Synthesis of Α,β-Unsaturated Ketones by Rhodium-Catalyzed Carbonylative Arylation of Internal Alkynes With Arylboronic Acids
| dc.contributor.author | Kuş, Melih | |
| dc.contributor.author | Aksın Artok, Özge | |
| dc.contributor.author | Ziyanak, Fırat | |
| dc.contributor.author | Artok, Levent | |
| dc.coverage.doi | 10.1055/s-2008-1078047 | |
| dc.date.accessioned | 2016-10-31T13:56:20Z | |
| dc.date.available | 2016-10-31T13:56:20Z | |
| dc.date.issued | 2008 | |
| dc.description.abstract | The Rh-catalyzed reaction of arylboronic acids with internal alkynes under a CO atmosphere in the presence of an acid additive afforded α,β-unsaturated ketones as the major products. Hydroacylation of internal alkynes, except in the case of diaryl acetylenes, proceeded in syn fashion, yielding the E-configured isomer. A mixture of E- and Z-isomers was obtained with diphenyl acetylene. Reactions were also highly regioselective for various nonsymmetric alkynes. | en_US |
| dc.description.sponsorship | Scientific and Technical Research Council of Turkey (TBAG-106T385), National Boron Research Institute (BOREN-2006-14-Ç13-09), and IZTECH (2007-IYTE-14) | en_US |
| dc.identifier.citation | Kuş, M., Aksın Artok, Ö., Ziyanak, F., and Artok, L. (2008). Synthesis of α,β-unsaturated ketones by rhodium-catalyzed carbonylative arylation of internal alkynes with arylboronic acids. Synlett, (17), 2587-2592. | en_US |
| dc.identifier.doi | 10.1055/s-2008-1078047 | en_US |
| dc.identifier.doi | 10.1055/s-2008-1078047 | |
| dc.identifier.issn | 0936-5214 | |
| dc.identifier.scopus | 2-s2.0-55549108402 | |
| dc.identifier.uri | https://hdl.handle.net/11147/2354 | |
| dc.identifier.uri | http://doi.org/10.1055/s-2008-1078047 | |
| dc.language.iso | en | en_US |
| dc.publisher | Georg Thieme Verlag | en_US |
| dc.relation.ispartof | Synlett | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Alkynes | en_US |
| dc.subject | Boron | en_US |
| dc.subject | Carbonylation | en_US |
| dc.subject | Enones | en_US |
| dc.subject | Rhodium | en_US |
| dc.title | Synthesis of Α,β-Unsaturated Ketones by Rhodium-Catalyzed Carbonylative Arylation of Internal Alkynes With Arylboronic Acids | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| gdc.author.institutional | Kuş, Melih | |
| gdc.author.institutional | Aksın Artok, Özge | |
| gdc.author.institutional | Ziyanak, Fırat | |
| gdc.author.institutional | Artok, Levent | |
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| gdc.description.department | İzmir Institute of Technology. Chemistry | en_US |
| gdc.description.endpage | 2592 | en_US |
| gdc.description.issue | 17 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| gdc.description.scopusquality | Q3 | |
| gdc.description.startpage | 2587 | en_US |
| gdc.description.volume | 2008 | |
| gdc.description.wosquality | Q3 | |
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| gdc.identifier.wos | WOS:000260777600005 | |
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| gdc.oaire.keywords | Alkynes | |
| gdc.oaire.keywords | Enones | |
| gdc.oaire.keywords | Carbonylation | |
| gdc.oaire.keywords | Rhodium | |
| gdc.oaire.keywords | Boron | |
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