Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 1Citation - Scopus: 1Modification of Al-Oxide Tunnel Barriers With Organic Self-Assembled Monolayers(American Institute of Physics, 1999) Okur, Salih; Zasadzinski, John F.Al-oxide tunneling barriers were modified by exposure to a vapor of n-octadecyltrimethoxysilane which forms self-assembled monolayers. The dynamic conductance dI/dV of the modified Al-oxide barrier between Al and Pb electrodes was measured at 4.2 K. Quasilinear conductance backgrounds are observed up to 200 mV with a strength that increases with increasing exposure time from 10 to 60 min. A saturation effect is observed around 200 mV. Beyond 200 mV the dynamic conductance shows a parabolic behavior indicative of elastic tunneling from an asymmetric barrier. The linear background is attributed to inelastic tunneling from a continuum of excitationsArticle Citation - WoS: 24Citation - Scopus: 25Processing of Polymers With Supercritical Fluids(John Wiley and Sons Inc., 1999) Alsoy Altınkaya, Sacide; Duda, John LarryThe removal of impurities, such as residual solvents, unreacted monomers, catalysts, and side-reaction products from polymers represents an important step in polymer processing. Conventional devolatilization techniques for the purification of polymers have limited effectiveness. Devolatilization with supercritical fluids, however, can enhance impurity removal by increasing the thermodynamic driving force and molecular diffusivity.Article Citation - WoS: 4Citation - Scopus: 4Simultaneous Quasiparticle and Josephson Tunneling in Bscco-2212 Break Junctions(Institute of Electrical and Electronics Engineers Inc., 1999) Özyüzer, Lütfi; Miyakawa, Nobuaki; Zasadzinski, John F.; Yusof, Zikri M.; Romano, Pierom; Kendziora, Christopher A.; Hinks, David G.; Gray, Kenneth E.Tunneling measurements are reported for superconductor-insulator-superconductor (SIS) break junctions on underdoped, optimally-doped, and overdoped single crystals of tSrsCaCiOs-).,! (Bi2212). The junction I -V characteristics exhibit welldefined quasiparticle current jumps at eV = 2A as well as hysteretic Josephson currents. The quasiparticle branch has been analyzed in the framework of dxa_y2 (d-wave) superconductivity and indicates that there is preferential tunneling along the lobe directions of the d-wave gap. For overdoped Bi-2212 with TC-62 K, the Josephson current is measured as a function of junction resistance, Rn, which varied by two orders of magnitude (1 kO to 100 kO). IcRn product is proportional to the 0.47 power of /c and displays a maximum of 7.0 mV. When the hole doping is decreased from overdoped (Tc=62 K) to the underdoped regime (Tc=70 K), the average IcRn product increases as does the quasiparticle gap. The maximum IcRn is ~ 40% of the A/e at each doping level, with a value as high as 25 mV in underdoped Bi-2212.Article Citation - WoS: 37Citation - Scopus: 41Differences in the Densities of Charged Defect States and Kinetics of Staebler-Wronski Effect in Undoped (nonintrinsic) Hydrogenated Amorphous Silicon Thin Films(American Institute of Physics, 1997) Güneş, Mehmet; Wronski, Christopher R.A variety of undoped (nonintrinsic) hydrogenated amorphous silicon (a-Si:H) thin films was studied in greater detail using steady-state photoconductivity, σph, subband-gap absorption, α(hν), steady-state photocarrier grating (SSPG), and electron-spin-resonance (ESR) techniques both in the annealed and stabilized light soaked states. The experimental results were self-consisiently modeled using a detailed numerical analysis. It was found that large differences in the optoelectronic properties of device quality a-Si:H thin films can only be explained using a gap slate distribution which consists of positively charged D+ defect states above the Fermi level, the neutral D0 defect states, and the negatively charged D- defect states below the Fermi level. There are large differences both in the densities of neutral and charged defect states and R ratios in different a-Si:H films in the annealed state. The densities of both neutral and charged defect states increased, however, R ratios decreased in the stabilized light soaked state. Very good agreement was obtained between the densities of neutral defect states measured by ESR and those derived from the numerical analysis in the stabilized light soaked state. The kinetics of the Staebler-Wronski effect was also investigated. There was no direct correlation between the decrease of steady-state photoconductivity and increase of subband-gap absorption. The self-consistent fits to wide range of experimental results obtained with the three Gaussian distributions of charged defect states imply that this model is much better representation of the bulk defect states in undoped hydrogenated amorphous silicon thin films.Article Citation - WoS: 19Flexible Poly(vinyl Chloride)-Zeolite Composites for Dye Adsorption From Aqueous Solutions(Taylor and Francis Ltd., 1996) Balköse, Devrim; Ulutan, Sevgi; Çakıcıoğlu Özkan, Seher Fehime; Ülkü, Semra; Köktürk, UğurFlexible poly(vinyl chloride) (PVC) composites having natural zeolite clinoptillolite were prepared by plastisol-plastigel technology. Adsoption of methylene blue on each raw material and on composites was studied both from an equilibrium and a rate approach. It was observed that the adsorption