Hydrothermal Synthesis and Characterization of a New Layered Compound Li2vgeo5
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Date
2004
Authors
Eanes, Mehtap
Journal Title
Journal ISSN
Volume Title
Publisher
Elsevier Ltd.
Open Access Color
BRONZE
Green Open Access
Yes
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Publicly Funded
No
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Average
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Abstract
The new compound Li2VGeO5 with a layered structure has been synthesized at 580°C via the hydrothermal method. The compound crystallizes in the space group P4/n of the tetragonal system with two formula units in a cell of dimensions a=6.5187(9)Å, c=4.5092(9)Å (T=298K), V=191.61(5)Å3. The structure is composed of layers made of repeating [(VO5)(GeO4)]1- units. Li+ ions reside between the layers. The magnetic susceptibility data show an antiferromagnetic coupling below 5K with C=0.47emuKmol-1, and θ=-13K with μeff=1.89μB for each Li 2VGeO5 unit.
Description
Keywords
Antiferromagnetic coupling, Crystal structure, Hydrothermal method, Lithium compounds, Electronic configuration, Crystal structure, Hydrothermal method, Electronic configuration, Antiferromagnetic coupling, Lithium compounds
Fields of Science
02 engineering and technology, 0210 nano-technology, 01 natural sciences, 0104 chemical sciences
Citation
Emirdag-Eanes, M., and Kolis, J. W. (2004). Hydrothermal synthesis and characterization of a new layered compound Li2VGeO5. Journal of Alloys and Compounds, 370(1-2), 90-93. doi:10.1016/j.jallcom.2003.09.027
WoS Q
Q1
Scopus Q
Q1
OpenCitations Citation Count
6
Source
Journal of Alloys and Compounds
Volume
370
Issue
1-2
Start Page
90
End Page
93
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CrossRef : 5
Scopus : 5
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Mendeley Readers : 2
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5
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3
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861
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442
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