Chemistry / Kimya
Permanent URI for this collectionhttps://hdl.handle.net/11147/4072
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Article Citation - WoS: 1Citation - Scopus: 2Synthesis and Characterization of Amido and Amido(monoalkylamido)nitrosyl-[tris(3,5 Complexes(Marcel Dekker Inc., 1997) Topaloğlu, Işıl; McCleverty, Jon A.The chloro-amido complex [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl(NH 2)] was prepared by treating [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl 2] with an excess of ammonia. The monoalkylamido complexes [Mo{HB(3,5-Me2C3HN2)3}-(NO)(NH 2)(NHR)] (R = Me, Et, Pr-n and Bu-n) were obtained by the reaction of [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl(NH 2)] with the appropriate primary amines. The IR and 1H NMR spectra of the new complexes were investigated.
