Regio- and Stereoselective Synthesis of 2,3,5-Trienoates by Palladium-Catalyzed Alkoxycarbonylation of Conjugated Enyne Carbonates
| dc.contributor.author | Karagöz, Ezgi Şule | |
| dc.contributor.author | Kuş, Melih | |
| dc.contributor.author | Akpınar, Gürkan Eray | |
| dc.contributor.author | Artok, Levent | |
| dc.coverage.doi | 10.1021/jo5014993 | |
| dc.date.accessioned | 2017-04-25T08:59:08Z | |
| dc.date.available | 2017-04-25T08:59:08Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | Palladium-catalyzed carbonylation of 2,4-enyne carbonates in an alcohol and under balloon pressure of CO proceeds through 1,5-substitution to yield (E)-2,3,5-trienoates. The olefin geometry of the substrate is important to control the overall stereochemistry of this alkoxycarbonylation method. The reaction proceeds through successive formation of π-allylpalladium with an R3 group oriented syn and σ-allenyl palladium complexes. | en_US |
| dc.description.sponsorship | TUBITAK | en_US |
| dc.identifier.citation | Karagöz, E.Ş., Kuş, M., Akpınar, G.E., and Artok, L. (2014). Regio- and stereoselective synthesis of 2,3,5-trienoates by palladium-catalyzed alkoxycarbonylation of conjugated enyne carbonates. Journal of Organic Chemistry, 79(19), 9222-9230. doi:10.1021/jo5014993 | en_US |
| dc.identifier.doi | 10.1021/jo5014993 | en_US |
| dc.identifier.doi | 10.1021/jo5014993 | |
| dc.identifier.issn | 0022-3263 | |
| dc.identifier.issn | 1520-6904 | |
| dc.identifier.scopus | 2-s2.0-84907761944 | |
| dc.identifier.uri | https://doi.org/10.1021/jo5014993 | |
| dc.identifier.uri | https://hdl.handle.net/11147/5396 | |
| dc.language.iso | en | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.relation.ispartof | Journal of Organic Chemistry | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Carbonates | en_US |
| dc.subject | Group-oriented | en_US |
| dc.subject | Stereochemistry | en_US |
| dc.subject | Palladium compounds | en_US |
| dc.subject | Stereoselective synthesis | en_US |
| dc.title | Regio- and Stereoselective Synthesis of 2,3,5-Trienoates by Palladium-Catalyzed Alkoxycarbonylation of Conjugated Enyne Carbonates | en_US |
| dc.type | Article | en_US |
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| gdc.author.institutional | Karagöz, Ezgi Şule | |
| gdc.author.institutional | Kuş, Melih | |
| gdc.author.institutional | Akpınar, Gürkan Eray | |
| gdc.author.institutional | Artok, Levent | |
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| gdc.description.department | İzmir Institute of Technology. Chemistry | en_US |
| gdc.description.endpage | 9230 | en_US |
| gdc.description.issue | 19 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
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| gdc.description.startpage | 9222 | en_US |
| gdc.description.volume | 79 | en_US |
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| gdc.oaire.keywords | Palladium compounds | |
| gdc.oaire.keywords | Molecular Structure | |
| gdc.oaire.keywords | Group-oriented | |
| gdc.oaire.keywords | Stereoselective synthesis | |
| gdc.oaire.keywords | Carbonates | |
| gdc.oaire.keywords | Stereoisomerism | |
| gdc.oaire.keywords | Alkenes | |
| gdc.oaire.keywords | Catalysis | |
| gdc.oaire.keywords | Stereochemistry | |
| gdc.oaire.keywords | Alcohols | |
| gdc.oaire.keywords | Palladium | |
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