Synthesis and Characterization of Amido and Amido(monoalkylamido)nitrosyl-[tris(3,5 Complexes

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Date

1997

Authors

Topaloğlu, Işıl

Journal Title

Journal ISSN

Volume Title

Publisher

Marcel Dekker Inc.

Open Access Color

BRONZE

Green Open Access

Yes

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Abstract

The chloro-amido complex [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl(NH 2)] was prepared by treating [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl 2] with an excess of ammonia. The monoalkylamido complexes [Mo{HB(3,5-Me2C3HN2)3}-(NO)(NH 2)(NHR)] (R = Me, Et, Pr-n and Bu-n) were obtained by the reaction of [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl(NH 2)] with the appropriate primary amines. The IR and 1H NMR spectra of the new complexes were investigated.

Description

Keywords

Synthesis(Chemistry), Molybdenum, Ammonia, Molybdenum, Ammonia, Synthesis(Chemistry)

Fields of Science

01 natural sciences, 0104 chemical sciences

Citation

Topaloğlu, I., and McCleverty, J. A. (1997). Synthesis and characterization of amido and amido(monoalkylamido)nitrosyl-[tris(3,5-dimethylpyrazolyl)borato]molybdenum complexes. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 27(8), 1205-1217. doi:10.1080/00945719708000258

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1

Source

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

Volume

27

Issue

8

Start Page

1205

End Page

1217
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Scopus : 2

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2

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1

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955

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Downloads

534

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