Chemistry / Kimya
Permanent URI for this collectionhttps://hdl.handle.net/11147/4072
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Article Citation - WoS: 2Citation - Scopus: 5Synthesis and Characterization of Two Oxo-Bridged Oxo(arylimido) [tris(3,5-Dimethylpyrazolyi)borato]molybdenum(v) Complexes and Crystal Structure of [motp*(o)ci](µ-O)[motp*(ci)(?nc6h 4ome)](Springer Verlag, 2004) Topaloğlu, Işıl; Günyar, Alev; Jeffery, John C.; Hamidov, HayrullahReaction of the oxo-molybdenum(V) compound, [MoTp*(O)Cl2], [Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate] with p-methoxy and p-nitroaniline in the presence of Et3N under N2, afforded the oxo-bridged oxo(arylimido) molybdenum(V) complexes, [MoTp*(O)Cl](μ- O)[MoTp*(Cl)(≡NC6H4R)] (1, R = OMe; 2, R = NO2). The new compounds were characterized by elemental analysis, i.r., mass, and 1H-n.m.r. spectra. The single crystal X-ray crystallographic determination of [MoTp*(O)Cl](μ-O)[MoTp*(Cl) (≡NC6H4OMe)] was carried out to confirm that there is a Mo - O - Mo bridge and a near linear arylimido group in the structure.Article Citation - WoS: 1Citation - Scopus: 4Synthesis and Characterization of a New Mono-Molybdenated Metallo-Ligand [mo{hb(3,5-Me2c3hn2)3}(no)cl(oc 6h4pph2-P)](Marcel Dekker Inc., 1999) Topaloğlu, Işıl; McCleverty, Jon A.The "metallo-ligands" can be considered effectively as a modified triphenylphosphine ligand, and used to generate novel transtion metal complexes in which electron-transfer and magnetism is embedded within the stable ligand framework. A new mono-molybdenated metallo-ligand was synthesized and characterized by NMR (1H and 31P-{1H}), IR and mass spectroscopy techniques as a starting material in the search for designing novel bimetallic complexes exhibiting optoelectronic properties and development of non-linear optical materials that possess commercial device applications.