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Citation - WoS: 2
Citation - Scopus: 3
The Amido and Bisalkoxo-Complexes of [tri(3,5-Dimethylpyrazolyl)borato]molydenum Nitrosyl
(TÜBİTAK, 1998) Topaloğlu, Işıl
In this study, the amido nitrosyl molybdenum complex, [Mo{HM(3,5-Me2C3HN2)3}(NO)Cl(NH 2)], was prepared. This compound reacts with alocohols, yielding the bisalkoxo complexes, [Mo{HM(3,5-Me2C3HN2)3}(NO)(OR) 2] (R = Me, Et, Prn, Bun). The new complexes were analyzed by IR and 1H-NMR spectroscopy.
Citation - WoS: 1
Citation - Scopus: 2
Synthesis and Characterization of Amido and Amido(monoalkylamido)nitrosyl-[tris(3,5 Complexes
(Marcel Dekker Inc., 1997) Topaloğlu, Işıl; McCleverty, Jon A.
The chloro-amido complex [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl(NH 2)] was prepared by treating [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl 2] with an excess of ammonia. The monoalkylamido complexes [Mo{HB(3,5-Me2C3HN2)3}-(NO)(NH 2)(NHR)] (R = Me, Et, Pr-n and Bu-n) were obtained by the reaction of [Mo{HB(3,5-Me2C3HN2)3}(NO)Cl(NH 2)] with the appropriate primary amines. The IR and 1H NMR spectra of the new complexes were investigated.

Chemistry / Kimya