Chemistry / Kimya

Permanent URI for this collectionhttps://hdl.handle.net/11147/4072

Browse

Filters

20111

Settings

Scopus Q: search.filters.scopusQuartile.Q1Subject: search.filters.subject.Alkoxycarbonylation

Search Results

Now showing 1 - 1 of 1
  • Article
    Citation - WoS: 37
    Citation - Scopus: 38
    Palladium-Catalyzed Alkoxycarbonylation of (z)-2 Carbonates Leading To 2,3,5-Trienoates
    (American Chemical Society, 2011) Akpınar, G. Eray; Kuş, Melih; Üçüncü, Muhammed; Karakuş, Erman; Artok, Levent
    Pd(0)-catalyzed carbonylation of (Z)-2-en-4-yn carbonates in the presence of a balloon pressure of CO in an alcohol donates vinylallenyl esters with an exclusively E-configuration and in high yields. The fact that no such reactivity could be observed with E-configured enyne carbonates may indicate that the reaction is promoted via the cooperative coordination of palladium with both alkynyl and carbonate moieties.