Chemistry / Kimya

Permanent URI for this collectionhttps://hdl.handle.net/11147/4072

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Author: search.filters.author.Aygün, MuhittinSubject: search.filters.subject.Catalysis

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  • Article
    Citation - WoS: 21
    Citation - Scopus: 21
    Palladium-Catalyzed Alkoxycarbonylation of Conjugated Enyne Oxiranes: a Diastereoselective Method for the Synthesis of 7-Hydroxy
    (American Chemical Society, 2015) Kuş, Melih; Artok, Levent; Aygün, Muhittin
    Palladium-catalyzed alkoxycarbonylative 1,5-substitution of conjugated enyne oxiranes provides a diastereoselective route to (E)-configured 7-hydroxy-2,3,5-trienoates. The reactions proceeded in a highly stereoselective manner, possibly through sequential formation of π-allylpalladium and σ-vinylallenyl palladium complexes. The major diastereomeric form of the product is determined by the configuration of the alkenyl moiety of the substrate.