Chemistry / Kimya
Permanent URI for this collectionhttps://hdl.handle.net/11147/4072
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Article Citation - WoS: 7Citation - Scopus: 7Cleavage of Ring a and Formation of an Unusual Nor-Triterpene Skeleton Via the Baeyer-Villiger Reaction(Elsevier Ltd., 2012) Tağ, Özgür; Çağır, Ali; Khan, Ikhlas A.; Bedir, ErdalWith the aim to generate a compound library for our biological screening studies, cycloastragenol was subjected to chemical transformation studies. The Baeyer-Villiger oxidation experiments provided an interesting 3,5-seco-4-nor-triterpene skeleton via ring opening followed by an unusual rearrangement. A new methodology is described for transforming triterpenoids into 3,5-seco-4-nor derivatives.
