Palladium-Catalyzed Alkoxycarbonylation of Conjugated Enyne Oxiranes: a Diastereoselective Method for the Synthesis of 7-Hydroxy

dc.contributor.author Kuş, Melih
dc.contributor.author Artok, Levent
dc.contributor.author Kuş, Melih
dc.contributor.author Artok, Levent
dc.contributor.other 04.01. Department of Chemistry
dc.contributor.other 04. Faculty of Science
dc.contributor.other 01. Izmir Institute of Technology
dc.coverage.doi 10.1021/acs.joc.5b00382
dc.date.accessioned 2017-07-07T11:48:34Z
dc.date.available 2017-07-07T11:48:34Z
dc.date.issued 2015
dc.description.abstract Palladium-catalyzed alkoxycarbonylative 1,5-substitution of conjugated enyne oxiranes provides a diastereoselective route to (E)-configured 7-hydroxy-2,3,5-trienoates. The reactions proceeded in a highly stereoselective manner, possibly through sequential formation of π-allylpalladium and σ-vinylallenyl palladium complexes. The major diastereomeric form of the product is determined by the configuration of the alkenyl moiety of the substrate. en_US
dc.description.sponsorship Federal Ministry of Education and Research (Germany) via Intensified Cooperation Program; Scientific and Technological Research Council of Turkey (210T092) en_US
dc.identifier.citation Kuş, M., Artok, L., and Aygün, M. (2015). Palladium-catalyzed alkoxycarbonylation of conjugated enyne oxiranes: A diastereoselective method for the synthesis of 7-hydroxy-2,3,5-trienoates. Journal of Organic Chemistry, 80(11), 5494-5506. doi:10.1021/acs.joc.5b00382 en_US
dc.identifier.doi 10.1021/acs.joc.5b00382
dc.identifier.doi 10.1021/acs.joc.5b00382 en_US
dc.identifier.issn 0022-3263
dc.identifier.issn 1520-6904
dc.identifier.scopus 2-s2.0-84930625632
dc.identifier.uri https://doi.org/10.1021/acs.joc.5b00382
dc.identifier.uri https://hdl.handle.net/11147/5889
dc.language.iso en en_US
dc.publisher American Chemical Society en_US
dc.relation info:eu-repo/grantAgreement/TUBITAK/TBAG/210T092 en_US
dc.relation.ispartof Journal of Organic Chemistry en_US
dc.rights info:eu-repo/semantics/openAccess en_US
dc.subject Catalysis en_US
dc.subject Palladium compounds en_US
dc.subject Stereoselectivity en_US
dc.subject Alkoxycarbonylation en_US
dc.subject Diastereoselective en_US
dc.title Palladium-Catalyzed Alkoxycarbonylation of Conjugated Enyne Oxiranes: a Diastereoselective Method for the Synthesis of 7-Hydroxy en_US
dc.type Article en_US
dspace.entity.type Publication
gdc.author.institutional Kuş, Melih
gdc.author.institutional Artok, Levent
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gdc.coar.access open access
gdc.coar.type text::journal::journal article
gdc.collaboration.industrial false
gdc.description.department İzmir Institute of Technology. Chemistry en_US
gdc.description.endpage 5506 en_US
gdc.description.issue 11 en_US
gdc.description.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
gdc.description.scopusquality Q2
gdc.description.startpage 5494 en_US
gdc.description.volume 80 en_US
gdc.description.wosquality Q1
gdc.identifier.openalex W4241187106
gdc.identifier.pmid 25912857
gdc.identifier.wos WOS:000355962300012
gdc.index.type WoS
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gdc.oaire.accesstype BRONZE
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gdc.oaire.influence 3.1908833E-9
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gdc.oaire.keywords Palladium compounds
gdc.oaire.keywords Diastereoselective
gdc.oaire.keywords Stereoselectivity
gdc.oaire.keywords Catalysis
gdc.oaire.keywords Alkoxycarbonylation
gdc.oaire.popularity 4.22913E-9
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gdc.oaire.sciencefields 01 natural sciences
gdc.oaire.sciencefields 0104 chemical sciences
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gdc.opencitations.count 21
gdc.plumx.crossrefcites 19
gdc.plumx.mendeley 12
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