WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7150
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Article Citation - WoS: 5Citation - Scopus: 4Influence of Partitioning Treatment on Microstructure and Mechanical Properties of an Alloyed Ductile Iron Austempered at Different Temperatures(Walter de Gruyter GmbH, 2023) Neite, Maximilian; Münstermann, Sebastian; Nalçacı, Burak; Davut, Kemal; Erdoğan, MehmetThe present study was conducted to uncover effects of partitioning treatment on Cu-Ni-Mo alloyed ductile iron (DI) austempered at different temperatures. For this purpose, the DI samples, produced via sand casting, were austenitized at 900 °C for 60 min, followed by austempering at the temperatures of 275-325-375 °C for 120 min and afterwards a partitioning treatment was applied at 200 °C for 15 min. In the characterization studies, dilatometer, image analysis, JMat-Pro, mechanical tests, XRD, optical microscope, and scanning electron microscope (SEM) equipped with EBSD detector were utilized. Characterization studies showed that the effects of partitioning treatment were directly correlated with austempering temperature and high carbon austenite volume fraction changed in the range of 19.48-35.45%. That redistribution of carbon (C) between bainitic ferrite and high carbon austenite occurred, in turn, the carbon content of high carbon austenite increased with the partitioning treatment irrespective of austempering temperature were uncovered. Furthermore, the partitioning treatment considerably changed the grain morphologies of both high carbon austenite and banitic ferrite. As a consequence of these microstructural differences, the highest tensile strength of 1489.2 MPa was established in the sample austempered at 275 °C and partitioned at 200 °C, whereas the highest ductility of 5.61% acquired at the austempering temperature of 375 °C. © 2023 Walter de Gruyter GmbH, Berlin/Boston.Article Citation - WoS: 3Citation - Scopus: 4Microfluidic-Assisted Preparation of Nano and Microscale Chitosan Based 3d Composite Materials: Comparison With Conventional Methods(Wiley, 2022) Kimna, Ceren; Değer, Sibel; Tamburacı, Sedef; Tıhmınlıoğlu, FundaAlthough nanofillers contribute to improved physical characteristics and biological functionalities of polymer-based biomaterials, their dispersion in polymer matrices is still a challenging issue in terms of obtaining consistency for the inherent properties. To tackle this problem, homogenization techniques are applied to disperse the nanofillers in such polymers, however, these methods can cause undesired changes especially in the rheological properties and the physical structure of the biopolymer matrices. Recently, as a novel homogenization technique, microfluidization has been used to homogenize polymer nanocomposites to minimize these limitations. In this study, two different nanocomposite structures as chitosan/montmorillonite (CS/MMT) and chitosan/polyhedral oligomeric silsesquioxane nanocages (CS/POSS) were homogenized with microfluidization and investigated in terms of physical alterations. Furthermore, the effect of microfluidizer technique on material characteristics was compared with conventional homogenization techniques, i.e., ultrasonic bath and sonication in terms of solution, nano – (e.g., hydrodynamic size, drug encapsulation) and macroscopic material characteristics (e.g., porosity, mechanical properties, swelling and thermal degradation). It was found that the microfluidizer homogenization improves the physical characteristics in both nano and macroscale materials: Nanospheres obtained from CS/MMT composites showed enhanced stability, uniform size distribution (<100 nm, PDI: [removed]50%) whereas 3D porous CS/POSS scaffolds showed improved structural uniformity (i.e., homogeneous and interconnected microstructure) and enhanced thermal and mechanical properties. The obtained results indicate that the microfluidizer homogenization ensures a successful nanofiller dispersion in polymer matrices, thereby improving the biomaterial characteristics impressively compared to the sonication methods.Article Citation - WoS: 4Citation - Scopus: 5Effects of Tib2 Nanoparticle Content on the Microstructure and Mechanical Properties of Aluminum Matrix Nanocomposites(Walter de Gruyter GmbH, 2017) Kandemir, SinanThe present work reports the fabrication of A357 alloy matrix nanocomposites reinforced with 0.5, 1.0 and 2.0 wt.-% TiB2 nanoparticles (20-30 nm) by a novel method which is the combination of semi-solid mechanical mixing and ultrasonic dispersion of nanoparticles in liquid state. The microstructural and mechanical properties of the fabricated nanocomposites were investigated. The microstructural studies conducted with optical and advanced electron microscopes indicated that reasonably effective deagglomeration and uniform distribution of TiB2 nanoparticles into the matrix were achieved. Transmission electron microscopy studies also confirmed that the nanoparticles were embedded into the matrix and a good bonding was obtained between the matrix and the reinforcement. Increasing nanoparticle content led to grain refinement and significant enhancement in the mechanical properties of nanocomposites. The addition of 0.5, 1.0, and 2.0 wt.