Chemistry / Kimya

Permanent URI for this collectionhttps://hdl.handle.net/11147/4072

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2005 - 200912010 - 20181

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Subject: search.filters.subject.SilicaWoS Q: search.filters.wosQuartile.Q2

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Now showing 1 - 2 of 2
  • Article
    Citation - WoS: 8
    Citation - Scopus: 10
    Trypsin-Immobilized Silica: a Novel Adsorbent for V(iv) and V(v) Removal From Water
    (Water Environment Federation, 2018) Erdem Yayayürük, Aslı; Shahwan, Talal; Şanlı Mohamed, Gülşah; Eroğlu, Ahmet Emin
    In the present study, trypsin-immobilized silica was employed for the removal of V(IV) and V(V) ions from water. The synthesized sorbent was first characterized and then investigated for the removal of V(IV) and V(V) under various experimental conditions. The adsorption performance of the sorbent was tested as a function of pli, sorbent amount, initial vanadium concentration, contact time, and temperature. The sorption process was then investigated, both from a kinetic perspective and also in terms of isotherm models. The Langmuir adsorption isotherm was the best model to describe the sorption process. Sorption thermodynamics were spontaneous and exothermic. The proposed method was successfully applied to real samples for the removal of V(IV)and V(V) with sufficient accuracy and precision.
  • Article
    Citation - WoS: 47
    Effect of Filler Amount on Thermoelastic Properties of Poly (dimethylsiloxane) Networks
    (Elsevier Ltd., 2005) Demir, Mustafa Muammer; Menceloğlu, Yusuf Z.; Erman, Burak
    End-linked poly(dimethylsiloxane) (PDMS) networks were prepared in the presence of fumed silica particles with hydroxyl groups at their surfaces. The silica particles were introduced into the polymer solution prior to end-linking. Hydroxyl ended PDMS chains were end-linked via the tetra functional crosslinker, tetraethoxysilane. The filler content varied in the range 0-5 wt%. Atomic Force Microscopy was used to image and characterize the silica particles. Swelling, stress-strain and thermoelasticity experiments were performed. The temperature coefficient and the energetic part of the force in uniaxial extension are found to increase with increasing silica amount. This observation is ascribed to effects contributed possibly by the adsorption layer around the silica particles.