Gold(i)/Zn(ii) Catalyzed Tandem Hydroamination/Annulation Reaction of 4-Yne
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BRONZE
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Yes
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Abstract
The tandem hydroamination-annulation reaction of 4-pentyne-nitriles in the presence of amine nucleophiles and a cooperatively operating catalyst system, consisting of Ph3PAuCl and Zn(ClO4)2, provides an efficient route to 2-aminopyrroles. Two regioisomeric 2-aminopyrroles were formed in moderate to good yields. © 2010 The Royal Society of Chemistry.
Description
Keywords
Tandem hydroamination, Zinc, Annulation reaction, Cyclization, Pyrrole derivative, Zinc, Pyrrole derivative, Tandem hydroamination, Annulation reaction, Cyclization
Fields of Science
01 natural sciences, 0104 chemical sciences
Citation
Demir, A. S., Emrullahoğlu, M., and Buran, K. (2010). Gold(i)/Zn(ii) catalyzed tandem hydroamination/annulation reaction of 4-yne-nitriles. Chemical Communications, 46(42), 8032-8034. doi:10.1039/c0cc02357d
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OpenCitations Citation Count
61
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46
Issue
42
Start Page
8032
End Page
8034
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