capacity of zeolite decreased when it was embedded in composites. The equilibrium uptake of methylene blue increased with an increasing zeolite fraction in composites. Methylene blue was adsorbed from a 0.02 g·cm-3 aqueous solution slowly, but was nearly adsorbed completely with a composite having a 0.3 volume fraction of zeolite. The effective diffusion coefficient of methylene blue in composites was of the order of 10-13 m2·s-1 and decreased with increasing filler fraction.Article Citation - WoS: 10Citation - Scopus: 11Use of Clinoptilolite in Ethanol Dehydration(Taylor and Francis Ltd., 1996) Tıhmınlıoğlu, Funda; Ülkü, SemraClinoptilolite-type natural zeolite, which exists in various regions of Turkey, has been experimentally studied. For the ethanol-water-local clinoptilolite system, uptake and breakthrough curves were determined under a nitrogen gas atmosphere. In adsorption kinetics and adsorption equilibrium studies, the effects of particle size, temperature and, amount of zeolite on the uptake rate have been investigated. The breakthrough curves for four different flow rates of ethanol and three different bed heights were determined in dynamic column studies. The results of the experiments show that intraparticle diffusion is the main resistance. The local clinoptilolite is a promising adsorbent for water adsorption from aqueous ethanol.Article Citation - WoS: 23Citation - Scopus: 26Body Waves in Fractured Porous Media Saturated by Two Immiscible Newtonian Fluids(Springer Verlag, 1996) Tuncay, Kağan; Çorapçıoplu, M. YavuzA study of body waves in fractured porous media saturated by two fluids is presented. We show the existence of four compressional and one rotational waves. The first and third compressional waves are analogous to the fast and slow compressional waves in Biot's theory. The second compressional wave arises because of fractures, whereas the fourth compressional wave is associated with the pressure difference between the fluid phases in the porous blocks. The effects of fractures on the phase velocity and attenuation coefficient of body waves are numerically investigated for a fractured sandstone saturated by air and water phases. All compressional waves except the first compressional wave are diffusive-type waves, i.e., highly attenuated and do not exist at low frequencies.Article Citation - WoS: 54Citation - Scopus: 61Wave Propagation in Fractured Porous Media(Springer Verlag, 1996) Tuncay, Kağan; Çorapçıoplu, M. YavuzA theory of wave propagation in fractured porous media is presented based on the double-porosity concept. The macroscopic constitutive relations and mass and momentum balance equations are obtained by volume averaging the microscale balance and constitutive equations and assuming small deformations. In microscale, the grains are assumed to be linearly elastic and the fluids are Newtonian. Momentum transfer terms are expressed in terms of intrinsic and relative permeabilities assuming the validity of Darcy's law in fractured porous media. The macroscopic constitutive relations of elastic porous media saturated by one or two fluids and saturated fractured porous media can be obtained from the constitutive relations developed in the paper. In the simplest case, the final set of governing equations reduce to Biot's equations containing the same parameters as of Biot and WillisArticle Citation - WoS: 88Citation - Scopus: 92Material Parameters of Quaternary Iii–v Semiconductors for Multilayer Mirrors at 1:55 Μm Wavelength(IOP Publishing Ltd., 1996) Güden, Mustafa; Piprek, JoachimNine quaternary (Al,Ga,In) - (P,As,Sb) semiconductor compounds lattice matched to InP are investigated theoretically. Direct bandgap, refractive index at wavelength, and thermal conductivity are calculated as a function of the composition. These material properties are important, e.g. in distributed Bragg reflectors of vertical-cavity lasers. The alloy systems AlGaAsSb, AlGaPSb and GaInPSb are found to promise better performance of those mirrors than the common InGaAsP system.Article Citation - WoS: 10Electrolysis of Mgcl2 With a Top Inserted Anode and an Mg-Pb Cathode(Springer Verlag, 1994) Güden, Mustafa; Karakaya, İshakHigh energy consumption in the production of magnesium by molten salt electrolysis is mainly due to the recombination of magnesium and chlorine. The large interelectrode distance used, in conventional techniques, to reduce the extent of ‘back reaction’, results in a significant potential drop. A laboratory cell that enables the operation with smaller interelectrode distance and easy separation of electrode products has been used to study electrolytic magnesium production. The cell features a top inserted graphite anode and a Mg-Pb alloy cathode at the bottom. Current efficiency and power consumption were determined at 690° C using a current density of 0.48 A cm−2. Experiments were performed to study the effects of MgCl2 concentration and anode-cathode distance (a.c.d.) on cell operation. Results indicated that an electrolyte containing 20% MgCl2 (equiweight NaCl:KCl and 1 % NaF) with a 3 cm a.c.d. reduced the cell voltage to 3.72 V. This value corresponds to an energy consumption of 11.3 kWh kg−1 including the refining of Mg-Pb alloy produced at the cathode. This cell performance is more energy efficient compared to conventional magnesium cells.