Materials Science and Engineering / Malzeme Bilimi ve Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/4719
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Article Citation - WoS: 3Citation - Scopus: 4Electrical Characterizations of Schottky Diodes on Ito Modified by Aromatic Sams(Polish Academy of Sciences, 2013) Havare, A. Kemal; Okur, Salih; Yağmurcukardeş, Nesli; Can, M.; Aydın, H.; Şeker, M.; Demiç, ŞerafettinIn order to understand the electronic properties of the organic Schottky diode, ITO/TPD/Al and ITO/SAM/ TPD/Al organic Schottky devices were fabricated to obtain currentffvoltage characteristics. From the slopes and y-axis intercepts of the plots, the values of the ideality factor, barrier heights of the ITO/SAM/TPD/Al diode were determined as 2.03 and 0.56 eV, respectively. The surface characterizations of modified and unmodified ITO were performed via atomic force microscopy.Article Citation - WoS: 1Citation - Scopus: 1Improvement of Anode/Htl Interface Properties Using Self-Assembled Monolayer in Organic Electronic Devices(Polish Academy of Sciences, 2013) Yaman, M.; Yağmurcukardeş, Nesli; Havare, A. Kemal; Aydın, H.; Ocakoğlu, Kasım; Okur, SalihFabrication and characterization of highly effcient organic light-emitting diode with surface modification of indium tin oxide anodes by using self-assembled monolayer technique have been studied. Four different self-assembled molecules, K-28 ruthenium complex, octadecylamine hydrochloride, octadecyltrichlorosilane and mercaptohexdecanoic acid are used to modify ITO surface to improve the interface properties. Space charge limited currents measurements have been used to evaluate carrier mobility under steady state current. The results show that the surface properties such as the stability of ITO anode layer have significant effects on charge injection in organic light-emitting diode devices.Article Citation - WoS: 49Citation - Scopus: 51Voc Sensors Based on a Metal Oxide Nanofibrous Membrane/Qcm System Prepared by Electrospinning(Royal Society of Chemistry, 2014) Horzum Polat, Nesrin; Taşçıoğlu, Didem; Özbek, Cebrail; Okur, Salih; Demir, Mustafa MuammerWe report a simple synthetic route to fabricate crystalline ZnO and CeO2/ZnO nanofibrous mats and their sensing characteristics against volatile organic compounds (VOCs) such as benzene, propanol, ethanol, and dichloromethane. Precursor fibers were fabricated by electrospinning of poly(vinyl alcohol) and metal salt(s) at 2.5 kV cm-1 in aqueous solution. The fibers were directly deposited on the crystal surface of a quartz crystal microbalance (QCM). The crystal, which was coated by nanostructured PVA/metal precursor(s) fibers, was subjected to calcination in air at 500 °C for 5 h. The formation of an oxide based nanofiber mat was revealed by scanning electron microscopy and X-ray diffraction. Upon exposure of the nanofiber mats to the VOCs, the compounds adsorbed onto the surface of oxidic fibers. The physisorption of the compounds was confirmed by FTIR and QCM. Both systems showed sensitivity to the VOCs and they hold a broad promise particularly for sensing applications of volatile alcoholic compounds. The introduction of CeO2 into the ZnO structure reduced the sensitivity of ZnO most probably due to the decrement of oxygen vacancies.