-% TiB2 nanoparticles increased the 0.2 % proof stress of matrix alloy by approximately 31, 48 and 61 %, respectively. The contribution of different mechanisms to the strength enhancement is discussed. It is proposed that the strengthening is mainly due to Orowan mechanism and dislocation generation effect by the coefficient of thermal expansion mismatch between the TiB2 nanoparticles and the matrix.Article Citation - WoS: 14Citation - Scopus: 16Microstructure and Mechanical Properties of A357/Sic Nanocomposites Fabricated by Ultrasonic Cavitation-Based Dispersion of Ball-Milled Nanoparticles(SAGE Publications Inc., 2017) Kandemir, SinanIn this work, A357/0.5 wt.% SiC nanocomposites were fabricated with a combination of ultrasonic processing and a nanoparticle feeding mechanism that involves the introduction of a closed end aluminium tube filled with the ball-milled SiC nanoparticles (20-30 nm) and aluminium powders (<75 μm) into the melt for complete deagglomeration and uniform dispersion of nanoparticles through the matrix. The microstructural and mechanical properties of the fabricated nanocomposites were investigated. The microstructural studies conducted with optical and advanced electron microscopes indicate that relatively effective deagglomeration and uniform dispersion of SiC nanoparticles into the molten alloy were achieved. The hardness and tensile properties of the nanocomposites were notably improved compared to those of the ultrasonically processed A357 alloy without reinforcement, showing the strengthening potency of nanoparticles and the good bonding obtained at the particle-reinforcement interface.Article Citation - WoS: 55Citation - Scopus: 64High-Early Ductile Cementitious Composites With Characteristics of Low Early-Age Shrinkage for Repair of Infrastructures(Springer Verlag, 2015) Şahmaran, Mustafa; Al-Emam, Muhannad; Yıldırım, Gürkan; Şimşek, Yunus Emre; Erdem, Tahir Kemal; Lachemi, MohamedReduced performance in concrete infrastructures is mainly caused by the formation of cracks, which may arise due to deteriorating mechanisms during service life. In most cases, reduced performance calls for urgent repairs to the degraded section. Therefore, it is highly desirable to develop dimensionally stable, ductile repair materials that can attain adequately high strength in a limited amount of time, compensate for significant deformation due to mechanical and environmental loadings, and prevent early-age shrinkage cracks. In this paper, the performance of such a material (high-early-strength engineered cementitious composites, HES-ECC, with very low early-age shrinkage capacity) was investigated by studying mechanical properties and dimensional stability. Composites were produced with different water to cementitious materials and slag to Portland cement ratios. In order to enhance composite properties in terms of ductility and early-age shrinkage characteristics, saturated lightweight aggregates replaced sand in the mixtures. The experimental results show that the majority of HES-ECC mixtures developed in this study attained compressive strength values of more than 20.0 MPa and minimum flexural strength of 6.0 MPa within 6 h. Moreover, the HES-ECC mixtures exhibited strain-hardening behavior with strain capacities comparable to normal strength ECC, as well as substantially reduced autogenous shrinkage strain, both of which are unlikely to trigger the formation of cracks in tension at early ages. The integration of these conflicting parameters suggests that HES-ECC can easily meet the need for fast and durable repairs.Article Citation - WoS: 166Citation - Scopus: 170Mechanical Properties of Monolayer Gas and Gase Crystals(American Physical Society, 2016) Yağmurcukardeş, Mehmet; Senger, Ramazan Tuğrul; Peeters, François M.; Şahin, HasanThe mechanical properties of monolayer GaS and GaSe crystals are investigated in terms of their elastic constants: in-plane stiffness (C), Poisson ratio (ν), and ultimate strength (σU) by means of first-principles calculations. The calculated elastic constants are compared with those of graphene and monolayer MoS2. Our results indicate that monolayer GaS is a stiffer material than monolayer GaSe crystals due to the more ionic character of the Ga-S bonds than the Ga-Se bonds. Although their Poisson ratio values are very close to each other, 0.26 and 0.25 for GaS and GaSe, respectively, monolayer GaS is a stronger material than monolayer GaSe due to its slightly higher σU value. However, GaS and GaSe crystals are found to be more ductile and flexible materials than graphene and MoS2. We have also analyzed the band-gap response of GaS and GaSe monolayers to biaxial tensile strain and predicted a semiconductor-metal crossover after 17% and 14% applied strain, respectively, for monolayer GaS and GaSe. In addition, we investigated how the mechanical properties are affected by charging. We found that the flexibility of single layer GaS and GaSe displays a sharp increase under 0.1e/cell charging due to the repulsive interactions between extra charges located on chalcogen atoms. These charging-controllable mechanical properties of single layers of GaS and GaSe can be of potential use for electromechanical applications. © 2016 American Physical Society.Article Citation - WoS: 19Citation - Scopus: 20Isothermal Crystallization Kinetics and Mechanical Properties of Polycaprolactone Composites With Zinc Oxide, Oleic Acid, and Glycerol Monooleate(John Wiley and Sons Inc., 2013) Alp, Burcu; Cesur, SerapThe isothermal crystallization and mechanical behavior of polycaprolactone (PCL) with zinc oxide (ZnO) with oleic