Bodipy-Vinyl Dibromides as Triplet Sensitisers for Photodynamic Therapy and Triplet-Triplet Annihilation Upconversion
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Abstract
We devised a new generation of halogen-based triplet sensitisers comprising geminal dibromides at the vinyl backbone of a BODIPY fluorophore. Incorporating geminal dibromides into the pi-conjugation of BODIPY enhanced intersystem crossing due to the heavy atom effect, which in turn improved the extent of excited triplet states.
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Keywords
BODIPY, Dibromides, Photodynamic therapy, Boron Compounds, Bromides, Photosensitizing Agents, Vinyl Compounds, Dose-Response Relationship, Drug, Molecular Structure, Cell Survival, Optical Imaging, Antineoplastic Agents, Photochemotherapy, A549 Cells, Humans, Drug Screening Assays, Antitumor, Cell Proliferation
Fields of Science
01 natural sciences, 0104 chemical sciences
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WoS Q
Q2
Scopus Q
Q2
OpenCitations Citation Count
19
Source
Chemical Communications
Volume
57
Issue
49
Start Page
6039
End Page
6042
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CrossRef : 13
Scopus : 23
PubMed : 6
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