Rhodium(i)-Catalyzed Carbonylative Arylation of Alkynes With Arylboronic Acids Using Formaldehyde as a Carbonyl Source
| dc.contributor.author | Wang, Chuang | |
| dc.contributor.author | Morimoto, Tsumoru | |
| dc.contributor.author | Kanashiro, Hiroyuki | |
| dc.contributor.author | Tanimoto, Hiroki | |
| dc.contributor.author | Nishiyama, Yasuhiro | |
| dc.contributor.author | Kakiuchi, Kiyomi | |
| dc.contributor.author | Artok, Levent | |
| dc.coverage.doi | 10.1055/s-0033-1341046 | |
| dc.date.accessioned | 2018-02-20T13:20:35Z | |
| dc.date.available | 2018-02-20T13:20:35Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | The rhodium(I)-catalyzed reaction of alkynes with arylboronic acids in the presence of formaldehyde resulted in a carbon monoxide gas-free carbonylative arylation to yield α,β-enones. The simultaneous loading of phosphine-ligated and phosphine-free rhodium(I) complexes is required for efficient catalysis, which catalyze the abstraction of a carbonyl moiety from formaldehyde (decarbonylation) and its subsequent introduction into the substrate (carbonylation), respectively. | en_US |
| dc.description.sponsorship | Ministry of Education, Culture, Sports, Science and Technology, Japan | en_US |
| dc.identifier.citation | Wang, C., Morimoto, T., Kanashiro, H., Tanimoto, H., Nishiyama, Y., Kakiuchi, K., and Artok, L. (2014). Rhodium(I)-catalyzed carbonylative arylation of alkynes with arylboronic acids using formaldehyde as a carbonyl source. Synlett, 25(8), 1155-1159. doi:10.1055/s-0033-1341046 | en_US |
| dc.identifier.doi | 10.1055/s-0033-1341046 | en_US |
| dc.identifier.doi | 10.1055/s-0033-1341046 | |
| dc.identifier.issn | 0936-5214 | |
| dc.identifier.issn | 1437-2096 | |
| dc.identifier.scopus | 2-s2.0-84899923051 | |
| dc.identifier.uri | http://doi.org/10.1055/s-0033-1341046 | |
| dc.identifier.uri | https://hdl.handle.net/11147/6814 | |
| dc.language.iso | en | en_US |
| dc.publisher | Georg Thieme Verlag | en_US |
| dc.relation.ispartof | Synlett | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Alkynes | en_US |
| dc.subject | Arylation | en_US |
| dc.subject | Carbonylation | en_US |
| dc.subject | Formaldehyde | en_US |
| dc.subject | Rhodium | en_US |
| dc.title | Rhodium(i)-Catalyzed Carbonylative Arylation of Alkynes With Arylboronic Acids Using Formaldehyde as a Carbonyl Source | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| gdc.author.institutional | Artok, Levent | |
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| gdc.coar.type | text::journal::journal article | |
| gdc.collaboration.industrial | false | |
| gdc.description.department | İzmir Institute of Technology. Chemistry | en_US |
| gdc.description.endpage | 1159 | en_US |
| gdc.description.issue | 8 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| gdc.description.scopusquality | Q3 | |
| gdc.description.startpage | 1155 | en_US |
| gdc.description.volume | 25 | en_US |
| gdc.description.wosquality | Q3 | |
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| gdc.oaire.keywords | Alkynes | |
| gdc.oaire.keywords | Formaldehyde | |
| gdc.oaire.keywords | Carbonylation | |
| gdc.oaire.keywords | Rhodium | |
| gdc.oaire.keywords | Arylation | |
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