acid and glycerol monooleate (GMO) were studied. Theoretical melting points calculated by the Flory-Huggins and Thompson-Gibbs models were thoroughly compared with differential scanning calorimetry experimental observations. The isothermal crystallization kinetic parameters by Avrami analysis showed that crystallization was controlled by nucleation, crystal growth was spherical, and the nucleation type changed between thermal and athermal nucleation. X-ray diffraction showed that when the additives were used together both the crystal thickness and the degree of crystallinity increased. A multiple-response regression analysis was made with the ZnO, oleic acid, and GMO concentrations as variables and the crystallinity as output. Interaction parameters by the Pukanzky model were calculated from the tensile strength at the yield point and indicated that the addition of oleic acid or GMO improved the interface between the ZnO particles and PCL.Article Citation - WoS: 17Citation - Scopus: 21Effects of Particle Size and Electrical Resistivity of Filler on Mechanical, Electrical, and Thermal Properties of Linear Low Density Polyethylene-Zinc Oxide Composites(John Wiley and Sons Inc., 2013) Özmıhçı Ömürlü, Filiz; Balköse, DevrimThe effects of particle size and electrical resistivity of zinc oxide (ZnO) on mechanical properties, electrical and thermal conductivities of composites made with linear low density polyethylene (LLDPE) were investigated. Micron sized (mZnO), submicron sized (sZnO), and nano sized (nZnO) powders having resistivities of 1.5 × 106, 1.5 × 109, and 1.7 × 108 were used to prepare composites with 5-20 vol % filler. The tensile strength was lowered and the modulus of elasticity of the composites was increased with ZnO addition. Rather than the particle size of the ZnO, its initial resistivity and aspect ratio affected the resistivity of composites. The resistivity of the LLDPE was lowered from 2.3 × 1016 Ω cm down to 1.4 × 1010 Ω cm with mZnO addition. Thermal conductivity of the composites was increased with ZnO addition 2.5-3 times of the polymer matrix. The composites can be used for electrostatically dissipating and heat sink applications due to their decreased electrical resistivity and increased thermal conductivity.Article Citation - WoS: 75Citation - Scopus: 87Use of Spent Foundry Sand and Fly Ash for the Development of Green Self-Consolidating Concrete(Springer Verlag, 2011) Şahmaran, Mustafa; Lachemi, Mohamed; Erdem, Tahir Kemal; Yücel, Hasan ErhanIn the United States alone, the foundry industry discards up to 10 million tons of sand each year, offering up a plentiful potential resource to replace sand in concrete products. However, because the use of spent foundry sand (SFS) is currently very limited in the concrete industry, this study investigates whether SFS can successfully be used as a sand replacement material in cost-effective, green, self-consolidating concrete (SCC). In the study, SCC mixtures were developed to be even more inexpensive and environmentally friendly by incorporating Portland cement with fly ash (FA). Tests done on SCC mixtures to determine fresh properties (slump flow diameter, slump flow time, V-funnel flow time, yield stress, and relative viscosity), compressive strength, drying shrinkage and transport properties (rapid chloride permeability and volume of permeable pores) show that replacing up to 100% of sand with SFS and up to 70% Portland cement with FA enables the manufacture of green, lower cost SCC mixtures with proper fresh, mechanical and durability properties. The beneficial effects of FA compensate for some possible detrimental effects of SFS.Article Citation - WoS: 13Citation - Scopus: 18Effect of Corn-Zein Coating on the Mechanical Properties of Polypropylene Packaging Films(John Wiley and Sons Inc., 2011) Tıhmınlıoğlu, Funda; Atik, İsa Doğan; Özen, BanuIn this study, a novel film structure of corn zein coated on polypropylene (PP) synthetic films for food packaging applications was developed, and the mechanical properties of the resulting coated film, as affected by the coating formulation, were investigated. Composite structures of PP films coated with corn zein were obtained through a simple solvent casting method. Different amounts of corn zein (5 and 15%) were dissolved in 70 and 95% aqueous ethanol solution at 50 C. Solutions of corn zein plasticized with poly(ethylene glycol) and glycerol (GLY) at various levels (20 and 50%) were applied on corona-discharge-treated PP. A statistical analysis based on full factorial design was performed to examine the influence of the coating formulation on the final properties of the corn-zein-coated PP films. A significant (p < 0.05) improvement in the coated film’s mechanical properties was observed compared to those of the uncoated PP. The effect of the plasticization of the coating solutions was also quite significant. In general, GLY provided better improvements in the mechanical properties of the corn-zein-coated PP films. The statistical analysis of the results showed that the corn-zein and plasticizer concentrations and plasticizer type used in the coating formulations were more effective parameters and had significant effects on the mechanical behavior of the coated PP films. In conclusion, corn-zein coatings could have potential as alternatives to conventional synthetic polymers used in composite multilayer structures for food packaging applications.