Synthesis and Characterization of Two Oxo-Bridged Oxo(arylimido) [tris(3,5-Dimethylpyrazolyi)borato]molybdenum(v) Complexes and Crystal Structure of [motp*(o)ci](µ-O)[motp*(ci)(?nc6h 4ome)]
| dc.contributor.author | Topaloğlu, Işıl | |
| dc.contributor.author | Günyar, Alev | |
| dc.contributor.author | Jeffery, John C. | |
| dc.contributor.author | Hamidov, Hayrullah | |
| dc.coverage.doi | 10.1007/s11243-004-9171-5 | |
| dc.date.accessioned | 2016-06-07T08:03:18Z | |
| dc.date.available | 2016-06-07T08:03:18Z | |
| dc.date.issued | 2004 | |
| dc.description.abstract | Reaction of the oxo-molybdenum(V) compound, [MoTp*(O)Cl2], [Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate] with p-methoxy and p-nitroaniline in the presence of Et3N under N2, afforded the oxo-bridged oxo(arylimido) molybdenum(V) complexes, [MoTp*(O)Cl](μ- O)[MoTp*(Cl)(≡NC6H4R)] (1, R = OMe; 2, R = NO2). The new compounds were characterized by elemental analysis, i.r., mass, and 1H-n.m.r. spectra. The single crystal X-ray crystallographic determination of [MoTp*(O)Cl](μ-O)[MoTp*(Cl) (≡NC6H4OMe)] was carried out to confirm that there is a Mo - O - Mo bridge and a near linear arylimido group in the structure. | en_US |
| dc.description.sponsorship | TÜBİTAK | en_US |
| dc.identifier.citation | Topaloğlu, I., Günyar, A., Jeffery, J. C., and Hamidov, H. (2004). Synthesis and characterization of two oxo-bridged oxo(arylimido) [tris(3,5-dimethylpyrazolyI)borato]molybdenum(V) complexes and crystal structure of [MoTp*(O)CI](μ-O)[MoTp*(CI)(≡NC6H 4OMe)]. Transition Metal Chemistry, 29(7), 780-785. doi:10.1007/s11243-004-9171-5 | en_US |
| dc.identifier.doi | 10.1007/s11243-004-9171-5 | |
| dc.identifier.doi | 10.1007/s11243-004-9171-5 | en_US |
| dc.identifier.issn | 1572-901X | |
| dc.identifier.issn | 0340-4285 | |
| dc.identifier.issn | 0340-4285 | |
| dc.identifier.scopus | 2-s2.0-10844240538 | |
| dc.identifier.uri | http://doi.org/10.1007/s11243-004-9171-5 | |
| dc.identifier.uri | https://hdl.handle.net/11147/4731 | |
| dc.language.iso | en | en_US |
| dc.publisher | Springer Verlag | en_US |
| dc.relation.ispartof | Transition Metal Chemistry | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Organometallics | en_US |
| dc.subject | Biochemical catalysis | en_US |
| dc.subject | Ligands | en_US |
| dc.subject | Organometallic chemistry | en_US |
| dc.subject | Polynuclear complexes | en_US |
| dc.title | Synthesis and Characterization of Two Oxo-Bridged Oxo(arylimido) [tris(3,5-Dimethylpyrazolyi)borato]molybdenum(v) Complexes and Crystal Structure of [motp*(o)ci](µ-O)[motp*(ci)(?nc6h 4ome)] | en_US |
| dc.type | Article | en_US |
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| gdc.author.institutional | Topaloğlu, Işıl | |
| gdc.author.institutional | Günyar, Alev | |
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| gdc.description.department | İzmir Institute of Technology. Chemistry | en_US |
| gdc.description.endpage | 785 | en_US |
| gdc.description.issue | 7 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| gdc.description.scopusquality | Q3 | |
| gdc.description.startpage | 780 | en_US |
| gdc.description.volume | 29 | en_US |
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| gdc.oaire.keywords | Polynuclear complexes | |
| gdc.oaire.keywords | Biochemical catalysis | |
| gdc.oaire.keywords | Organometallic chemistry | |
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