Hydrothermal Synthesis and Characterization of a Novel Supramolecular Hybrid Based on Keggin and Cu(i) Complex

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Eanes, Mehtap

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BRONZE

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Yes

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Abstract

A novel inorganic-organic hybrid molecule, [Cu(4,4′bipyH)3(4,4bipy)][HPW12O40]2.12H2O (1), has been hydrothermally synthesized and characterized by IR spectra, TG and single crystal X-ray diffraction analyses. Structural analysis reveals that the novel compound 1 composed of two Kegging polyoxoanion connected with Cu complex fragment forming a big molecule that extends in 3D via hydrogen bonding.

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Keywords

Hydrothermal, Keggin, Polyoxoanion, Keggin, Polyoxoanion, Hydrothermal

Fields of Science

01 natural sciences, 0104 chemical sciences

Citation

Emirdag-Eanes, M., and Önen, B. (2013). Hydrothermal synthesis and characterization of a novel supramolecular hybrid based on Keggin and Cu(I) complex. Inorganic Chemistry Communications, 38, 83–87. doi:10.1016/j.inoche.2013.10.014

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38

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83

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87
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