Palladium-Catalyzed Alkoxycarbonylation of Conjugated Enyne Oxiranes: a Diastereoselective Method for the Synthesis of 7-Hydroxy
| dc.contributor.author | Kuş, Melih | |
| dc.contributor.author | Artok, Levent | |
| dc.contributor.author | Aygün, Muhittin | |
| dc.coverage.doi | 10.1021/acs.joc.5b00382 | |
| dc.date.accessioned | 2017-07-07T11:48:34Z | |
| dc.date.available | 2017-07-07T11:48:34Z | |
| dc.date.issued | 2015 | |
| dc.description.abstract | Palladium-catalyzed alkoxycarbonylative 1,5-substitution of conjugated enyne oxiranes provides a diastereoselective route to (E)-configured 7-hydroxy-2,3,5-trienoates. The reactions proceeded in a highly stereoselective manner, possibly through sequential formation of π-allylpalladium and σ-vinylallenyl palladium complexes. The major diastereomeric form of the product is determined by the configuration of the alkenyl moiety of the substrate. | en_US |
| dc.description.sponsorship | Federal Ministry of Education and Research (Germany) via Intensified Cooperation Program; Scientific and Technological Research Council of Turkey (210T092) | en_US |
| dc.identifier.citation | Kuş, M., Artok, L., and Aygün, M. (2015). Palladium-catalyzed alkoxycarbonylation of conjugated enyne oxiranes: A diastereoselective method for the synthesis of 7-hydroxy-2,3,5-trienoates. Journal of Organic Chemistry, 80(11), 5494-5506. doi:10.1021/acs.joc.5b00382 | en_US |
| dc.identifier.doi | 10.1021/acs.joc.5b00382 | |
| dc.identifier.doi | 10.1021/acs.joc.5b00382 | en_US |
| dc.identifier.issn | 0022-3263 | |
| dc.identifier.issn | 1520-6904 | |
| dc.identifier.scopus | 2-s2.0-84930625632 | |
| dc.identifier.uri | https://doi.org/10.1021/acs.joc.5b00382 | |
| dc.identifier.uri | https://hdl.handle.net/11147/5889 | |
| dc.language.iso | en | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.relation | info:eu-repo/grantAgreement/TUBITAK/TBAG/210T092 | en_US |
| dc.relation.ispartof | Journal of Organic Chemistry | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Catalysis | en_US |
| dc.subject | Palladium compounds | en_US |
| dc.subject | Stereoselectivity | en_US |
| dc.subject | Alkoxycarbonylation | en_US |
| dc.subject | Diastereoselective | en_US |
| dc.title | Palladium-Catalyzed Alkoxycarbonylation of Conjugated Enyne Oxiranes: a Diastereoselective Method for the Synthesis of 7-Hydroxy | en_US |
| dc.type | Article | en_US |
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| gdc.author.institutional | Kuş, Melih | |
| gdc.author.institutional | Artok, Levent | |
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| gdc.description.department | İzmir Institute of Technology. Chemistry | en_US |
| gdc.description.endpage | 5506 | en_US |
| gdc.description.issue | 11 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
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| gdc.description.startpage | 5494 | en_US |
| gdc.description.volume | 80 | en_US |
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| gdc.oaire.keywords | Palladium compounds | |
| gdc.oaire.keywords | Diastereoselective | |
| gdc.oaire.keywords | Stereoselectivity | |
| gdc.oaire.keywords | Catalysis | |
| gdc.oaire.keywords | Alkoxycarbonylation | |
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