34SSO4 and δ34 SFeS2 values indicated that the oxidation of pyrite, along with dissolution and precipitation reactions of Fe(III) minerals, is the main reason for acid formation in the region. Overall, the results showed that acid generation during early stage formation of an AML associated with pyrite-rich mine waste is primarily controlled by the oxidation of pyrite with Fe cycles becoming the dominant processes regulating pH and metal cycles in the later stages of mine lake development.Article Citation - WoS: 24Citation - Scopus: 29Prediction of Acid Mine Drainage Generation Potential of Various Lithologies Using Static Tests: Etili Coal Mine (nw Turkey) as a Case Study(Springer Verlag, 2016) Şanlıyüksel Yücel, Deniz; Baba, AlperThe Etili neighborhood in Can County (northwestern Turkey) has large reserves of coal and has been the site of many small- to medium-scale mining operations since the 1980s. Some of these have ceased working while others continue to operate. Once activities cease, the mining facilities and fields are usually abandoned without rehabilitation. The most significant environmental problem is acid mine drainage (AMD). This study was carried out to determine the acid generation potential of various lithological units in the Etili coal mine using static test methods. Seventeen samples were selected from areas with high acidic water concentrations: from different alteration zones belonging to volcanic rocks, from sedimentary rocks, and from coals and mine wastes. Static tests (paste pH, standard acid–base accounting, and net acid generation tests) were performed on these samples. The consistency of the static test results showed that oxidation of sulfide minerals, especially pyrite—which is widely found not only in the alteration zones of volcanic rocks but also in the coals and mine wastes—is the main factor controlling the generation of AMD in this mine. Lack of carbonate minerals in the region also increases the occurrence of AMD.Article Citation - WoS: 27Citation - Scopus: 31Statistical Analysis of Causes of Death (2005-2010) in Villages of Simav Plain, Turkey, With High Arsenic Levels in Drinking Water Supplie(Taylor and Francis Ltd., 2015) Gündüz, Orhan; Bakar, Coşkun; Şimşek, Celalettin; Baba, Alper; Elçi, Alper; Gürleyük, Hakan; Mutlu, Merdiye; Çakır, AyşeThe purpose of this research was to compare the causes of death in 5 villages situated in Simav Plain, Turkey, during 2005-2010 where different arsenic levels were detected in drinking water supplies. Since groundwater in Simav Plain had arsenic concentrations that ranged between 7.1 and 833.9 ppb, a two-phase research was formulated. In the first phase, public health surveys were conducted with 1,003 villagers to determine the distribution of diseases. In the second phase, verbal autopsy surveys and official death records were used to investigate the causes of death. In total, 402 death cases were found in the study area where cardiovascular system diseases (44%) and cancers (15.2%) were major causes. Cancers of lung (44.3%), prostate (9.8%), colon (9.8%), and stomach (8.2%) were comparably higher in villages with high arsenic levels in drinking water supplies. Furthermore, the majority of cases of liver, bladder, and stomach cancers were observed in villages with high arsenic levels. © 2015 Taylor and Francis Group, LLC.