Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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1996 - 19993

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End date: 1999Publisher: search.filters.publisher.Marcel Dekker Inc.

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Now showing 1 - 3 of 3
  • Article
    Citation - WoS: 1
    Citation - Scopus: 4
    Synthesis and Characterization of a New Mono-Molybdenated Metallo-Ligand [mo{hb(3,5-Me2c3hn2)3}(no)cl(oc 6h4pph2-P)]
    (Marcel Dekker Inc., 1999) Topaloğlu, Işıl; McCleverty, Jon A.
    The "metallo-ligands" can be considered effectively as a modified triphenylphosphine ligand, and used to generate novel transtion metal complexes in which electron-transfer and magnetism is embedded within the stable ligand framework. A new mono-molybdenated metallo-ligand was synthesized and characterized by NMR (1H and 31P-{1H}), IR and mass spectroscopy techniques as a starting material in the search for designing novel bimetallic complexes exhibiting optoelectronic properties and development of non-linear optical materials that possess commercial device applications.
  • Article
    Citation - WoS: 1
    Citation - Scopus: 2
    Synthesis and Characterization of Amido and Amido(monoalkylamido)nitrosyl-[tris(3,5 Complexes
    (Marcel Dekker Inc., 1997) Topaloğlu, Işıl; McCleverty, Jon A.
    The chloro-amido complex [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl(NH 2)] was prepared by treating [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl 2] with an excess of ammonia. The monoalkylamido complexes [Mo{HB(3,5-Me2C3HN2)3}-(NO)(NH 2)(NHR)] (R = Me, Et, Pr-n and Bu-n) were obtained by the reaction of [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl(NH 2)] with the appropriate primary amines. The IR and 1H NMR spectra of the new complexes were investigated.
  • Article
    Citation - WoS: 4
    Citation - Scopus: 4
    Synthesis, Characterization and Reactivity of [exo-Nido 9h10me2)]
    (Marcel Dekker Inc., 1996) Topaloğlu, Işıl
    In this work, the reaction of the 16-electron species [Rh(η3-C8H13)-(η5-C 2B9H9Me2)] with PPh3 was investigated and the product, [exo-nido-Rh-(PPh3)2(η5-C2B 9H10Me2)], which is in an equilibrium with the closo analogue was characterized by 31p{1H}, 1H, 13C and 11B NMR spectroscopy. A mechanism for the complex formation is suggested which is related to the previously reported reactions between the 16-electron complex and PR3 (R = Me and Et) ligands.